Title:
【発明の名称】飽和炭化水素の光脱水素方法
Document Type and Number:
Japanese Patent JPH0745415
Kind Code:
B2
Abstract:
PURPOSE:To produce a dimer which is an intermolecular dehydrogenation product and an unsaturated hydrocarbon which is an intra-molecular dehydrogenation product in one step by irradiating a saturated hydrocarbon with light in the presence of a complex compound of Rh or Pt and acetone. CONSTITUTION:Intermolecular and intramolecular dehydrogenation products are produced in one step by irradiating a saturated hydrocarbon (e.g. pentane or cyclohexane) with light at normal temperature in the presence of a complex compound of Rh or Pt [e.g. Rh6(CO))16 or Pt(C4H6O2)2] and 0.1-2.0 pts.vol. (based on 1 pt. vol. of saturated hydrocarbon) of acetone. A xenon lamp, etc., can be used as the light source in addition to white light emitted from a high- pressure mercury lamp.
Inventors:
Takamasa Hanaoka
Hironori Arakawa
Kazuhiko Takeuchi
Takehiko Matsuzaki
Yoshihiro Sugi
Hironori Arakawa
Kazuhiko Takeuchi
Takehiko Matsuzaki
Yoshihiro Sugi
Application Number:
JP3331489A
Publication Date:
May 17, 1995
Filing Date:
February 13, 1989
Export Citation:
Assignee:
Director of Industrial Technology
International Classes:
B01J19/12; B01J31/20; B01J31/22; C01B3/04; C07B61/00; C07C2/84; C07C5/333; C07C9/14; C07C9/22; C07C11/02; C07C13/20; C07C13/28; (IPC1-7): C07C13/20; C01B3/04; C07C2/84; C07C5/333; C07C9/14; C07C9/22; C07C11/02; C07C13/28
Domestic Patent References:
| JP6490137A | ||||
| JP6452729A |
Attorney, Agent or Firm:
Director, Institute of Materials Technology, Institute of Industrial Technology