Title:
HIGH SURFACE MICROPOROUS MATERIALS WHICH ARE ACTIVE IN OXIDATION REACTIONS. TIQ-6 AND METIQ-6
Document Type and Number:
WIPO Patent Application WO2001037629
Kind Code:
A8
Abstract:
The invention relates to a microporous material formed by oxygen, silicon, germanium, aluminum, boron, gallium, zirconium and/or titanium known as TIQ-6, to a method for preparing said material and to its applications as catalyst in oxidation reactions. The TIQ-6 preparation method is based on the synthesis of a gel containing titanium and/or zirconium, hydrothermal treatment thereof under controlled conditions and treatment of the resulting laminar material with an organic compound solution, preferably having a long hydrocarbonated chain containing a proton accepting group. This swollen material is subjected to a specific treatment involving agitation, ultrasound or any other method known in prior art with the purpose of obtaining a delaminated solid with a high outer surface. The invention also relates to a material having similar characteristics as that of TIQ-6 but additionally having organic groups anchored on the surface thereof and called METIQ-6, to a method for preparing the latter and to the utilization thereof as catalyst in oxidation reactions. The incorporation of organic species during synthesis of the material called METIQ-6 is carried out by means of a post-synthesis process on the TIQ-6 material.
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Inventors:
CORMA CANOS AVELINO (ES)
FORNES SEGUI VICENTE (ES)
DIAZ MORALES URBANO (ES)
DOMINE MARCELO EDUARDO (ES)
FORNES SEGUI VICENTE (ES)
DIAZ MORALES URBANO (ES)
DOMINE MARCELO EDUARDO (ES)
Application Number:
PCT/ES2000/000456
Publication Date:
February 06, 2003
Filing Date:
November 24, 2000
Export Citation:
Assignee:
CONSEJO SUPERIOR INVESTIGACION (ES)
UNIV VALENCIA POLITECNICA (ES)
CORMA CANOS AVELINO (ES)
FORNES SEGUI VICENTE (ES)
DIAZ MORALES URBANO (ES)
DOMINE MARCELO EDUARDO (ES)
UNIV VALENCIA POLITECNICA (ES)
CORMA CANOS AVELINO (ES)
FORNES SEGUI VICENTE (ES)
DIAZ MORALES URBANO (ES)
DOMINE MARCELO EDUARDO (ES)
International Classes:
B01J29/89; B01J31/02; B01J35/10; B01J37/00; C01B37/00; C01B39/00; C01B39/08; C01B39/46; C01B39/48; C07B41/02; C07B41/06; C07B41/08; C07B43/00; C07B45/04; C07B61/00; C07C37/08; C07C39/02; C07C45/29; C07C47/02; C07C49/04; C07C51/23; C07C53/08; C07C315/00; C07C317/02; C07D301/12; C07D487/22; (IPC1-7): B01J29/89; C01B39/48; C07D301/12
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