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Title:
THERMOSETTING POLYMER, SOLUTION CONTAINING THE SAME AND FILM USING THE SOLUTION
Document Type and Number:
Japanese Patent JP2000186140
Kind Code:
A
Abstract:

To obtain a thermosetting polymer exhibiting excellent heat resistance, electrical characteristics, such as a low dielectric constant, and low water absorption, which are necessitated as electric and electronic materials, and useful as wiring base materials, etc., by subjecting a specific phenol and a diethynyl compound to oxidative coupling.

This thermosetting polymer is obtained by subjecting (A) 70-95 mol% of 2,6-diphenylphenol expressed by the formula and (B) 5-30 mol% of a diethynyl compound expressed by the formula: CH≡C-Ar-C≡CH (Ar is a divalent aromatic unit) (for example, m-diethynylbenzene) to oxidative coupling polymerization at 40-110°C, and has a weight-average molecular weight of 2,000-500,000 when measured by gel permeation chromatography. The component B is added, for example, in an amount of 5-30% based on the total amount of the component A and component B. The polymerization is preferably performed in the presence of a copper compound/amine-based catalyst in a solvent, such as toluene.


Inventors:
KITA KOHEI
TANABE TSUNEAKI
Application Number:
JP36552798A
Publication Date:
July 04, 2000
Filing Date:
December 22, 1998
Export Citation:
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Assignee:
ASAHI CHEMICAL IND
International Classes:
H01L21/312; C08G65/40; C08K5/00; C08L71/12; C09D171/10; (IPC1-7): C08G65/40; C08K5/00; C08L71/12; C09D171/10; H01L21/312