Title:
ACTIVATED CATALYST FOR FISCHER-TROPSCH SYNTHESIS REACTION AND METHOD FOR PRODUCING HYDROCARBONS
Document Type and Number:
WIPO Patent Application WO/2012/132905
Kind Code:
A1
Abstract:
This catalyst for the Fischer-Tropsch synthesis reaction comprises: a carrier containing silica and 0.5-14% by mass of zirconium oxide with respect to the mass of the carrier; and 10-40% by mass of cobalt metal and cobalt oxides in terms of tricobalt tetraoxide with respect to the mass of the catalyst, the cobalt metal and cobalt oxides being supported by the carrier. The degree of reduction of the cobalt atoms is 75-93%, and the hydrogen gas adsorption amount per unit mass of the catalyst at 100°C is 0.40-1.0 ml/g.
Inventors:
NAGAYASU YOSHIYUKI (JP)
ONO HIDEKI (JP)
HAYASAKA KAZUAKI (JP)
YOKOI MAYUMI (JP)
ONO HIDEKI (JP)
HAYASAKA KAZUAKI (JP)
YOKOI MAYUMI (JP)
Application Number:
PCT/JP2012/056567
Publication Date:
October 04, 2012
Filing Date:
March 14, 2012
Export Citation:
Assignee:
JAPAN OIL GAS & METALS JOGMEC (JP)
INPEX CORP (JP)
JX NIPPON OIL & ENERGY CORP (JP)
JAPAN PETROLEUM EXPLORATION CO (JP)
COSMO OIL CO LTD (JP)
NIPPON STEEL ENG CO LTD (JP)
NAGAYASU YOSHIYUKI (JP)
ONO HIDEKI (JP)
HAYASAKA KAZUAKI (JP)
YOKOI MAYUMI (JP)
INPEX CORP (JP)
JX NIPPON OIL & ENERGY CORP (JP)
JAPAN PETROLEUM EXPLORATION CO (JP)
COSMO OIL CO LTD (JP)
NIPPON STEEL ENG CO LTD (JP)
NAGAYASU YOSHIYUKI (JP)
ONO HIDEKI (JP)
HAYASAKA KAZUAKI (JP)
YOKOI MAYUMI (JP)
International Classes:
B01J23/75; C10G2/00; C07B61/00
Domestic Patent References:
| WO2005099897A1 | 2005-10-27 | |||
| WO2005099897A1 | 2005-10-27 |
Foreign References:
| JP2003500188A | 2003-01-07 | |||
| JP2007537035A | 2007-12-20 | |||
| JPS59102440A | 1984-06-13 | |||
| JPS59102440A | 1984-06-13 | |||
| US4568663A | 1986-02-04 | |||
| JP2002501431A | 2002-01-15 |
Other References:
S. ALI ET AL.: "Zr Promotion of Co/Si02 for Fischer-Tropsch Synthesis", JOURNAL OF CATALYSIS, vol. 157, no. 1, November 1995 (1995-11-01), pages 35 - 41, XP055005824
A. FELLER ET AL.: "Cobalt Cluster Effects in Zirconium Promoted Co/Si02 Fischer-Tropsch Catalysts", JOURNAL OF CATALYSIS, vol. 185, no. 1, 1 July 1999 (1999-07-01), pages 120 - 130, XP004465291
See also references of EP 2692431A4
A. FELLER ET AL.: "Cobalt Cluster Effects in Zirconium Promoted Co/Si02 Fischer-Tropsch Catalysts", JOURNAL OF CATALYSIS, vol. 185, no. 1, 1 July 1999 (1999-07-01), pages 120 - 130, XP004465291
See also references of EP 2692431A4
Attorney, Agent or Firm:
SHIGA Masatake et al. (JP)
Masatake Shiga (JP)
Masatake Shiga (JP)
Download PDF:
Claims: