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Title:
METHOD FOR PRE-HYDROGENATION OF CATALYTICALLY CRACKED GASOLINE
Document Type and Number:
WIPO Patent Application WO/2020/052144
Kind Code:
A1
Abstract:
Disclosed is a method for pre-hydrogenation of catalytically cracked gasoline, comprising passing catalytically cracked gasoline through a pre-hydrogenation reactor to carry out thiol etherification and double bond isomerization reactions, wherein the reaction conditions are as follows: a reaction temperature of 80 to 160°C, a reaction pressure of 1 to 5 MPa, a liquid hourly space velocity of 1 to 10 h -1, and a hydrogen to oil volume ratio of 3-8:1. A pre-hydrogenation catalyst comprises a support and an active component, the support comprising an alumina composite support having a macroporous structure, and one or more selected from ZSM-5, ZSM-11, ZSM-12, ZSM-35, mordenite, amorphous silicon aluminum, SAPO-11, MCM-22, Y molecular sieve, or beta molecular sieve, and the active component comprising one or more of cobalt, molybdenum, nickel, and tungsten supported on a surface of the support, wherein the active component is in an amount of 0.1 to 15.5% as oxides. The method is useful for producing gasoline with low alkene and ultra-low sulfur contents, and a high octane number.

Inventors:
WANG TINGHAI (CN)
BAO XIAOJUN (CN)
YUE YUANYUAN (CN)
WANG XUELI (CN)
LIU JIE (CN)
ZHU HAIBO (CN)
YUAN PEI (CN)
BAI ZHENGSHUAI (CN)
Application Number:
PCT/CN2018/122104
Publication Date:
March 19, 2020
Filing Date:
December 19, 2018
Export Citation:
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Assignee:
UNIV FUZHOU (CN)
International Classes:
B01J23/888; C10G45/04; B01J29/48; C10G45/08; C10G45/12
Foreign References:
CN103372450A2013-10-30
CN101088614A2007-12-19
CN101173185A2008-05-07
CN101191079A2008-06-04
CN101885985A2010-11-17
JPS57184442A1982-11-13
Attorney, Agent or Firm:
FUZHOU JUNCHENG ZHISHICHANQUAN DAILI YOUXIANGONGSI (CN)
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