3’-アルコキシスピロ環テトラミン酸及びテトロン酸

Japanese Patent JP5053841

B2

1-Oxa- or 1-azaspiro[4.5]dec-3-ene derivatives (I) are new. 1-Oxa- or 1-azaspiro[4.5]dec-3-ene derivatives of formula (I) are new. W : H, (halo)alkyl, halo, (halo)alkoxy or CN; X : (halo)alkyl, halo, (halo)alkoxy or CN; Y : H, (halo)alkyl, halo, (halo)alkoxy or CN in the 4 position; Z : H; W : H, halo or alkyl; X : (halo)alkyl, halo, (halo)alkoxy or CN; Y : optionally substituted phenyl or heteroaryl in the 4 position; Z : H; W : H, halo or alkyl; X : (halo)alkyl, halo, (halo)alkoxy or CN; Y : optionally substituted phenyl or heteroaryl in the 5 position; Z : H, alkyl or halo in the 4 position; W : H, Me, Pr, iPr, halo, CN or CF 3; X : (halo)alkyl, halo, (halo)alkoxy or CN; Y = alkyl in the 4 position; Z : H; W : H, halo, alkyl or alkoxy; X : (halo)alkyl, halo, (halo)alkoxy or CN; Y : H, halo, (halo)alkyl or haloalkoxy in the 4 position; Z : halo, (halo)alkyl, CN or (halo)alkoxy in the 3 or 5 position; A : optionally substituted alkanediyl, cycloalkyl or heterocycloalkyl; B : H or optionally substituted alkyl, alkenyl, alkoxy, alkoxyalkoxy, phenyl, or cycloalkyl optionally interrupted by heteroatoms and/or CO; D : NH or O; Q 1>H or optionally substituted alkyl, alkoxy, alkoxyalkyl, alkylthioalkyl, cycloalkyl, heterocycloalkyl, phenyl, heteroaryl, phenylalkyl or heteroarylalkyl; Q 2>H or alkyl; CQ 1>Q 2>an optionally substituted 3-6C ring optionally interrupted by a heteroatom; G : H, COR 1>, C(L)MR 2>, SOI 2R 3>, P(L)R 4>R 5>, E or C(L)NR 6>R 7>; E : a metal or ammonium ion; L, M : O or S; R 1>alkyl, alkenyl, alkoxyalkyl, alkylthioalkyl or polyalkoxyalkyl, each optionally substituted with halo or CN; cycloalkyl or heterocyclyl, each optionally substituted with halo, alkyl or alkoxy; or optionally substituted phenyl, phenylalkyl, heteroaryl, phenoxyalkyl or heteroaryloxyalkyl; R 2>alkyl, alkenyl, alkoxyalkyl or polyalkoxyalkyl, each optionally substituted with halo or CN; or optionally substituted cycloalkyl, phenyl or benzyl; R 3>-R 5>alkyl, alkoxy, alkylamino, dialkylamino, alkylthio, alkenylthio or cycloalkylthio, each optionally substituted with halo; or optionally substituted phenyl, benyl, phenoxy or phenylthio; R 6>, R 7>H; alkyl, cycloalkyl, alkenyl, alkoxy or alkoxyalkyl, each optionally substituted with halo or CN; or optionally substituted phenyl or benzyl; or together form an optionally substituted ring optionally containing O or S. Independent claims are also included for: (1) a process for preparing (I); (2) composition comprising at least one compound (I) and at least one of a list of safeners; (3) intermediates of formula (II), (XVI), (XIV), (XVII), (XIX), (XVIII), (III) and (XX). R 8>alkyl. [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] [Image] ACTIVITY : Herbicide; Insecticide; Acaricide; Plant antifungal. 7-Butoxy-4-hydroxy-3-(2,4,6-trimethylphenyl)-1-azaspiro[4.5]dec-3-en-2-one gave at least 70% control of Avena sativa, Lolium multiflorus and Staria viridis in a post-emergence test at an application rate of 320 g/ha. MECHANISM OF ACTION : None given.

Fisher, liner
Gaerzhen, Oliver
Leir, Shute Juan
Brett Chunider, Thomas
Huicht, Dieter
Martham, Olga
Arnold, Cristian
Aura, thomas
Hills, Martin The Jeffrey
Cane, heinz
Rosinger, chris

JP2007517166A

October 24, 2012

June 18, 2005

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BAYER CROPSCIENCE AG

C07D209/54; A01N25/32; A01N43/08; A01N43/36; A01N43/42; A01N43/56; A01N43/80; A01P3/00; A01P7/04; A01P13/02; A61K31/343; A61K31/403; A61K31/4439; A61K31/5377; A61P33/14; C07C229/48; C07C233/60; C07D307/12; C07D307/94; C07D401/12; C07D409/12

JP7179450A
JP5294953A
JP11510481A
JP2002507599A
JP2002504538A
JP2000507564A

WO2004024688A1

ITO,M.,HETEROCYCLES,2002年,V57 N5,P909-914

Yoshio Kawaguchi
Makoto Ono
Chihiro Watanabe
Kenkyo Kanayama
Katsuma Osaki
Mitsuaki Tsubokura

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