Title:
OPTICALLY ACTIVE MUSCONE COMPOSITION AND PERFUME PRODUCT CONTAINING THE SAME
Document Type and Number:
WIPO Patent Application WO/2006/051597
Kind Code:
A1
Abstract:
[PROBLEMS] To provide a perfume composition which is a more tasteful musk-like aroma and is a new perfume material of excellent aroma quality. When the perfume composition is added to a perfume product, retentivity is improved and a high-performance excellent musk-like aroma can be emitted. [MEANS FOR SOLVING PROBLEMS] The perfume composition contains as an active ingredient a mixture of optically active muscone isomers which is a mixture of the (R)- and (S)-isomers of optically active muscone, the blending ratio of the former to the latter being from 90/10 to 95/5 (by mass) or from 75/25 to 80/20 (by mass).
Inventors:
YAMAMOTO KENICHI (JP)
YAGI MISAO (JP)
MATSUDA HIROYUKI (JP)
MARUYAMA KENJI (JP)
YAGI MISAO (JP)
MATSUDA HIROYUKI (JP)
MARUYAMA KENJI (JP)
Application Number:
PCT/JP2004/016825
Publication Date:
May 18, 2006
Filing Date:
November 12, 2004
Export Citation:
Assignee:
TAKASAGO PERFUMERY CO LTD (JP)
YAMAMOTO KENICHI (JP)
YAGI MISAO (JP)
MATSUDA HIROYUKI (JP)
MARUYAMA KENJI (JP)
YAMAMOTO KENICHI (JP)
YAGI MISAO (JP)
MATSUDA HIROYUKI (JP)
MARUYAMA KENJI (JP)
International Classes:
C11B9/00; (IPC1-7): C11B9/00
Other References:
SCAFATO P ET AL: "Asymmetric activation of tropos catalysts in the stereoselective catalytic conjugate additions of R2Zn to alpha, beta-enones: an efficient synthesis of (-)-muscone.", TETRAHEDRON., vol. 60, no. 40, 27 September 2004 (2004-09-27), pages 8801 - 8806, XP004565029
IULIANO A ET AL: "Deoxycholic acid-based phosphates as chiral ligands in the enantioselective conjugate addition of dialkylzincs to cyclic enones: preparation of (-)-(R)-muscone.", TETRAHEDRON: ASYMMETRY., vol. 15, no. 16, 23 August 2004 (2004-08-23), pages 2533 - 2538, XP004533948
SCAFATO P ET AL: "Catalytic enantioselective conjugate addition of dialkyl zinc reagents to alpha, beta-unsaturated ketones mediated by new phosphite ligands containing binaphthalene/1,2-diphenylethane moieties: a practical synthesis of (R)-(-)-muscone.", TETRAHEDRON: ASYMMETRY., vol. 14, no. 24, 2003, pages 3873 - 3877, XP004476259
YAMAMOTO T ET AL: "A novel synthetic method for (R)- and (S)-muscones by enantioselective hydrogenation of (E)- and (Z)-3-methyl-2-cyclopentadecen-1-ones catalyzed by p-tolyl-BINAP-Ru(II) complexes.", TETRAHEDRON., vol. 58, no. 45, 2002, pages 9209 - 9212, XP004390244
SCAFATO P ET AL.: "Tetrahedron", vol. 60, 2004, ELSEVIER SCIENCE PUBLISHERS, pages: 8801 - 8806
TOMOYUKI OGAWA ET AL., J. CHEM. SOC., vol. 20, 1991, pages 1438 - 1439
KAZUHIKO TANAKA ET AL., J. CHEM. SOC., vol. 11, 1990, pages 795 - 797
YAMAMOTO T. ET AL.: "Tetrahedron", vol. 58, 2002, ELSEVIER SCIENCE PUBLISHERS, pages: 9209 - 9212
LULIANO A ET AL.: "Tetrahedron Asymmetry", vol. 15, 2004, PERGAMON PRESS LTD., pages: 2533 - 2538
ALEXAKIS A ET AL., SYNLETT, vol. 11, 1999, pages 1811 - 1813
See also references of EP 1820842A4
IULIANO A ET AL: "Deoxycholic acid-based phosphates as chiral ligands in the enantioselective conjugate addition of dialkylzincs to cyclic enones: preparation of (-)-(R)-muscone.", TETRAHEDRON: ASYMMETRY., vol. 15, no. 16, 23 August 2004 (2004-08-23), pages 2533 - 2538, XP004533948
SCAFATO P ET AL: "Catalytic enantioselective conjugate addition of dialkyl zinc reagents to alpha, beta-unsaturated ketones mediated by new phosphite ligands containing binaphthalene/1,2-diphenylethane moieties: a practical synthesis of (R)-(-)-muscone.", TETRAHEDRON: ASYMMETRY., vol. 14, no. 24, 2003, pages 3873 - 3877, XP004476259
YAMAMOTO T ET AL: "A novel synthetic method for (R)- and (S)-muscones by enantioselective hydrogenation of (E)- and (Z)-3-methyl-2-cyclopentadecen-1-ones catalyzed by p-tolyl-BINAP-Ru(II) complexes.", TETRAHEDRON., vol. 58, no. 45, 2002, pages 9209 - 9212, XP004390244
SCAFATO P ET AL.: "Tetrahedron", vol. 60, 2004, ELSEVIER SCIENCE PUBLISHERS, pages: 8801 - 8806
TOMOYUKI OGAWA ET AL., J. CHEM. SOC., vol. 20, 1991, pages 1438 - 1439
KAZUHIKO TANAKA ET AL., J. CHEM. SOC., vol. 11, 1990, pages 795 - 797
YAMAMOTO T. ET AL.: "Tetrahedron", vol. 58, 2002, ELSEVIER SCIENCE PUBLISHERS, pages: 9209 - 9212
LULIANO A ET AL.: "Tetrahedron Asymmetry", vol. 15, 2004, PERGAMON PRESS LTD., pages: 2533 - 2538
ALEXAKIS A ET AL., SYNLETT, vol. 11, 1999, pages 1811 - 1813
See also references of EP 1820842A4
Attorney, Agent or Firm:
Ebata, Toshio (24-1 hachobori 3-chome, Chuo-k, Tokyo 32, JP)
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