Title:
A-D-D'-A ASYMMETRIC ORGANIC PHOTOVOLTAIC RECEPTOR MATERIAL AND APPLICATION THEREOF
Document Type and Number:
WIPO Patent Application WO/2023/000835
Kind Code:
A1
Abstract:
The present invention relates to the technical field of organic photovoltaics, and in particular, to an A-D-D'-A asymmetric organic photovoltaic receptor material and an application thereof. Double electron donor (D-D') units of alkoxy indenothiophene and cyclopentadiene dithiophene are used for constructing a framework containing a non-covalent bond configuration lock together, and the tail end of the framework is modified by 3-(dicyanomethylene) indene-1-ketone substituted with fluorine and chlorine atoms. A receptor containing only a simple fused ring has many advantages such as a coplanar framework, a low-energy disorder degree, and a J-aggregation tendency; the optical band gap of such an asymmetric micromolecule receptor can be controlled and adjusted within a range of 1.30-1.45 eV; and the asymmetric micromolecule receptor can be combined with most of donor materials to construct an efficient bulk heterojunction binary organic solar cell (OSC). When the donor material is polymer PM6, the energy conversion efficiency of a binary OSCs device is as high as 13.67%, the open-circuit voltage is 0.85 eV, and Eloss is only 0.50 V.
Inventors:
ZHU WEIGUO (CN)
ZHU JIANING (CN)
TAN HUA (CN)
SHAO ZHENGYONG (CN)
ZHU MENGBING (CN)
WANG JUNFENG (CN)
ZHU JIANING (CN)
TAN HUA (CN)
SHAO ZHENGYONG (CN)
ZHU MENGBING (CN)
WANG JUNFENG (CN)
Application Number:
PCT/CN2022/096517
Publication Date:
January 26, 2023
Filing Date:
June 01, 2022
Export Citation:
Assignee:
UNIV CHANGZHOU (CN)
International Classes:
C07D495/04
Foreign References:
| CN113563362A | 2021-10-29 | |||
| CN111039961A | 2020-04-21 | |||
| CN110218216A | 2019-09-10 | |||
| CN109081825A | 2018-12-25 |
Other References:
ZHU JIANING; SHAO ZHENGYONG; WANG JUNFENG; SUN DAWEI; ZHU MENGBING; SONG XIN; TAN HUA; ZHU WEIGUO: "Non-fused-ring asymmetrical electron acceptors assembled by multi-functional alkoxy indenothiophene unit to construct efficient organic solar cells", CHEMICAL ENGENEERING JOURNAL, ELSEVIER, AMSTERDAM, NL, vol. 444, 28 April 2022 (2022-04-28), AMSTERDAM, NL , XP087056112, ISSN: 1385-8947, DOI: 10.1016/j.cej.2022.136509
CHEN SHANSHAN, LEE SANG MYEON, XU JIANQIU, LEE JUNGHO, LEE KYU CHEOL, HOU TIANYU, YANG YANKANG, JEONG MINGYU, LEE BYONGKYU, CHO YO: "Ultrafast Channel II process induced by a 3-D texture with enhanced acceptor order ranges for high-performance non-fullerene polymer solar cells", ENERGY & ENVIRONMENTAL SCIENCE, RSC PUBL., CAMBRIDGE, vol. 11, no. 9, 1 January 2018 (2018-01-01), Cambridge , pages 2569 - 2580, XP093026270, ISSN: 1754-5692, DOI: 10.1039/C8EE01546E
KANG, ZHENJING ET AL.: "Push−Pull Type Non-Fullerene Acceptors for Polymer Solar Cells:Effect of the Donor Core", ACS APPLIED MATERIALS & INTERFACES, vol. 9, no. 29, 5 July 2017 (2017-07-05), pages 24771 - 24777, XP055581129, ISSN: 1944-8244, DOI: 10.1021/acsami.7b05417
CHEN SHANSHAN, LEE SANG MYEON, XU JIANQIU, LEE JUNGHO, LEE KYU CHEOL, HOU TIANYU, YANG YANKANG, JEONG MINGYU, LEE BYONGKYU, CHO YO: "Ultrafast Channel II process induced by a 3-D texture with enhanced acceptor order ranges for high-performance non-fullerene polymer solar cells", ENERGY & ENVIRONMENTAL SCIENCE, RSC PUBL., CAMBRIDGE, vol. 11, no. 9, 1 January 2018 (2018-01-01), Cambridge , pages 2569 - 2580, XP093026270, ISSN: 1754-5692, DOI: 10.1039/C8EE01546E
KANG, ZHENJING ET AL.: "Push−Pull Type Non-Fullerene Acceptors for Polymer Solar Cells:Effect of the Donor Core", ACS APPLIED MATERIALS & INTERFACES, vol. 9, no. 29, 5 July 2017 (2017-07-05), pages 24771 - 24777, XP055581129, ISSN: 1944-8244, DOI: 10.1021/acsami.7b05417
Attorney, Agent or Firm:
CHANGZHOU INNOVATION PATENT AGENCY (CN)
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