To provide a transfer sheet which has a toner image and a resin film and causes neither void nor nonuniformity in printing in a pattern printed on the surface of a heat-resistant solid, and a printing method of the toner image.

In a transfer sheet having on a substrate a toner image constituted of toner containing thermoplastic resin and being colored after burning and a resin film, the ashing temperature of the thermoplastic resin contained in the toner is lower than that of the resin film. The toner image and the resin film of the transfer sheet are peeled off from the substrate and stuck on the surface of a heat-resistant solid by bringing the resin film side into close contact with the surface, and then the heat-resistant solid having the resin film and the toner image is heated to or above the ashing temperature of the resin film.