To provide a porous group 4 metal oxide which is useful as a catalyst having excellent thermal stability, a large specific surface area, controlled and sharp pore diameter distribution, and outstanding reaction selectivity, and containing highly dispersed catalyst metal or as a catalyst carrier.
The porous titania is obtained by adding, as a grain growth suppressing agent for suppressing the grain growth at the time of firing, an oxyanion and/or metal carbonyl anion containing a metal selected from P, S, Mo, W, V, B, Al and Si or a metal cation selected from Fe, Ni, Co, Mg, Mn, Pt, Pd, Rh and Ru to hydrosol or hydrogel or a dried material of them of hydrous titanium hydroxide expressed by general formula: MO
COPYRIGHT: (C)2006,JPO&NCIPI
Shinichi Inoue
Toru Takatsuka
Akihiro Muto
Takeo Ono
JP60050721B2 | ||||
JP8022378B2 | ||||
JP62029095B2 | ||||
JP57044605B2 | ||||
JP3755732B2 | ||||
JP4017366B2 | ||||
JP4054563B2 |
US5021392 | ||||
US4511455 |
Tomohiro Nakamura
Aoya Kazuo
Masashi Torino
Eiichi Sano
Mitsunaga Igarashi
Kazuya Sasaki