Blends of styrene-butadiene diblock and styrene-butadiene-styrene tri-block interpolymers can be used in a variety of applications. In an adhesive composition, the diblock polymer provides tack strength, while the triblock polymer provides the composition with its elastomeric properties.

One process for preparing such composition is to physically blend independently prepared triblock and the diblock copolymers. However, such a process requires a large blending capacity and is therefore undesired. Moreover, separate preparation of the diblock and triblock polymers makes control of the final composition of the mixture extremely difficult. Better adhesive properties generally result from having identical molecular weights of the styrene blocks in the diblock and triblock polymers, and blending makes achieving an optimal ratio of component polymers difficult.

Another method of forming diblock/triblock compositions involves partial coupling of live diblock species. Suitable coupling agents include reactive halogen compounds such as, for example, dimethyl dichlorosilane, SiCl4, CH2Br2, PCI3, and divinyl benzene. This method can achieve matching of the molecular weights of the styrene blocks in the diblock and triblock polymers, if a solvent in which the polystyrene is completely soluble is used. If the polystyrene is insoluble in the solvent (for example, hexane), the polystyrene maximum molecular weight is limited. For acceptable adhesive properties, exceeding this maximum molecular weight is desirable.

Yet another method of forming diblock/triblock compositions is to use a multiple catalyst charge and staggered addition of monomers with deactivation of a portion of the growing polymer chains before or during sub- sequent monomer charge (s). For example, a high diblock TPE can be formed

by allowing Li to initiate styrene polymerization, addition of further catalyst/initiator and butadiene, and a further charge of styrene is added.

The resulting compositions exhibit poor adhesion to stainless steel and polypropylene and have low cohesive tensile strength, however.

SUMMARY OF THE INVENTION Briefly, the present invention provides a process for preparing a polymer composition which includes both a triblock and diblock interpolymers. The process includes polymerizing in an inert hydrocarbon solvent vinyl aromatic monomer in the presence of an anionic catalyst system (initiator) until substantially complete conversion to a living vinyl aromatic polymer has occurred. A conjugated diene is added to copolymerize with the living vinyl aromatic polymer. A first terminating agent is added in sufficient amount to terminate at least a portion, but less than all, of the copolymer, thereby forming the diblock interpolymer. A second portion of vinyl aromatic monomer is added, then a second terminating agent, thereby forming the triblock interpolymer. Optionally, at least one of the terminating agents can be a functional terminating agent.

In another aspect, a block copolymer composition is provided. The composition includes a first block interpolymer of the general formula A1B1A2 and a second block interpolymer of the general formula AIBI. A, and 2 independently represent poly (vinyl aromatic) block and B1 represents a poly (conjugated diene) block. At least one of the block interpolymers is terminated by a functional group selected from hydroxyl, alkoxysilane, amine, and carboxyl.

In another aspect, an adhesive composition is provided. The adhesive composition includes about 15 to 40% (by wt.) of the just described polymer composition, about 40 to 70% (by wt.) of a compatible tackifying resin, and about 5 to 30% (by wt.) of a plasticizer.

In another aspect, a process is provided for preparing a diblock/ triblock polymer composition in which at least one of the diblock and triblock

polymers is functionalized. The process includes polymerizing one of a vinyl aromatic monomer and a conjugated diene monomer in an inert hydrocarbon solvent in the presence of a first portion of an anionic catalyst system until substantially complete conversion to a first living polymer has occurred. The first living polymer contributes first blocks of both a triblock interpolymer and a diblock interpolymer. The first block of each of the triblock and diblock interpolymers includes either a first vinyl aromatic polymer or a first diene polymer. The other of the vinyl aromatic monomer and the conjugated diene monomer is added, allowing formation of a midblock of the triblock interpol- mer and a second block of the diblock interpolymer. At least one of a func- tional terminating agent and a protic terminating agent is added in a sufficient amount to terminate less than all of the polymer chains. A second portion of the same type of monomer as was used to form the first blocks is added followed by at least the other of the functional terminating agent and the protic terminating agent, forming the triblock interpolymer and the diblock interpolymer.

The following definitions apply hereinthroughout unless a contrary intention is expressly indicated: "interpolymer"means a polymer that includes mer units derived from two or more different monomers; and "living polymer"means a polymer prepared by anionic polymerization that has active terminals which enable the polymer to undergo further polymerization or to be terminated through a suitable terminating process.

DETAILED DESCRIPTION OF PREFERRED EMBODIMENTS The process of the present invention includes the sequential steps of 1) polymerizing a vinyl aromatic monomer in an inert hydrocarbon solvent in the presence of a suitable catalyst or initiator until substantially complete conversion to a living vinyl aromatic polymer ;

2) adding a conjugated diene and allowing it to polymerize until substantially complete conversion to a living block copolymer ; 3) adding a terminating agent to terminate a portion of the living polymers ; 4) adding a second portion of a vinyl aromatic monomer and allowing substantially all of it to polymerize; and 5) adding a terminating agent to terminate the remainder of the living polymers.

("Substantially complete conversion"means that the polymerization is allowed to proceed until at least 90%, more preferably at least 95%, and most preferably at least 98%, of the initially charged monomer has been polymerized. As a result, the blocks are relatively free of monomer (s) other than the one (s) just charged.) The terminating agent used in step 3 is preferably a functional terminating agent, and the terminating agent used in step 5 is preferably a protic terminating agent, although a functional terminating agent or any other combination of the two terminating agents may be used in steps 3 and 5. The functional terminating agent includes a functional group (i. e, a group other than H) selected to add functionality to the resulting diblock and triblock interpolymers. The protic terminator removes residual catalyst or initiator (Li, in the case of an organolithium system) from the interpolymers formed, and thereby prevents further reaction of the copolymers. Where both a functional terminating agent and a protic terminating agent are used, the protic terminating agent preferably is used after the functional terminating agent.

After the polymerization has been terminated, the product can be isolated by, e. g., drum drying, steam stripping, or flash evaporation.

The process results in a composition including a triblock copolymer of the general formula A1B1A2 and a diblock copolymer of the general formula AIBI where A1 represents a poly (vinyl aromatic block) formed in step 1; A2 represents a poly (vinyl aromatic block) formed in step 3; and B1 represents

a poly (conjugated diene block) formed in step 2. A, and A2 may be the same or different.

The above described process (with a functional terminating agent, T- X, used in step 3 and a protic terminating agent, P-H, used in step 5) may be illustrated by the following reaction scheme.

Step Add Products 1 A + Li As-Li 2 B Au-Li 3 T-X A1-B1-Li + A,-BI-T + XLi 4 A A1-B1-A2-Li +A1-B1-T 5 P-H A1-BrArH +ArB1-T In this reaction scheme, only a portion of the polymer chains are terminated with the terminating agent T-X, while the remainder of the chains are terminated by the protic terminating agent P-H.

The conjugated diene blocks B1 in the diblock and triblock are substantially identical. By"substantially identical"is meant that the ratio of the molar weights of the two blocks is preferably from about 0.9 to 1.1, more preferably from about 0.095 to 1.05, and most preferably is equal to 1. The approximately equal B block sizes in the diblock and triblock interpolymers is in contrast to other methods of preparing diblock/triblock mixtures, which often result in the midblock in the triblock having a molecular weight of approximately twice that of the corresponding block in the diblock.

Similarly, the vinyl aromatic blocks A, in the diblock and triblock are also substantially identical, i. e., the ratio of the molar weights of the two blocks is preferably from about 0.9 to 1.1, more preferably from about 0.095 to 1.05, and most preferably is equal to 1. By control of the two vinyl aromatic monomer additions, the vinyl aromatic blocks A, and A2 in the triblock may also be substantially identical, i. e., the ratio of the molar weights of the two blocks can be from about 0.9 to 1.1, more preferably from about 0.095 to 1.05, and most preferably is equal to 1.

The vinyl aromatic monomer can be one or more of styrene, a-methyl styrene, a-methyl styrene, p-methyl styrene, p-tert-butyl styrene, and 1,3- dimethyl styrene. Styrene is preferred. A, and Aa may be derived from randomly copolymerized styrene and a-methyl styrene, although both A blocks preferably are homopolymer blocks.

The conjugated diene preferably contains from 4 to 8 carbon atoms such as 1,3-butadiene, isoprene, 2,3-dimethyl-1,3-butadiene, 1,3- pentadiene, 1,3-hexadiene, or mixtures thereof, of which 1,3-butadiene and/or isoprene are preferred. For example, B, may be derived from randomly copolymerized butadiene and isoprene, or one or more blocks of each of butadiene and isoprene although the B, blocks in the diblock and triblock preferably are homopolymer blocks.

Examples of suitable inert hydrocarbon solvents include linear or branched aliphatic hydrocarbons, such as n-hexane and isopentane as well as cyclic aliphatic hydrocarbons such as cyclohexane, cycloheptane, and cyclopentane, alone or in a combination of two or more such solvents.

Hexane, optionally with cyclohexane, is particularly preferred.

The functional terminating agent is selected so as to provide functionality, i. e., impart desirable properties to the resultant interpolymer composition. The interpolymer composition particularly is suited for use as an adhesive, alone or with other components of an adhesive composition.

For these uses, functional groups which add desirable adhesive properties are selected. The properties are chosen dependent on the specific end use. For example, one functional group may improve peel adhesion to stainless steel, while another to polypropylene or polyethylene. (In this respect, terminating agents which provide hydroxyl functional groups improve adherence to polyethylene and polypropylene.) On addition of the functional terminator, the living polymer anions on the diblock interpolymers are provided with a functional group. Adding a protic terminator in step 5 terminates the triblock with an H group, although it will be appreciated that functional groups may be placed on both the diblock

and triblock, or on the triblock alone, by changing the terminating agents added. For example, steps 3 and 5 may separately include any one of adding a functional terminating agent; adding a protic terminating agent; adding a functional terminating agent followed by a protic terminating agent; or adding a protic terminating agent, followed by a functional terminating agent.

Use of a functional terminating agent to functionally terminate at least a portion of the diblock and/or triblock interpolymers in at least one of steps 3 and 5 is preferred. Functional termination of the diblock interpolymer (s) is most preferred.

Exemplary functional terminators are shown in Table 1, accompanied by the functional group provided in the diblock and triblock polymers.

Table 1 Functional Terminator Functional Group 1. Monofunctional epoxy compounds, such Hydroxyl,-OH as cyclohexene oxide 2. Alkoxysilanes such as tetraethoxysilane Alkoxysilane,-Si (OAlk) 3 Si (OEt) 4 such as ethoxysilane 3. Imines, particularly condensation Amine,-NH (R) products of benzaldehydes and amines such as Schiff Bases, e. g., Dimethyl- aminobenzilidene butylamine 4. C02 Carboxyl,-COOH The protic terminating agent can be any one or more commonly known active hydrogen compounds such as water (e. g., in the form of steam); alcohols such as methanol, ethanol, and isopropanol ; phenols ; and carboxylic acids such as ethyl hexanoic acid.

The functional terminating agent is added in a sufficient quantity so as to terminate only a portion of the interpolymer chains (i. e., in less than a stoichiometric amount). For example, 25%, 50%, or 80% of the interpolymer

chains can be terminated with the functional group in step 3, while the remainder can be protically terminated in step 5. In this way, the percentage of functionally terminated interpolymer chains can be selected to provide optimal properties of the composition, according to its intended use.

Additionally, the ratio of diblock to triblock interpolymers also is determined by the amount of terminating agent added in step 3.

The polymerization process is one which yields a living polymer after steps 1-4. The reactive end group typically is negatively charged and forms an ionic bond (or other ionic association) with a positively charged species, such as a metal cation. A variety of polymerization catalysts (or initiators) are suited to catalyzing steps 1-4, and forming a living polymer. Preferred catalysts or initiators are organic alkali metal compounds, particularly organolithium catalysts. The organolithium catalyst may be any organolithium compound that acts as an initiator having the general formula RLi, where R is selected fromCi-C2o alkyls, cycloalkyls, alkenyls, aryls, and aralkyls. Exemplary R groups include n-butyl, sec-butyl, methyl, ethyl, isopropyl, cyclohexyl, allyl, vinyl, phenyl, benzyl, and the like. Suitable organic compounds of Li include organolithium or Li salts of an organic acid such as alkyllithium compounds, Li salts of alcohols, Li salts of glycol ethers, Li salts of alcohols, phenols, thioalcohols, and thiophenols, Li salts of dialkylaminoethanol, Li salts of secondary amines, Li salts of cyclic imines, and the like. A preferred class of organolithium compounds is the alkyllithium compounds, wherein the alkyl group may be a linear alkyl or cycloalkyl group. Preferred organic compounds of Li include 2-610 alkyllithiums such as methyl lithium, ethyl lithium, n-propyl lithium, n-butyl lithium, sec-butyl lithium, isoamyllithium, and the like, alone or in combination. Preferred alkyllithium compounds are n-butyl lithium and sec- butyl lithium, with the latter being particularly preferred. The anionic initiator may be a combination of two or more initiators.

Other so-called living catalysts (anionic catalyst systems) may be employed in addition to, or in place of the organolithium catalyst. These

include organic salts or complexes of rare earth (lanthanum series) metals, organomagnesium compounds, organoaluminum compounds, organozinc compounds, and organic compounds of barium or strontium. Suitable catalytic systems include : I. (a) a salt or a complex of a lanthanide series metal ; and (b) an organomagnesium compound. ii. (a) a salt or a complex of a lanthanide series metal ; (b) an organomagnesium compound; and (c) an organic compound of Li.

I11. (a) an organomagnesium compound; (b) an organic compound of Li; and (c) an organic compound of Ba or Sr.

IV. (a) an organomagnesium compound ; (b) an organic compound of Li; (c) an organic compound of Ba or Sr; and (d) an organoaluminum or organozinc compound.

The lanthanide series metal may be any rare earth element of those having an atomic number of 57 (La) to 71 (Lu). However, the polymerization activity of certain of these elements, e. g., Sm, in previously described cata- lysts is low. Therefore, a compound of Ce, Pr, Nd, Gd, Tb, or Dy is preferred. A mixture of two or more rare earth elements may be used. A compound of Nd or"didymium" (which is a mixture of rare earth elements containing approximately 72% Nd, 20% La, and 8% Pr) is particularly preferred.

Examples of compounds suitable as the salt or a complex of a lanthanum metal are didymium versatate (derived from VersaticT""acid, a synthetic acid composed of a mixture of highly branched isomers of C10 monocarboxylic acids, sold by Shell Chemicals), Nd versatate, and Pr (2,2,6,6-tetramethyl-3,5-heptane dione). Didymium and Nd versatate are preferred on the grounds of ready solubility, ease of preparation, and stability.

Other lanthanides useful as the salt or a complex of a lanthanum metal are organic acid salts of lanthanum or organic phosphoric acid salts of Ce. The organic acid salt of La or organic phosphoric acid salt of Ce can readily be obtained, for example, by making an alkali metal salt of an organic acid to react with a chloride of La or Ce in water or an organic solvent, such as an alcohol, ketone, or the like. The organic acid salt of La or organic phosphoric acid salt of cerium may contain inorganic salts or La or Ce or organic acids as impurities in small amounts.

Exemplary organic acids that may be used to form the lanthanide salt/complex include organic acid compounds, including compounds of alcohols, thioalcohols, phenols and thiols, such as methyl alcohol, ethyl alcohol, and propyl alcohol, isopropyl alcohol, and ter-butyl alcohol ; carboxylic acids or sulfur analogs, such as isovaleric acid, caprylic acid, octanoic acid, lauric acid, myristic acid, palmitic acid, stearic acid, oleic acid, linoleic acid, cyclopentanecarboxylic acid, naphthenic acid, ethylhexanoic acid, pivalic acid; alkyl aryl sulfonic acids, such as dodecylbenzenesulfonic acid, tetradecyl benzenesulfonic acid, hexadecyl benzenesulfònic acid, octadecylbenzenesulfonic acid, dibutyl naphthalenesulfonic acid, n-hexyl- naphthalenesulfonic acid, and dibutylphenyl sulfonic acid; mono-alkyl esters of H2SO4 such as sulfuric acid mono-ester of lauryl alcohol, sulfuric acid mono-ester of oleyl alcohol, and sulfuric alcohol acid mono-ester of stearyl alcohol ; phosphate diesters of ethylene oxide adduct of alcohol or phenol, such as phosphate diester of ethylene oxide adduct of dodecyl alcohol, or of octyl alcohol ; phosphite diesters, such as phosphite diester of ethylene oxide adduct of dodecyl alcohol or of stearyl alcohol ; pentavalent organic phosphoric acid compounds such as dibutyl phosphate and dipentyl phosphate; and trivalent phosphorous acids such as bis (2-ethylhexyl) phosphite, bis (1-methylheptyl) phosphite, and bis (2-ethylhexyl) phosphinous acid.

Exemplary organomagnesium compounds are of the general formula MgR1R2 where R1 and R2 are aliphatic or aromatic hydrocarbon groups such

as alkyl, cycloalkyl, aryl, aralkyl, allyl, or cyclodiene groups, which may be the same or different. Examples include diethylmagnesium, di-n-propyl- magnesium, di-isopropylmagnesium, and the like, alone or in combination, where dibutyl magnesium is preferred.

Exemplary Ba or Sr organic compounds include Ba or Sr salts of aliphatic or aromatic groups, such as salts of alcohols, phenols, thioalcohols, thiophenols, carboxylic acids or sulfur analogs, glycol ethers, dialkylaminoalcohols, diarylaminoalcohols, secondary amines, cyclic imines, sulfonic acids, and sulfate esters either alone or in combination. Examples include salts of ethyl alcohol, n-propyl alcohol ; salts of ethanethiol, 1- butanethiol, thiophenol, cyclohexanethiol, and 2-naphthalenethiol ; salts of isovaleric acid, caprilic acid, lauric acid, myristic acid, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, dimethylaminoethanol, diethylaminoethanol, di-n-propylaminoethanol dimethylamine, diethylamine, ethyleneimine, triethyleneimine, pyrrolidine, piperidine, hexamethylene imine, butanesulfonic acid, hexanesulfonic acid, decanesulfonic acid; sulfate esters of lauryl alcohol, oleyl alcohol, stearyl alcohol, and the like.

Exemplary organoaluminum compounds are of the general formula AIR3R4R5 3, 5 independently are selected from H, aliphatic hydrocarbon groups, and aromatic hydrocarbon groups, with the proviso that all cannot be H. Examples include triethyl aluminum, tri- isobutylaluminum, tri-n-propylaluminum, tri-n-hexylaluminum, diethyl aluminum monohydride, and the like.

Suitable organozinc compounds are of the general formula R-Zn-R, where R6 and R7 independently are selected from H, aliphatic hydrocarbon groups, or aromatic hydrocarbon groups, with the proviso that all cannot be H. Examples include diethyl zinc, di-n-propyl zinc, di-iso-amyl zinc, di- isobutyl zinc, and the like.

If desired, the polymerization may be carried out in the presence of a polar modifier, such as a Lewis base, e. g., THF. Examples of other polar compounds are ethers, such as dimethyl ether, diethyl ether, diphenyl ether,

dibenzyl ether, and anisole ; amines, such as trimethylamine, triethylamine, pyridine, and tetramethyl ethylene diamine; thioethers, such as thiophene; and polyethers such as 1,2-dimethoxy ethane, glyme, and diglyme.

The polymerization reactions may be carried out at equal or different temperatures within the range of from about-10° to 150°C, preferably 10° to 110°C. The reaction pressure is not critical but should be sufficient to maintain the reaction mixture in the liquid phase. In step 1 of the reaction scheme, a reactor capable of mixing and heating or cooling is charged with a solvent, such as cyclohexane, the first monomer, such as styrene, and sufficient organolithium catalyst (such as an organolithium catalyst) to generate poly (vinyl aromatic) blocks of a desired molecular weight, preferably 5,000 to 21,000 weight average molecular weight (Mw). A polar modifier, such as THF, is optionally added at this stage to improve uniformity of polymer chain length and/or allow a lower reaction temperature. The styrene may be pre-blended with a portion of the solvent to aid mixing.

The reactor then can be heated to an appropriate temperature, preferably about 20° to 65°C. Once the monomers have been (substantially) polymerized, the mixture is preferably cooled and, in step 2, the second monomer (e. g., butadiene) is charged. As with the styrene, the butadiene may be pre-blended with solvent. The temperature is then raised to about 55° to 100°C and the polymerization allowed to proceed until substantially all the butadiene has polymerized onto the living styrene polymers.

After the terminating agent has been added, in step 4 a further addition of vinyl aromatic monomer is added and the reactor is heated to an appropriate temperature, preferably about 55° to 100°C. The polymerization is allowed to proceed until substantially all the styrene has polymerized with the remaining living styrene-butadiene interpolymers. No further addition of catalyst is needed in this step, unless it is desired to continue the reaction scheme to form a mixture of diblock/triblock and tetrablock (or more) interpolymers. Further monomer additions can be performed, if desired, to

produce multiblock polymers, with or without additional charges of catalyst.

For diblock/triblock compositions, however, the reaction is preferably quenched in step 5 by addition of a protic terminator. Alternatively, a functional terminator may be added at this stage to functionally terminate at least a portion of the living triblock interpolymers. In this case, step 5 preferably also includes addition of a protic terminator following the step of functional termination of a portion of the triblock polymers.

Further steps may be included, such as the addition of an antioxidant or stabilizer to the composition. Exemplary stabilizers or antioxidants include high molecular weight hindered phenols, such as S-and P- containing phenols. Representative hindered phenols include 1,3,5- trimethyl, 2,4-tris (3,5-di-tertbutyl-4-hydroxybenzyl) benzene; pentaerythrityl tetrakis-3-tris (3,5-di-tertbutyl-4-hydroxybenzyl) propionate, and the like.

In an alternative embodiment, partial functional termination is used in combination with further additions of monomers. A functional terminator, such as cyclohexene oxide, can be added to the polymerization mixture.

Additional charge (s) of one or more of the monomers is then added to the polymerization mixture. This provides a mixture of di and triblock functionally or protically terminated interpolymers, together with multiblock polymers which may be longer than the di-and triblock interpolymers (depending on whether additional catalyst charges are added) and may be functionally or protically terminated.

As indicated above, the process is not limited to providing diblock and triblock compositions. The process can be extended, prior to final quenching, to add further charges of one or more monomers. For example, by adding a further charge of conjugated diene after step 5, the resulting composition can include a 4-block interpolymer A1-B1-A2-B2 and a triblock interpolymer A-B-A2, which both may be protically or functionally terminated, and where the monomers used to form blocks B1 and B2 may be the same or different.

The vinyl aromatic content of the triblock and diblock copolymers may vary over a wide range. For adhesive formulations, the vinyl aromatic content preferably does not exceed 55% (by wt.) based on the total weight of the block copolymer. More particularly, the vinyl aromatic content of both diblock and triblock copolymers is preferably from 10 to 50% (by wt.), more preferably from 12 to 40% (by wt.), and most preferably from 14 to 35% (by wt.), although higher or lower vinyl aromatic content may be desirable for some applications.

The molecular weight of the vinyl aromatic blocks is not bound to specific values, but the Mw may suitably be from 5,000 to 30,000, preferably 10,000 to 21,000. The apparent molecular weight of the triblock copolymer may suitably be from 50,000 to 400,000, preferably 70,000 to 125,000.

Molecular weights, throughout the specification, are as measured by GPC using polystyrene standards.

In another embodiment, a similar process is used to form a block copolymer composition including block copolymers in a solvent such as a linear hydrocarbon, e. g., hexane, or a mixture of solvents, such as a hexane/cyclohexane mixture, in which the poly (vinyl aromatic) blocks are insoluble or poorly soluble. Here, a small amount of a poly (conjugated diene) such as polybutadiene is formed first. This acts as a dispersant for the poly (vinyl aromatic) block formed in the second step. The reaction scheme thus may proceed as follows, using the same letters as above to represent the various components and using the letter b to represent a small amount of conjugated diene or conjugated diene polymer block : Step Add Products 1 a b + Li b-Li 1b A + Li A1-Li + b-A1-Li 2 B A1-B1-Li + b-A1-B1-Li 3 T-X A1-B1-Li + b-ArB1-Li +A1-B-T+ b-A1-B1-T+ LiX 4 A A1-B1-A2-Li + b-A1-B1-A2-Li + A1-B1-T + b-A1-B1-T

5 P-H A1-B1-A2-H + b-A1-B1-A2-H +A1-B1-T+ b-A1-B1-T Only a small amount of poly (conjugated diene) is needed to disperse the poly (vinyl aromatic) polymer. Thus, step 1a includes charging only a small portion of conjugated diene (preferably less than about 20%, more preferably less than 10%, and most preferably around 5% of the total conjugated diene) and of the catalyst/initiator (preferably less than half the catalyst charge, more preferably about one third of the total catalyst charge) to generate a small amount of b-Li, e. g, polybutadiene of relatively low molecular weight. Preferably, the molecular weight of the polymer formed in step 1 a is about 4500.

The poly (conjugated diene) is generated in a sufficient amount to disperse the vinyl aromatic compound added in step 1 b and to solubilize the poly (vinyl aromatic). Preferably, sufficient vinyl aromatic monomer and enough catalyst are added in step 1 b to ensure that the styrene blocks of the resulting interpolymers are of equivalent molecular weight. Because of the small amount of b-Li generated in step 1a, step 1b results in the formation of a small amount of b-A1-Li and a larger amount of A-Li. The method for steps 2-5 is otherwise the same as for the first embodiment.

The b-A1-B1-A2-H and b-A1-B-T, being relatively small in amount, have little effect on the overall properties of the composition. Thus, the overall properties of the copolymer composition are primarily dependent on the A1-B1-A2-H and A1-B1-T copolymers. Additionally, while b-ArBrT and b- A-Ba-A2-H are actually tri-and four-block copolymers, they tend to function as di-and tri-blocks, respectively, because of the small size of the b blocks.

The present invention also relates to a block copolymer composition that includes (1) a triblock copolymer B1-A1-B2 having two different or equal polymer end blocks Bf and B2 derived from conjugated diene and one polymer midblock A1 derived from vinyl aromatic compound; and (2) a diblock polymer A,-B2 having one polymer block A1 derived from a vinyl

aromatic compound and one polymer block B2 derived from a conjugated diene.

The process for forming the composition is the same as that described above except in that conjugated diene monomer is charged in place of vinyl aromatic monomer, and vice versa. Since the diene is soluble in either cyclic or linear hydrocarbon solvents, the composition may be formed, for example, in hexane, without the need for step 1a. The process proceeds with step 1 b by charging diene and all of the catalyst into the reactor. Step 2 charges vinyl aromatic monomer, and step (4) involves another charge of diene.

In accordance with yet another embodiment of the invention, steps 3 and 4 of the first embodiment are reversed, as follows : Step Add Products 1 A + Li At-Li 2 B + Li A1-B1-Li + B1-Li 3 A A1-B1-ArLi + Bu-Li 4 T-X A1-B1-A2-T + B1-A2-T + A1-B1-A2-Li + Bu-Li + XLi 5 P-H A1-B1-A2-T +B>-A2-T + A-BAs-H +Bt-A2-H In this reaction scheme, only a portion of the polymer chains are terminated with the terminating agent T-X after step 3, while the remainder of the chains are terminated by the protic terminating agent (replacing the positively charged Li with H) in step 5. In this embodiment, the functional terminating agent is distributed over both the diblock and triblock copolymers.

The compositions of the present invention are suited for use in adhesive compositions, asphalt compositions, and a variety of other uses.

To form an adhesive composition, the diblock/triblock composition may be combined with a variety of tackifying resins, plasticizing oils, waxes, stabi- lizers, and the like. Exemplary tackifying resins include hydrocarbon resins,

synthetic polyterpenes, rosin esters, natural terpenes, and the like.

Examples include natural and modified rosins such as gum rosin, wood rosin, hydrogenated rosin; glycerol and pentaerythrol esters of natural and modified rosins; copolymers and terpolymers of natural terpenes, e. g., styrene/terpene; polyterpene resins; phenolic-modified terpene resins and hydrogenated derivatives thereof ; aliphatic petroleum hydrocarbon resins having a Ball and Ring softening point of from about 70° to 135°C ; aromatic petroleum hydrocarbon resins and hydrogenated derivatives thereof ; and alicyclic petroleum hydrocarbon resins and hydrogenated derivatives thereof.

Exemplary stabilizers or antioxidants include high molecular weight hindered phenols such as S-and P-containing phenols. Representative hindered phenols include 1,3,5-trimethyl, 2,4-tris (3,5-di-tertbutyl-4- hydroxybenzyl) benzene; pentaerythrityl tetrakis-3-tris (3,5-di-tertbutyl-4- hydroxybenzyl) propionate, and the like.

Plasticizing oils are preferably present in the adhesive composition to provide wetting action and/or viscosity control. Exemplary plasticizing oils include not only the usual plasticizing oils, but also olefin oligomers and low molecular weight polymers as well as vegetable and animal oils, and their derivatives.

Various petroleum-derived waxes may be used to impart fluidity in the molten condition to the adhesive and flexibility to the set adhesive.

Exemplary waxes include paraffin and microcrystalline waxes having a melting point within the range of about 55°C to 110°C, as well as synthetic waxes, such as low molecular weight polyethylene or Fischer-Tropsch waxes.

For example, a hot melt adhesive may be formed as follows : a) 15-40% by weight of a diblock/triblock composition; b) 40-70% of a compatible tackifying resin; c) 5 to 30% by weight of a plasticizing oil ; d) 0 to 5% by weight of a petroleum derived wax; and

e) optionally, a small amount (0.1 to 2 weight percent) of a stabilizer.

The invention is further illustrated by the following examples, without intending to limit the scope of the invention.

EXAMPLES Examples 1 and 6: Preparation of a DiblocSTriblock Composition Partially Functionally Terminated with Cyclohexene Oxide A reactor fitted with a stirrer and heating/cooling jacket was charged with 10.06 kg hexane, 0.27 kg of a blend of 33.0% butadiene in hexane, 45.4 g of 3% butyl lithium catalyst in hexane, and 2. 0 g of a THF/oligomeric oxolanopropane polar modifier (Firestone Polymers ; Akron, Ohio) as a 15% solution in hexane. The batch temperature was set at 77°C and heated for 30 minutes before the mixture was cooled to a temperature of 32°C. A second charge of 92. 1 g butyl iithium/hexane solution was added, and then 2.31 kg of a blend of 33.0% styrene in hexane was added, as quickly as possible. The batch temperature was set to 54°C and the reaction allowed to proceed for 30 more minutes, after reaching the peak. A sample of the polymerization mixture was taken into a clean, N2-purged bottle for analysis.

The reactor was then charged with a further 5.85 kg of the blend of 33.0% butadiene in hexane, as quickly as possible. The batch temperature was set to 77°C and the reaction allowed to proceed for another 30 minutes, after reaching the peak. Then, 0.303 kg of a blend of 1% cyclohexene oxide (a functional terminator) in hexane was added. This amount was sufficient to terminate about 50% of the catalyst, leaving about half of the polymer chains still living and thus able to copolymerize.

After a further 5 minutes, a further 1.13 kg of a blend of 33.0% styrene in hexane was added to the reactor.

After a further 30 minutes, cooling of the jacket was started. The polymerization mixture was transferred to a holding tank to reduce the temperature quickly. Then, 8.9 g of a protic terminator, ethyl hexanoic acid, was added to convert any remaining lithium in the interpolymers to LiOH.

25.4 g Irganox antioxidant (Ciba Geigy) was added to the polymerization mixture and agitated.

The product was drum dried to remove the solvent.

Example 2: Preparation of a Diblock/Triblock Composition Partially Terminated with Isopropanol The process of Example 1 was used to prepare a diblock/triblock composition although, in this case, isopropanol was used in place of cyclohexene oxide to terminate about 50% of the catalyst.

Example 3: Preparation of a Triblock Composition from Styrene and Butadien (control) The process of Example 1 was used to prepare a diblock/triblock composition although, in this case, no functional terminating agent was used.

Example 4: Preparation of a DiblocklTriblock Composition Without Functional Termination Via Multiple Catalyst Charges (control) The process of Example 3 was used to prepare a diblock/triblock composition although, in this case, the catalyst charge which accompanied the first addition of styrene was adjusted to ensure that the styrene blocks were of equivalent molecular weight and the weight percent of the diblock in the interpolymer composition was about 50. In a first step, a small amount of butadiene was polymerized in the presence of a first charge of the catalyst (b-Li). Styrene was then copolymerized with a second catalyst charge. (bS-Li + S-Li). Another catalyst charge accompanied a further addition of butadiene (bSB-Li + SB-Li + B-Li).

Example 5: Preparation of a Diblock/l'riblock Composition Without Functional Termination Via Blending a Diblock with a Triblock (control) The process was similar to Example 1, except that a diblock of butadiene and styrene was separately prepared and charged to the reactor with the initial hexane, styrene, butyl lithium catalyst, and polar modifier. The

diblock was used in about 50 weight percent of the interpolymer composition.

The interpolymer compositions prepared in Examples 1-6 and a control sample of Stereon 840 styrene butadiene multiblock polymer with 43% styrene and an MFR of 12 (Firestone Polymers) were then subjected to a variety of analytical tests, as follows : Pressure Sensitive Adhesive (PSA) Tests For these tests the composition was dissolved in toluene and cast on to metalized polyester to produce a tape.

Viscosity, cP, after stripping the solvent from the adhesive, was measured at four different temperatures (149°, 163°, 177°, and 204°C) according to ASTM D2196.

Quick Stick, g/cm, was measured according to Pressure Sensitive Tape Council method PSTC-5.

Peel Adhesion, g/cm, was measured on three different substrates, stainless steel, polyethylene, and polypropylene, according to PSTC-1 (ASTM D3330).

SAFT, °C, was measured according to ASTM D4498.

Polyken Tack, g, was measured according to ASTM D2979.

Rolling Ball, cm, was measured according to PSTC-6 (ASTM D3121).

Gardner Color was measured according to ASTM D1544.

Coating Weight (measured in g/100 cm2) was measured by coating a sheet of metallized polyester (DuPont) of known weight/unit area with the composition, weighing a known area, and deducting the weight of polyester in the sample.

Hot Melt Adhesive Tests These tests were carried out on the composition in the form of a hot melt adhesive.

Adhesive Tensile, kg/cm2, was determined by pouring the composition into a mold and allowing it to cool. The specimen is removed from the mold and subjected to standard tensile tests at room temperature.

Viscosity, cP, was measured at four different temperatures (149°, 163°, 177° and 204°C) according to ASTM D 2196.

The results of these tests are provided in Table 2. Molecular weights for these compositions, and % styrene, % block styrene, % vinyl butadiene, and % melt indexes are recorded in Table 3. Melt index was determined according to ASTM D1238 (MFR 200/5.0 (200°C, 5 kg)).

Table 2 S-840A 1 2 3 4 5 6 PSA RESULTS Viscosity,cP @149°C 2538 3775 3475 4225 3588 2930 4625 @163°C 1600 2350 2120 2675 2240 1825 2840 @177°C 1065 1420 1400 1745 1495 1208 1910 @204°C 542 692 695 858 720 568 875 quick Stick, g/cm 382 650 820 666 914 689 1173 Peel Adhesion, g/cm Stainless steel 1229 1218 1127 1377 1047 1262 1565 Polyethylene 147 292 277 208 425 257 384 Polypropylene 997 961 940 388 942 843 1233 SAFT, °C 58 57 56 46 60 57 56 Polyken Tack, g >1K >1K 966 >1K >1K >1K >1K Rolling ball, cm >10 >10 >10 >10 >10 >10 >10 GardnerColor 2 2 2 2 4 4 3 Coating Weight, 0.264 0. 254 0.272 0.294 0.265 0.290 0.364 g/100cm HMAResults Viscosity,cP @149°C 2785 2235 3195 3688 3110 2790 3245 <163°C 1720 1365 1975 2310 1915 1725 2050 @177°C 1108 895 1290 1520 1260 1145 1352 <204°C 552 428 638 745 640 565 615 Adhesive Tensile, 7.94 4.36 5.11 7.90 3.31 4. 12 3. 53 kglcm Table 3 1 2 3 4 5 6 Dn/a Process PFT1 PT2 MCC3 Blend PFT1 (control) Total MW Mn 53, 690 54,540 57,840 65,560 66,120 50,750 Mw 72,330 72,710 78,360 75, 680 74,450 81,130 Mw/Mn 1. 35 1.33 1.36 1.15 1.13 1.60 Block styrene MW Mn 15, 300 14,810 12,760 17,360 13,680 14,560 Mw 20,670 21,440 15,940 24,120 17,440 19,820 Mw/Mn 1. 35 1. 45 1.25 1.39 1. 28 1.36 Styrene wt percent 38.6 35.7 36.7 34.9 38.3 38.5 Block styrene, % as 100 100 100 100 70 100 /of styrene Vinyl butadiene 17. 6 11.1 12.7 14.2 22.4 10.0 Melt index (Cond. G) 4.4 11.6 5.9 6.2 8.0 5.6 'Partial functional termination 2 Partial termination 3 Multiple catalyst charge