Title:
DECALIN DERIVATIVE AND METHOD FOR PRODUCING SAME
Document Type and Number:
WIPO Patent Application WO/2016/063957
Kind Code:
A1
Abstract:
Provided are: a decalin derivative having a glycidyloxy group or an allyloxy group; and a method for producing the decalin derivative.
A decalin derivative represented by formula (1) is produced by: a method comprising reacting a hydroxydecalin compound represented by formula (2) with an allyl halide in the presence of a phase transfer catalyst and a basic substance to prepare an (allyloxy)decalin derivative represented by formula (1-1); or a method comprising reacting the (allyloxy)decalin derivative, hydrogen peroxide and a nitrile compound represented by formula R1-C≡N (wherein R1 represents a C1-6 alkyl group or a phenyl group which may have a substituent) together while maintaining the pH value of the reaction solution at 9 to 11 using a basic substance to prepare a (glycidyloxy)decalin derivative represented by formula (1-2).
(In the formulae, R represents a vinyl group or an epoxy group; and n represents 1 or 2.)
The decalin derivative represented by formula (1) is useful as a raw material or an intermediate for use in various organic synthetic chemical fields, an epoxy compound or a monomer for an epoxy compound.
Inventors:
MINEYAMA KENJI (JP)
IIDA TAKUYA (JP)
NAKAMURA TAKUMA (JP)
IIDA TAKUYA (JP)
NAKAMURA TAKUMA (JP)
Application Number:
PCT/JP2015/079851
Publication Date:
April 28, 2016
Filing Date:
October 22, 2015
Export Citation:
Assignee:
SUGAI CHEMICAL IND CO LTD (JP)
International Classes:
C07C43/188; C07C41/01; C07D301/12; C07D303/30
Domestic Patent References:
WO2008069973A2 | 2008-06-12 | |||
WO2015080059A1 | 2015-06-04 | |||
WO2010110151A1 | 2010-09-30 | |||
WO2013115360A1 | 2013-08-08 |
Foreign References:
JP2007091841A | 2007-04-12 | |||
JP2015178472A | 2015-10-08 | |||
JP2000072767A | 2000-03-07 | |||
JPS5781418A | 1982-05-21 | |||
JP2009510182A | 2009-03-12 | |||
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JP2013112649A | 2013-06-10 | |||
JP2008239579A | 2008-10-09 | |||
JP2012092247A | 2012-05-17 |
Other References:
SHIBUTANI YASUHIKO ET AL.: "Synthesis and cation- extraction study of chromogenic 14-crown-4 derivatives for spectrophotometric determination of lithium", ANALYTICA CHIMICA ACTA, vol. 375, 1998, pages 81 - 88, ISSN: 0003-2670
Attorney, Agent or Firm:
KUWATA Mitsuo et al. (JP)
Atsuo Kuwata (JP)
Atsuo Kuwata (JP)
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