METHOD FOR SYNTHESIS OF POLYMER COMPLEX CRYSTAL

Title:

METHOD FOR SYNTHESIS OF POLYMER COMPLEX CRYSTAL

Document Type and Number:

WIPO Patent Application WO/2008/111664

Kind Code:

A1

Abstract:

Disclosed is a synthesis method for synthesizing a polymer complex microcrystal having three-dimensionally regularly positioned pores therein within a short time and in a selective manner. Specifically disclosed is a method for synthesizing a polymer complex crystal, which is characterized by mixing a metal solution (1) with a ligand solution (2) so that the resulting mixture forms a single phase, wherein the metal solution (1) is prepared by mixing a zinc halide (II) and a solvent (A) which can dissolve the zinc halide therein, and the ligand solution (2) is prepared by mixing a tridentate ligand having three coordinately binding sites through which the ligand can coordinate to zinc in the zinc halide with a solvent (B) which can dissolve the tridentate ligand therein. The method enables to synthesize a microcrystal of a polymer complex which has a tree-dimensional network structure formed by the coordination of the tridentate ligand to the zinc, and also has three-dimensionally regularly positioned pores in the three-dimensional network structure.

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Inventors:

FUJITA MAKOTO (JP)
KAWANO MASAKI (JP)
HANEDA TSUYOSHI (JP)
NAKANISHI KIYOSHI (JP)
KOJIMA TAKAHIRO (JP)

Application Number:

PCT/JP2008/054696

Publication Date:

September 18, 2008

Filing Date:

March 07, 2008

Export Citation:

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Assignee:

UNIV TOKYO (JP)
TOYOTA MOTOR CO LTD (JP)
FUJITA MAKOTO (JP)
KAWANO MASAKI (JP)
HANEDA TSUYOSHI (JP)
NAKANISHI KIYOSHI (JP)
KOJIMA TAKAHIRO (JP)

International Classes:

C08G79/00; C07D401/14

Foreign References:

JP2002126512A	2002-05-08
JP2006188560A	2006-07-20

Attorney, Agent or Firm:

KISHIMOTO, Tatsuhito et al. (3rd FloorOak Building Kyobashi, 16-10, Kyobashi 1-chom, Chuou-ku Tokyo 31, JP)

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