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Title:
POLYOXYALKYLENE POLYOL, POLYOL IN WHICH POLYMER IS DISPERSED, FLEXIBLE POLYURETHANE FOAM, AND PROCESSES FOR PRODUCTION OF SAME
Document Type and Number:
WIPO Patent Application WO/2011/136367
Kind Code:
A1
Abstract:
Provided is a process for producing a polyoxyalkylene polyol that has a low total degree of unsaturation and that has a high terminal-primary-hydroxyl content though the oxyethylene content of the polyoxyalkylene polyol is low. A process for the production of a polyoxyalkylene polyol, which comprises: a first polymerization step of subjecting propylene oxide and/or a propylene oxide/ethylene oxide mixture to ring-opening addition polymerization with an initiator in the presence of a double metal cyanide complex catalyst (a1) to form a first intermediate polyol; a second polymerization step of conducting, after the first polymerization step, ring-opening addition polymerization of propylene oxide in the presence of a polymerization catalyst (a2) that consists of an alkali metal hydroxide and/or an alkali metal alcoholate to form a second intermediate polyol; and a third polymerization step of conducting, after the second polymerization step, ring-opening addition polymerization of ethylene oxide in the presence of a polymerization catalyst (a2) to form a polyoxyalkylene polyol (A1).

Inventors:
SASAKI TAKAYUKI (JP)
KUMAGAI NAOHIRO (JP)
ITO TAKASHI (JP)
HARADA HISAKAZU (JP)
HORIE AKIO (JP)
SUZUKI CHITOSHI (JP)
ARAI TAKEAKI (JP)
FURUMI MASAHITO (JP)
Application Number:
PCT/JP2011/060454
Publication Date:
November 03, 2011
Filing Date:
April 28, 2011
Export Citation:
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Assignee:
ASAHI GLASS CO LTD (JP)
SASAKI TAKAYUKI (JP)
KUMAGAI NAOHIRO (JP)
ITO TAKASHI (JP)
HARADA HISAKAZU (JP)
HORIE AKIO (JP)
SUZUKI CHITOSHI (JP)
ARAI TAKEAKI (JP)
FURUMI MASAHITO (JP)
International Classes:
C08G65/28; C08F283/06; C08G18/48; C08G65/10
Domestic Patent References:
WO2006115169A12006-11-02
Foreign References:
JPH0314812A1991-01-23
JPH07278289A1995-10-24
JPH10279655A1998-10-20
JP2007204680A2007-08-16
JP2004269849A2004-09-30
JP2002543228A2002-12-17
JP2616054B21997-06-04
JP2616055B21997-06-04
JPH11106500A1999-04-20
JP2000230027A2000-08-22
JP4273876B22009-06-03
JPH04300920A1992-10-23
JP2003165836A2003-06-10
JP2005015786A2005-01-20
JPH07196778A1995-08-01
JP2000513647A2000-10-17
JP2010105166A2010-04-30
Other References:
See also references of EP 2565215A4
Attorney, Agent or Firm:
SENMYO, Kenji et al. (JP)
Spring name Kenji (JP)
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Claims: