Title:
NOVEL POLY(SPIROBISINDANE-ARYL PIPERIDINIUM) COPOLYMER IONOMER, ANION EXCHANGE MEMBRANE, AND METHOD FOR PREPARING SAME
Document Type and Number:
WIPO Patent Application WO/2023/140628
Kind Code:
A1
Abstract:
The present invention relates to a technique for synthesizing a poly(spirobisindane-aryl piperidinium) copolymer having a piperidinium group introduced therein while containing a spirobisindane group in a repeating unit and having no aryl ether bond in a polymer backbone, and preparing an anion exchange membrane therefrom. A novel poly(spirobisindane-aryl piperidinium) copolymer ionomer, according to the present invention, has excellent chemical stability and mechanical properties, high ionic conductivity, improved gas permeability, and reduced mass transfer resistance. In addition, an anion exchange membrane prepared from the poly(spirobisindane-aryl piperidinium) copolymer ionomer and a composite membrane thereof have excellent chemical stability, mechanical properties, durability and water management ability, and thus can be applied to a membrane and a binder for an alkaline fuel cell, a water electrolysis device, carbon dioxide reduction, a metal-air battery, or the like.
Inventors:
LEE YOUNG MOO (KR)
PARK JONG HYEONG (KR)
HU CHUAN (KR)
PARK JONG HYEONG (KR)
HU CHUAN (KR)
Application Number:
PCT/KR2023/000901
Publication Date:
July 27, 2023
Filing Date:
January 19, 2023
Export Citation:
Assignee:
IUCF HYU (KR)
International Classes:
C08G61/02; C08G61/12; C08J5/22; C25B13/08; H01M8/083; H01M8/103; H01M8/1058; H01M8/1081
Foreign References:
| JP6979624B1 | 2021-12-15 |
Other References:
WANG HO HYUN, HU CHUAN, PARK JONG HYEONG, KIM HAE MIN, KANG NA YOON, BAE JOON YONG, LEE WON HEE, CHEN NANJUN, LEE YOUNG MOO: "Reinforced poly(fluorenyl-co-terphenyl piperidinium) anion exchange membranes for fuel cells", JOURNAL OF MEMBRANE SCIENCE, vol. 644, 1 March 2022 (2022-03-01), NL , pages 1 - 9, XP093079716, ISSN: 0376-7388, DOI: 10.1016/j.memsci.2021.120160
LI ZIQIN, GUO JING, ZHENG JIFU, SHERAZI TAUQIR A., LI SHENGHAI, ZHANG SUOBO: "A Microporous Polymer with Suspended Cations for Anion Exchange Membrane Fuel Cells", MACROMOLECULES, vol. 53, no. 24, 22 December 2020 (2020-12-22), US , pages 10998 - 11008, XP055951983, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.0c01948
CHEN NANJUN, WANG HO HYUN, KIM SUN PYO, KIM HAE MIN, LEE WON HEE, HU CHUAN, BAE JOON YONG, SIM EUN SEOB, CHUNG YONG-CHAE, JANG JUE: "Poly(fluorenyl aryl piperidinium) membranes and ionomers for anion exchange membrane fuel cells", NATURE COMMUNICATIONS, vol. 12, no. 1, 1 December 2021 (2021-12-01), pages 1 - 12, XP055940480, DOI: 10.1038/s41467-021-22612-3
CHOI JIEUN; JANG JUE-HYUK; CHAE JI EON; PARK HEE-YOUNG; LEE SO YOUNG; JANG JONG HYUN; KIM JIN YOUNG; HENKENSMEIER DIRK; YOO SUNG J: "Spirobiindane-Based Poly(arylene ether sulfone) Ionomers for Alkaline Anion Exchange Membrane Fuel Cells", MACROMOLECULAR RESEARCH, vol. 28, no. 3, 18 January 2020 (2020-01-18), Seoul, pages 275 - 281, XP037081643, ISSN: 1598-5032, DOI: 10.1007/s13233-020-8036-x
LI ZIQIN, GUO JING, ZHENG JIFU, SHERAZI TAUQIR A., LI SHENGHAI, ZHANG SUOBO: "A Microporous Polymer with Suspended Cations for Anion Exchange Membrane Fuel Cells", MACROMOLECULES, vol. 53, no. 24, 22 December 2020 (2020-12-22), US , pages 10998 - 11008, XP055951983, ISSN: 0024-9297, DOI: 10.1021/acs.macromol.0c01948
CHEN NANJUN, WANG HO HYUN, KIM SUN PYO, KIM HAE MIN, LEE WON HEE, HU CHUAN, BAE JOON YONG, SIM EUN SEOB, CHUNG YONG-CHAE, JANG JUE: "Poly(fluorenyl aryl piperidinium) membranes and ionomers for anion exchange membrane fuel cells", NATURE COMMUNICATIONS, vol. 12, no. 1, 1 December 2021 (2021-12-01), pages 1 - 12, XP055940480, DOI: 10.1038/s41467-021-22612-3
CHOI JIEUN; JANG JUE-HYUK; CHAE JI EON; PARK HEE-YOUNG; LEE SO YOUNG; JANG JONG HYUN; KIM JIN YOUNG; HENKENSMEIER DIRK; YOO SUNG J: "Spirobiindane-Based Poly(arylene ether sulfone) Ionomers for Alkaline Anion Exchange Membrane Fuel Cells", MACROMOLECULAR RESEARCH, vol. 28, no. 3, 18 January 2020 (2020-01-18), Seoul, pages 275 - 281, XP037081643, ISSN: 1598-5032, DOI: 10.1007/s13233-020-8036-x
Attorney, Agent or Firm:
CHUNG HYUN PATENT & LAW FIRM (KR)
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