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Title:
CHLOROFLUOROCARBON-RESISTANT RESIN COMPOSITION AND INNER BOX OF REFRIGERATOR MADE FROM THE COMPOSITION
Document Type and Number:
WIPO Patent Application WO/1997/025376
Kind Code:
A1
Abstract:
A chlorofluorocarbon-resistant resin composition comprising a cluster-like agglomerate graft polymer (Y) which is formed by the agglomeration of a small-particle-size graft copolymer (y) prepared by polymerizing 60 to 20 wt.% of a monomer mixture comprising 30 to 45 wt.% of a vinyl cyanide compound and 70 to 55 wt.% of an aromatic vinyl compound in the presence of 40 to 80 wt.% of a rubbery polymer having a weight-mean particle diameter of 0.05 to 0.2 'mu'm and having a graft ratio of 10 to 40 wt.% and has a weight-mean particle diameter of 0.8 to 2.0 'mu'm and a copolymer (Z) prepared by polymerizing 35 to 45 wt.% of a vinyl cyanide compound with 65 to 55 wt.% of an aromatic vinyl compound and having an intrinsic viscosity of 0.6 to 0.9, with the content of the rubbery polymer being 15 to 25 wt.%. This composition is superior to the prior-art resin compositions in chlorofluorocarbon resistance.

Inventors:
NAKAJIMA OSAMU (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
Application Number:
PCT/JP1996/000005
Publication Date:
July 17, 1997
Filing Date:
January 05, 1996
Export Citation:
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Assignee:
SUMIKA A & L INC (JP)
NAKAJIMA OSAMU (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
International Classes:
C08F255/02; C08F279/04; C08L25/12; C08L51/04; C08L55/02; F25D23/06; (IPC1-7): C08L25/12; C08F279/04; C08L51/04; C08L55/02; F25D23/06
Foreign References:
JPH06179796A1994-06-28
JPH02175745A1990-07-09
JPH02117942A1990-05-02
JPH05155949A1993-06-22
JPH06228409A1994-08-16
JPS62167348A1987-07-23
JPH03124757A1991-05-28
JPH02284906A1990-11-22
JPH0517541A1993-01-26
JPH0517658A1993-01-26
JPH0517540A1993-01-26
Other References:
See also references of EP 0872518A4
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