Title:
PRODUCTION METHOD FOR ANION EXCHANGE RESIN AND PRODUCTION METHOD FOR ELECTROLYTE FILM
Document Type and Number:
WIPO Patent Application WO/2022/014355
Kind Code:
A1
Abstract:
Provided is a production method for an anion exchange resin that can be used to produce an electrolyte film having excellent mechanical characteristics (strength). The present invention pertains to producing an anion exchange resin in which a hydrophobic group is directly bonded to a hydrophilic group, by reacting a monomer for forming the hydrophobic group with a monomer for forming the hydrophilic group in the presence of bis(1,5-cyclooctadiene)nickel(0) as a polymerization-accelerating agent and 2,2'-bipyridine as a coligand. When doing so, the number of moles of bis(1,5-cyclooctadiene)nickel(0) is set to be 1.2-1.8 times as great as the total number of moles of the monomer for forming the hydrophobic group and the monomer for forming the hydrophilic group, and the number of moles of 2,2'-bipyridine is set to be 1.5-2.5 times as great as the number of moles of bis(1,5-cyclooctadiene)nickel(0).
Inventors:
MIYATAKE KENJI (JP)
KONNO YOSUKE (JP)
YOKOTA NAOKI (JP)
NAGASE KATSUYA (JP)
KONNO YOSUKE (JP)
YOKOTA NAOKI (JP)
NAGASE KATSUYA (JP)
Application Number:
PCT/JP2021/025060
Publication Date:
January 20, 2022
Filing Date:
July 02, 2021
Export Citation:
Assignee:
UNIV YAMANASHI (JP)
TAKAHATA PREC CO LTD (JP)
TAKAHATA PREC CO LTD (JP)
International Classes:
C08G61/12; C08J5/22; H01B13/00
Foreign References:
| JP2019023258A | 2019-02-14 | |||
| JP2019023259A | 2019-02-14 | |||
| JP2017061583A | 2017-03-30 | |||
| JP2017014423A | 2017-01-19 | |||
| JP2016044224A | 2016-04-04 | |||
| JP2016033199A | 2016-03-10 |
Other References:
ONO HIDEAKI, KIMURA TARO, TAKANO AOI, ASAZAWA KOICHIRO, MIYAKE JUNPEI, INUKAI JUNJI, MIYATAKE KENJI: "Robust anion conductive polymers containing perfluoroalkylene and pendant ammonium groups for high performance fuel cells", JOURNAL OF MATERIALS CHEMISTRY A, ROYAL SOCIETY OF CHEMISTRY, GB, vol. 5, no. 47, 1 January 2017 (2017-01-01), GB , pages 24804 - 24812, XP055899831, ISSN: 2050-7488, DOI: 10.1039/C7TA09409D
Attorney, Agent or Firm:
SEZAKI Yukinori (JP)
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