Field of the invention

The present invention relates to a pearly lustre pigment with an anti-discoloring property and an excellent dispersing property, and to a method of preparing the same. The pigment of the present invention can be used as a pigment additive in preparation of plastic articles, inks, coating compositions and decorative boards.

Background of the invention

Recently, a titanium oxide resp. titanium oxide hydrate coated mica pigment as used as a colorant for resins has been found to have a problem that it causes discol oration (especially, yellowing) of resins with the lapse of time so that the resulting resins lose their original color. This is because of addition of additives of a hinder amine light stabilizer (HALS), a phenolic antioxidant such as BHT, a flame retard and an ultraviolet stabilizer to resins, in incorporation of titanium oxide-coated mi to them. In this connection, it is known that where titanium dioxide resp. oxide hydrate is in a resin, the titanium dioxide is catalytically activated due to light or heat energy as imparted thereto to thereby promote the interaction of the additives, or the titanium dioxide would directly react with the additives to cause discolorati of so-called yellowing phenomenon. (S. Okazaki, Colorants. 6,333-341 (1987); M. Seino, Titanium Oxides (published by Gihodo Publishing Co.), pp. 103-106; I. Jagnandan, H. Daun, T.J. Ambrosis & S.G. Gilbert, Journal of Pharmaceutical Science. 68 (7) 916 (1979); N.S. Allen, D.J. Bullen and J.F. Keller, Journal of Materials Science. 12, 1320 (1977)).

Due to the phenomenon, containers, decorative boards and other articles to be manufactured from the resins containing the materials would discolor with the lap of time, after stored, to after all lose their original colors.

As a method of inhibiting the catalytic activity of titanium dioxide in order to evade the phenomenon, in general, there has been provided a technique of stabilizing tita¬ nium dioxide by doping one or more of chromium compounds, silicon compounds, almrώiium compounds, zinc compounds, phosphoric acid compounds and zirconiu c compounds thereinto or by coating one or more of them thereover.

However, if such a surface-coating method is applied to a pearly luster pigment, in general, it would result in loss of the intrinsic luster of the pearly pigment since the amount of the coat is relatively large to be from 5 to 20 % by weight to the weight o JO the pigment as coated therewith. Japanese Patent Application Laid-Open No.

1-225669 has disclosed an organic acid-coated anti-yellowing titanium dioxide pig¬ ment. In the disclosed case, since the surface-treating agent in an organic material, the coated pigment may still have its pearly luster. However, with the lapse of time, the storage stability of the coated pigment becomes to be unsatisfactory.

15

Summary of the invention

The object of the present invention is to overcome the problems in the prior art tech niques. Therefore, the present invention provides a novel pearly luster pigment hav- 2o g the following characteristics (1) to (3) and also a method of preparing the same.

(1) It has an excellent anti-discoloring property for a long period of time.

(2) It hardly coagulates and has a good dispersing property.

25

(3) It does not lose its pearly luster.

Specifically, the present invention provides an anti-discoloring pearly luster pigmen on the basis of mica particles coated with titanium dioxide and/or titanium oxide 30 hydrate wherein:

(a) the surfaces of the titanium dioxide and/or titanium oxide hydrate coate mica particles are coated with from 1 to 7 parts by weight, to 100 party by weight of the titanium dioxide and/or titanium oxide hydrate coated 32 mica particles, of a silicon oxide and/or silicon oxide hydrate;

(b) the surfaces of the coated grains are further coated with from 0.5 to 5 parts by weight, to 100 parts by weight of the titanium dioxide and/or titanium oxide hydrate coated mica particles, of an aluminium oxide and/or aluminium oxide hydrate; and

(c) the surfaces of the coated particles are still further coated with from 0.5 to 3 parts by weight, to 100 parts by weight of the titamum dioxide and/or titanium oxide hydrate coated mica particles, of a zinc oxide and/or zinc oxide hydrate.

The present invention also provides a method of preparing an anti-discoloring pearl luster pigment, in which in a first step, titanium dioxide and/or titanium oxide hydr coated mica particles are suspended in water or in which an aqueous solution of a titanium salt is added dropwise to an aqueous suspension of mica particles the pH o which is largely maintained at a constant value by simultaneous addition of a base, whereby titanium dioxide and/or titanium oxide hydrate is coated onto the surface o the mica particles, then in a second step, an aqueous solution of a silicate and an aqueous solution of an inorganic acid are simultaneously dropwise added to the sus pension obtained in step 1 and stirred with maintaining the pH value of the suspen¬ sion essentially constant whereby a silicon oxide and/or silicon oxide hydrate is coated over the surface of the titanium dioxide and/or titanium oxide hydrate coated mica particles, then in a third step an aqueous solution of an aluminium salt and an aqueous solution of an inorganic base are simultaneously dropwise added to the slurry resulting in step 2 and stirred with maintaining the pH value of the slurry es¬ sentially constant whereby an aluminium oxide and/or aluminium oxide hydrate is coated over the surfaces of the particles obtained in step 2, and further in a fourth step an aqueous solution containing a zinc salt and an aqueous solution of an inorganic base are simultaneously dropwise added to the resulting slurry and stirred with maintaining the pH value of the slurry essentially constant whereby a zinc oxi and/or zinc oxide hydrate is coated over the surfaces of the particles obtained in ste 3, and thereafter the solids are taken out by filtration, washed with water and dried and optionally calcined.

Detailed description of the invention

In the pearly luster pigment of the present invention, the amount of the titanium oxi and/or oxide hydrate coat preferably is from 0.5-250 % by weight, in particular fro 1-100 % by weight and very specifically from 5-60 % by weight of ΗO ₂ with respe to the mass of the uncoated mica particles. The amount of the silicon oxide and/or oxide hydrate coat of the first layer to be coated over the surfaces of titanium dioxid resp. oxide hydrate coated mica particles is from 1 to 7 parts by weight to 100 parts by weight of the titanium dioxide and/or oxide hydrate coated mica particles. If the _j 0 amount is less than 1 part by weight, the pigment could not have an anti-discoloring property; but if it is more than 7 parts by weight, the pigment would lose the luster though it may have an anti-discoloring property. The amount of the aluminium oxid and/or oxide hydrate coat of the second layer over the pigment particles is from 0.5 5 parts by weight to 100 party by weight of the titanium dioxide and/or oxide hydra _j 5 coated mica particles. If the amount is less than 0.5 part by weight, the pigment coul not maintain the excellent dispersing property and luster; but if it is more than 5 par by weight, the pigment would lose the luster. The amount of the zinc oxide and/or oxide hydrate coat of the third layer over the pigment particles is from 0.5 to 3 parts by weight to 100 parts by weight of the titanium dioxide and/or oxide hydrate coate

20 mica particles. If the amount is less than 0.5 part by weight, the discoloring propert of the pigment would be insufficient; but if it is more than 3 parts by weight, the safety of the pigment would be unfavorable.

In general, a silicon oxide is preferably used for imparting and anti-discoloring prop 25 erty to pigments and the like, but it has a coagulating property and the affinity there with resins is poor. Because of the reasons, it is unsuitable as an outer layer. On the other hand, an aluminium oxide is preferably used for imparting a dispersing proper to pigments and, when compared with a silicate, it has a weaker coagulating propert so that it is suitable as an outer layer. A zinc oxide is suitable as an outermost layer 30 for the purpose of inhibiting discoloration due to interaction between additives, suc as BHT, and titanium oxide. However, in consideration of the safety, the amount of the coat of such a zinc oxide is desirably as small as possible.

In the pigment of the present invention, the catalytic activity of titanium dioxide 5 and/or oxide hydrate is inhibited by the silicon oxide coat of the first layer to thereb attain the anti-discoloring property, and the high dispersibility is attained by the

aluminium oxide coat of the second layer so that the luster of the pigment does not lower. Further, the interaction of the other additives in the resin is inhibited by the zinc oxide coat of the third layer so that the pigment may have a satisfactory anti-di coloring property and is therefore durable for a long period of time.

In the present invention, provision of the above-mentioned three layers of the first t third layers is indispensable. Provision of only one layer or two layers of them is in sufficient for attaining the object of the present invention, since the pigment could maintain the excellent anti-discoloring property and good dispersibility and also the _j o luster for a long period of time.

In accordance with the present invention, there is obtained a pearly pigment having long-term anti-discoloring property, an excellent dispersibility with little coagulatio and an excellent luster.

15

As a method of preparing the anti-discoloring pearly luster pigment of the present i vention, the present invention provides a method of preparing an anti-discoloring pearly luster pigment, in which in a first step, titanium dioxide and/or titanium oxid hydrate coated mica particles are suspended in water or in which an aqueous soluti

2o of a titanium salt is added dropwise to an aqueous suspension of mica particles the pH of which is largely maintained at a constant value by simultaneous addition of a base, whereby titanium dioxide and/or titanium oxide hydrate is coated onto the sur face of the mica particles, then in a second step, an aqueous solution of a silicate an an aqueous solution of an inorganic acid are simultaneously dropwise added to the

25 suspension obtained in step 1 and stirred with maintaining the pH value of the sus¬ pension essentially constant whereby a silicon oxide and/or silicon oxide hydrate is coated over the surface of the titanium dioxide and/or titanium oxide hydrate coate mica particles, then in a third step an aqueous solution of an aluminium salt and an aqueous solution of an inorganic base are simultaneously dropwise added to the 0 slurry resulting in step 2 and stirred with maintaining the pH value of the slurry es¬ sentially constant whereby an aluminium oxide and/or aluminium oxide hydrate is coated over the surfaces of the particles obtained in step 2, and further in a fourth step, an aqueous solution containing a zinc salt and an aqueous solution of an inorganic base are simultaneously dropwise added to the resulting slurry and stirred

3 with maintaining

the pH value of the slurry essentially constant whereby a zinc oxide and/or zinc oxi hydrate is coated over the surfaces of the particles obtained in step 3, and thereafter the solids are taken out by filtration, washed with water and dried and optionally calcined.

As the platelet like particles used as starting material which may be uncoated mica particles or mica particles coated with titanium dioxide and/or titanium oxide hydra generally usable are those having a grain size of from 2 to 200 μm and a thickness o from 0.2 to 5 μm, in particular 0.2-0.9 μm.

As the above-mentioned inorganic acid, for example, there are mentioned hydrochl ric acid, sulfuric acid and nitric acid.

As the above-mentioned aqueous solution of an inorganic base, for example, there i mentioned an aqueous solution of containing sodium hydroxide or potassium hydro ide.

As the above-mentioned titanium salt, there are mentioned, for example, titamum chloride or bromide or titanyl sulfate.

As the above-mentioned silicate, for example, there are mentioned sodium silicate and potassium silicate. —

As the above-mentioned aluminium salt, there are mentioned, for example, alu- minium chloride, aluminium nitrate, aluminium sulfate, ammonium aluminium sul¬ fate, sodium aluminium sulfate, and potassium aluminium sulfate.

As a material to used for forming such a zinc oxide coat, there are mentioned, for e ample, zinc chloride and zinc sulfate.

During the different precipitation steps, mainly the respective oxide hydrates are formed which usually are at least partly converted to the respective oxides during t final step of drying and optionally calcining. The respective coating layers in the pigments of the present invention are nor restricted to specific compositions but co prise all compositions from the respective oxide hydrate to the respective oxide.

It is also possible to filter off the intermediate pigment after at least one or more re¬ action steps 1-3 with subsequent washing, drying, optionally calcining and re-sus¬ pending of the intermediate pigment. This process is, however, rather time consumi and costly and is therefore less preferred especially for large scale productions. On the other hand, the conversion of the respective oxide hydrate to the respective oxi is usually found to be more complete in case intermediate drying and/or calcinatio steps are performed which is sometimes advantageous (higher thermal stability of t resulting pigment, higher lustre due to reduced amount of cracks in the respective coating layers).

As examples of resins to which the anti-discoloring pearly luster pigment of the pr sent invention may be applied, there are mentioned polyolefins such a polyethylene polypropylene and polybutadiene; polyvinyls such as polyvinyl chloride, polyvinyl esters and polystyrene; as well as acrylalkylphenols, alkyd resins, amino resins, si- loxanes, epoxy compounds, nylons, polyurethanes, phenoxy compounds, polysul- fones, polycarbonates, polyesters, polyethers, acetals, polyimides, and polyoxyeth enes. Of them, preferred are polyolefin resins.

To the resins, additives may be added, if desired. As examples of additives, there a mentioned a reaction initiator, an antioxidant, a swelling agent, an ultraviolet absor ent, a dye, an organic pigment, a plasticizer, a levelling agent, a flame retarder and others.

The method of preparing the novel anti-discoloring pearly luster pigment of the pre sent invention will be explained concretely hereunder.

First Step: Step of coating titanium oxide resp. oxide hydrate

The uncoated mica particles are suspended in an aqueous solution which by the ad tion of a suitable acid like hydrochloric acid or sulphuric acid is adjusted to a pH- value of about 0.5-5 and preferably of about 1.2-2.5. The suspension is preferably heated to a temperature of about 50-100 °C, preferably of about 70-80 °C. Subse¬ quently, a solution of a titanium salt is slowly added to the mica slurry the pH of which being largely maintained at a constant value by simultaneous addition of a b

such as, for example, NaOH. Especially preferred are TiC solutions which typicall contain between 1-40 °C by weight of TiCL _t . After the addition, the slurry is prefer¬ ably stirred for 30 minutes or more with still maintaining the temperature as it is. Further details of the coating process can be taken, for example, from DE 20 09 566

The resulting intermediate pigment which is coated with titanium dioxide and/or titanium oxide hydrate preferably contains 0.5-70 % by weight, in particular 10-50 by weight of Ti0 ₂ with respect to the mass of the uncoated mica grains.

The step of titanium dioxide resp. oxide hydrate coating can be omitted by starting the sequence of reaction steps with a pigment which is already coated with titanium dioxide resp. oxide hydrate instead on an uncoated mica grain. Such pigments whic are commercially available from Merck Japan, for example, as Iriodin® 100, Iriodin 120 or Iriodin® 225, are described, for example, in Japanese Patent Publications No 43-25,644 and 54-34,010.

Alternatively, the mica particles coated with titanium oxide and/or oxide hydrate ca be filtered off after the first reaction step, washed with water, dried, optionally cal¬ cined and re-suspended to be further treated according to reaction steps 2-4.

The titanium oxide and/or hydrate coating can contain other not inherently colored components such as aluminium oxide resp. hydrate, tin oxide resp. hydrate etc. whic are preferably coprecipitated with the titanium oxide resp. oxide hydrate. The term not inherently colored means that the additional components do not exhibit an ab- sorption color so that the overall appearance of the titamum dioxide resp. oxide hy¬ drate coated mica particles is white or whitish.

Pigments according to the present invention for which the first coating layer obtaine in step 1 consists only of titanium oxide and/or oxide hydrate are preferred.

Second Step: Step of coating silicon oxide resp. oxide hydrate

The slurry obtained in reaction step 1 resp. the slurry of pre-fabricated titanium dio ide and/or oxide hydrate coated mica particles is adjusted to a pH value of about 9-10, for example, with sodium hydroxide. The slurry is heated up to 30 °C or high preferably 50 to 90 °C, and an aqueous solution containing a necessary amount of a silicate is dropwise added thereto over a period of about one hour with stirring, wile the slurry liquid is kept to have a pH value of from 9 to 10 with an acidic aqueous solution, such as an aqueous hydrochloric acid solution. After addition, the resultin _j 0 slurry liquid is further stirred for 30 minutes or more with still maintaining the tem¬ perature thereof as it is.

Third Step: Step of coating aluminium oxide hydrate

_j 5 The pigment-containing slurry liquid is, after the above-mentioned silicon oxide hy¬ drate coating step, adjusted to have a pH value of from 5 to 6 with, for example, an aqueous hydrochloric acid solution. Then, a necessary amount of an aqueous solutio of an aluminium salt is dropwise added thereto over a period of about one hour, whi the pH value of the reaction system is kept to fall within the range of from 5 to 6 wi o an alkaline aqueous solution such as an aqueous sodium hydroxide solution. After addition, the resulting slurry liquid is further stirred for 30 minutes or more with stil maintaining the temperature thereof as it is.

Fourth Step: Step of coating zinc oxide hydrate

25

The pigment-containing slurry liquid is, after the above-mentioned aluminium oxide hydrate coated step, adjusted to have a pH value of from 6 to 7 with, for example, a aqueous sodium hydroxide solution. Then, a necessary amount of an aqueous solu¬ tion of a zinc salt is dropwise added thereto over a period of about one hour, while

30 the pH of the reaction system is kept to fall within the range of from 6 to 7 with an alkaline aqueous solution such as an aqueous sodium hydroxide solution. After addi tion, the resulting slurry is stirred for 30 minutes and the pH value thereof is adjuste to be from 8 to 9 with an aqueous alkaline solution such as an aqueous sodium hy¬ droxide solution. Then, it is further stirred for 10 minutes or more with still maintai

35 ing the temperature thereof as it is.

Fifth Step: Drying Step

After the first to fourth steps, the product formed is taken out by filtration, washed with water and dried (typically at 80 to 150 °C, for 10 to 15 hours). Optionally, the product can be calcined at temperatures typically from about 700-900 °C, especially about 800 °C.

Especially preferred are the following specific methods of preparation.

Method A:

Step 1: omitted; a pre-fabricated mica particle coated with titaniu oxide and/or titanium oxide hydrate is used

Steps 2-4: as described above

Step 5: calcination step is omitted

Method B:

Step 1: uncoated mica is used as starting material which is coated with titanium oxide and/or titanium oxide hydrate as de¬ scribed above

Steps 2-4: as described above

Step 5: calcination step is performed, preferably at temperatures about 800 °C.

Both Methods A and B provide pigments according to the present invention with ex cellent anti-yellowing properties. Method B, however, is often preferred because it i advantageous from a technical and economical point of view.

The product as obtained by the above mentioned steps has a pertinent pearly luster and dispersibility. As a result of an anti-yellowing test applied thereto, it has been confirmed that the product has a far better anti-discoloring property than conven¬ tional pearly luster pigments.

The present invention will be explained in more detail by way of the following ex¬ amples, comparative examples and test examples, which, however, are not intende to restrict the scope of the present invention.

Example 1

800 g of pearly luster pigment particles comprising about 38 parts by weight of tita nium dioxide-coated mica and having a particle size of from 5 to 20 μm (Iriodin® 120, produced by Merck Japan) were suspended in 8 litres of water and heated up _j 0 75 °C with stirring. An aqueous sodium hydroxide solution was added to the slurr so that the pH value thereof was adjusted to be 9.3; and an aqueous 10 % solution 66 g of sodium silicate (3 parts by weight as Si0 ₂ , to 100 parts by weight of Iriodi 120) was dropwise added thereto over a period of about 1 hour, while the pH valu the slurry liquid was maintained to be 9.3 with an aqueous 3 % hydrochloric acid _j 5 solution. After all the aqueous sodium silicate solution was dropwise added theret the whole was stirred for 30 minutes at a temperature of 75 °C. Next, an aqueous 3 solution of 19 g of aluminium chloride hexahydrate A1C1 ₃ • 6 H ₂ O (one part by weight as AI2O3 to 100 party by weight of Iriodin® 120) was dropwise added ther over a period of about one hour, while the pH value of the slurry liquid was main-

20 tained to be 5.5 with an aqueous 5 % solution of sodium hydroxide. After all the aqueous uminium salt solution was dropwise added thereto, the whole was stirre for 30 minutes at 75 °C. Further, an aqueous 2 % solution of 13.4 g of zinc chlorid Znθ ₂ (one part by weight as ZnO to 100 parts by weight of Iriodin® 120) was dro wise added thereto over a period of about one hour, while the pH value of the slur

25 liquid was maintained to be 6.5 with an aqueous 5 % solution of sodium hydroxid After addition, the whole was continuously stirred for further 30 minutes at 75 °C, then an aqueous 5 % solution of sodium hydroxide was gradually dropwise added thereto so that the pH value of the slurry liquid was elevated up to 8. This was the continuously stirred for further 10 minutes at 75 °C. The solid product thus forme

30 was taken out by filtration, washed with water and dried at 130 °C for 12 hours. T was then sieved through a 250-mesh sieve. The pigment thus obtained was applied resins, which showed an excellent dispersing property.

35

Examples 2 to 5

The same process as in Example 1 was repeated, using 800 g of the same titanium oxide-coated pearly pigment, except that the amounts of the surface-treating agents applied to the pigment were varied to those indicated in Table 1 below. All the coat pigments thus obtained showed an excellent dispersing property when applied to resins.

Example 6

An aqueous 42 % solution of 438.6 g TiCLj was added dropwise within a period of about 1 hour at a temperature of 75 °C to an aqueous suspension of 800 g of uncoat mica particles (particle size 10-50 μm) at a pH of 2.2 which was largely kept const by simultaneous addition of an aqueous 32 % NaOH solution. After all the TiCL» solution was added dropwise thereto, the whole was stirred for 30 minutes at a temperature of 75 °C. The resulting intermediate pigment exhibits a Tiθ ₂ content o

29 % with respect to the mass of uncoated mica.

Then, an aqueous sodium hydroxide solution was added to the slurry liquid so that the pH value thereof was adjusted to be 9.3; and an aqueous 15 % solution of 35.4 of sodium silicate (2 parts by weight as Siθ , to 100 parts by weight of titan dioxid and/or oxide hydrate coated mica) was dropwise added thereto over a period of abo 1 hour, while the pH value of the slurry liquid was maintained to be 9.3 with an aqueous 20 % hydrochloric acid solution. After all the aqueous sodium silicate solution was dropwise added thereto, the whole was stirred for 30 minutes at a temperature of 75 °C. Next, an aqueous 6 % solution of 15 g of aluminium chlorid hexahydrate A1C1 ₃ ^• 6 H2O (one part by weight as AI ₂ O ₃ to 100 parts by weight of titan dioxide and/or oxide hydrate coated mica) was dropwise added thereto over a period of about one hour, while the pH value of the slurry liquid was maintained to be 5.5 with an aqueous 32 % solution of sodium hydroxide. After all the aqueous aluminium salt solution was dropwise added thereto, the whole was stirred for

30 minutes at 75 °C. Further, an aqueous 4 % solution of 10.65 g of zinc chloride ZnC (one part by weight as ZnO to 100 parts by weight of titan dioxide and/or

hydrate coated mica) was dropwise added thereto over a period of about one hour, while the pH value of the slurry liquid was maintained to be 6.5 with an aqueous 32 % solution of sodium hydroxide. After addition, the whole was continuously stirred for further 30 minutes at 75 °C, then an aqueous 32 % solution of sodium hydroxide was gradually dropwise added thereto so that the pH value of the slurry liquid was elevated up to 8. This was then continuously stirred for further 10 minut at 75 °C. The solid product thus formed was taken out by filtration, washed with water, dried at 130 °C for 12 hours and calcined at 800-900 °C for 0.5 hours. This was then sieved through a 325-mesh sieve. The pigment thus obtained was applied t resins, which showed an excellent dispersing property.

Example 7 to 8

The same process as in Example 6 was repeated, using 452 g of the same uncoated mica particles, except that the amounts of the surface-treating agents as applied to t pigment were varied to those indicated in Table 1 below. All the coated pigments thus obtained showed an excellent dispersing property when applied to resins.

Comparative Example 1

The same process as in Example 1 was repeated, using 800 g of the same titanium dioxide-coated pearly pigment, except that no zinc salt was added and that the amounts of the other surface-treating agents were varied to those indicated in Table below. When the coated pigment thus obtained was applied to resins, there was no problem on the dispersibility of the pigment, but with the lapse of time, yellowing o the resins was observed. As a result, the coated pigment (comparative sample) ob¬ tained herein was recognized to have a problem on the anti-discoloring property.

Comparative Example 2

The same process as in Example 1 was repeated, using 800 g of the same titanium dioxide-coated pearly pigment, except that no aluminium salt was added and that th amounts of the other surface-treating agents were varied to those indicated in Table below.

When the coated pigment thus obtained was applied to resins noticeable coagulat of the pigment grains was observed and the dispersibility of the pigment was not good.

Comparative Example 3

The same process as in Example 1 was repeated, using 800 g o the same titanium dioxide-coated pearly pigment, except that no silicate was added and that the amounts of the other surface-treating agents were varied to those indicated in Ta below.

When the coated pigment thus obtained was applied to resins, there was no probl on the dispersibility of the pigment, but with the lapse of time, the resins yellowe like the case of Comparative Example 1. As a result, the coated pigment (compar sample) obtained herein was recognized to have a problem on the anti-discolorin property.

Table 1 Surface-treatin A ent wt. ts.

The samples prepared above were tested in the manner mentioned below and the test results are shown in the following tables.

1 ) Formation of Test Pieces : One g of a sample to be tested was well blended with 0.1 g of an antioxidant

(BHT, Yoshinox, trade name by Yshitomi Pharmaceutical Co), and 98.9 g of HDPE (Diapolymer, Mitsubishi Polyethylene JxlO), and the resulting mixture was shaped by injection molding to obtain test pieces each having a size of 24.5 cm length x 7.3 cm width x 0.2 cm thickness.

2) Method of Testing Light Resistance

A photo-cabinet was used, which had one black lamp (20 W, produced by Nippo Co.) as a light source. The black lamp emits essentially ultraviolet rays. The test pieces prepared above were put in the photo-cabinet with a distance of about 20 cm from the light source, for 2 weeks, and the b value of them wa measured with a colorimeter (CR-200 Model, produced by Minolta Co.). The difference between the b values (Δb) of the test pieces before and after the tes was calculated out. The results obtained are shown in Table 2 below.

Table 2

Sample Δb

Iriodin® 120 (non-treated) 5.0

Example 1 0.3

Example 2 1.0

Example 3 1.1

Example 4 0.8

Example 5 0.6

Example 6 0.1

Example 7 0.1

Example 8 0.0

Comparative Example 1 2.4

) Method of Measuring Luster:

One g of a sample pigment to be tested was weighed in a beaker, and 9 g of ink medium (VS Medium, produced by Dai-Nippon Seika KK) was added thereto and fully stirred and blended to give a uniform mix. This was coate on a white-black calendered paper with a bar coater No. 20 and dried, and t

L value of the coated paper was measured with the same colorimeter as that mentioned above over the black background. The results obtained are show Table 3 below.

Table 3

Sample L value

Example 1 69.9

Example 2 69.5 Example 3 69.3

Example 4 69.8

Example 5 69.3

Comparative Example 1 68.7

As explained in detail in the above, the anti-disoloring pearly luster pigment of the present invention has excellent anti-discoloring property and dispersing property, it still maintains the intrinsic gloss of the titanium dioxide and/or oxide hydrate coated mica particles. Therefore, the pigment of the present invention is used as a pigment ingredient in plastic articles, inks, coating compositions, decorative board and others.

While the invention has been described in detail and with reference to specific em bodiments thereof, it will be apparent to one skilled in the art that various changes and modifications can be made therein without departing from the spirit and scope thereof.