Title:
CHLOROFLUOROCARBON-RESISTANT RESIN COMPOSITION AND INNER BOX OF REFRIGERATOR MADE FROM THE COMPOSITION
Document Type and Number:
WIPO Patent Application WO/1997/025376
Kind Code:
A1
Abstract:
A chlorofluorocarbon-resistant resin composition comprising a cluster-like agglomerate graft polymer (Y) which is formed by the agglomeration of a small-particle-size graft copolymer (y) prepared by polymerizing 60 to 20 wt.% of a monomer mixture comprising 30 to 45 wt.% of a vinyl cyanide compound and 70 to 55 wt.% of an aromatic vinyl compound in the presence of 40 to 80 wt.% of a rubbery polymer having a weight-mean particle diameter of 0.05 to 0.2 'mu'm and having a graft ratio of 10 to 40 wt.% and has a weight-mean particle diameter of 0.8 to 2.0 'mu'm and a copolymer (Z) prepared by polymerizing 35 to 45 wt.% of a vinyl cyanide compound with 65 to 55 wt.% of an aromatic vinyl compound and having an intrinsic viscosity of 0.6 to 0.9, with the content of the rubbery polymer being 15 to 25 wt.%. This composition is superior to the prior-art resin compositions in chlorofluorocarbon resistance.
Inventors:
NAKAJIMA OSAMU (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
Application Number:
PCT/JP1996/000005
Publication Date:
July 17, 1997
Filing Date:
January 05, 1996
Export Citation:
Assignee:
SUMIKA A & L INC (JP)
NAKAJIMA OSAMU (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
NAKAJIMA OSAMU (JP)
HOSHIKAWA MICHIO (JP)
YAMAMOTO TETSUYA (JP)
AOKI HIROMICHI (JP)
KOJIMA HIROSHI (JP)
International Classes:
C08F255/02; C08F279/04; C08L25/12; C08L51/04; C08L55/02; F25D23/06; (IPC1-7): C08L25/12; C08F279/04; C08L51/04; C08L55/02; F25D23/06
Foreign References:
JPH06179796A | 1994-06-28 | |||
JPH02175745A | 1990-07-09 | |||
JPH02117942A | 1990-05-02 | |||
JPH05155949A | 1993-06-22 | |||
JPH06228409A | 1994-08-16 | |||
JPS62167348A | 1987-07-23 | |||
JPH03124757A | 1991-05-28 | |||
JPH02284906A | 1990-11-22 | |||
JPH0517541A | 1993-01-26 | |||
JPH0517658A | 1993-01-26 | |||
JPH0517540A | 1993-01-26 |
Other References:
See also references of EP 0872518A4
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