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Title:
CATHODE CATALYTIC LAYER STRUCTURE FOR ENHANCING CATALYST DURABILITY AND PREPARATION METHOD THEREFOR
Document Type and Number:
WIPO Patent Application WO/2021/093466
Kind Code:
A1
Abstract:
The present invention relates to the technical field of fuel cells, and disclosed is a fuel cell cathode catalytic layer structure for enhancing catalyst durability. The structure comprises a first catalytic section, a second catalytic section and a third catalytic section arranged in order from a region close to the diffusion layer side to a region close to the proton exchange membrane side; the first catalytic section, the second catalytic section, and the third catalytic section are internally provided with pure platinum catalysts; platinum loadings of the pure platinum catalysts at the inner parts of the first catalytic section, the second catalytic section and the third catalytic section decrease in order; the average particle sizes of the pure platinum catalyst particles at the inner parts of the first catalytic section, the second catalytic section, and the third catalytic section increase in order; the pure platinum catalyst that has a large diameter is more resistant to corrosion, and the pure platinum catalyst that has small diameter improves the initial performance of a fuel cell, which facilitates reducing the specific surface area loss of the catalyst under potential sweeping; and the platinum specific surface area and platinum mass distribution of an attenuated cathode catalyst are more uniform, which facilitates reducing the attenuated oxygen and proton mass transfer loss, thereby improving the attenuated fuel cell performance and improving the durability.

Inventors:
ZHANG JUNLIANG (CN)
ZHENG ZHIFENG (CN)
ZHU FENGJUAN (CN)
CHENG XIAOJING (CN)
WEI GUANGHUA (CN)
YANG FAN (CN)
XIA GUOFENG (CN)
Application Number:
PCT/CN2020/117323
Publication Date:
May 20, 2021
Filing Date:
September 24, 2020
Export Citation:
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Assignee:
UNIV SHANGHAI JIAOTONG (CN)
International Classes:
H01M4/86
Foreign References:
CN110993960A2020-04-10
CN110289423A2019-09-27
CN104247114A2014-12-24
CN103165915A2013-06-19
CN107146891A2017-09-08
KR20060135138A2006-12-29
Other References:
BARICCI ANDREA, MATTEO BONANOMI, HAORAN YU, LAURE GUETAZ, RADENKA MARIC, ANDREA CASALEGNO: "Modelling analysis of low platinum polymer fuel cell degradation under voltage cycling: Gradient catalyst layers with improved durability", JOURNAL OF POWER SOURCES, vol. 405, 14 October 2018 (2018-10-14), pages 89 - 100, XP055812791, DOI: 10.1016/j.jpowsour.2018.09.092
YU HAORAN; BARICCI ANDREA; BISELLO ANDREA; CASALEGNO ANDREA; GUETAZ LAURE; BONVILLE LEONARD; MARIC RADENKA: "Strategies to mitigate Pt dissolution in low Pt loading proton exchange membrane fuel cell: I. A gradient Pt particle size design", ELECTROCHIMICA ACTA, ELSEVIER, AMSTERDAM, NL, vol. 247, 20 July 2017 (2017-07-20), AMSTERDAM, NL, pages 1155 - 1168, XP085183443, ISSN: 0013-4686, DOI: 10.1016/j.electacta.2017.07.093
SHAHGALDI SAMANEH; OZDEN ADNAN; LI XIANGUO; HAMDULLAHPUR FERIDUN: "Cathode catalyst layer design with gradients of ionomer distribution for proton exchange membrane fuel cells", ENERGY CONVERSION AND MANAGEMENT, ELSEVIER SCIENCE PUBLISHERS, OXFORD., GB, vol. 171, 28 June 2018 (2018-06-28), GB, pages 1476 - 1486, XP085420194, ISSN: 0196-8904, DOI: 10.1016/j.enconman.2018.06.078
Attorney, Agent or Firm:
DUAN & DUAN LAW FIRM (CN)
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