Title:
ACETAMIDINES, THEIR PRODUCTION AND PRODUCTION OF ACETAMIDES USING THE SAME
Document Type and Number:
Japanese Patent JP3220733
Kind Code:
B2
Abstract:
PURPOSE: To obtain new N-alkylacetamidines useful as an intermediate for producing N-alkylacetamides useful as a germicide for agriculture.
CONSTITUTION: N-Alkylacetamidines expressed by formula I (X1 to X3 are H, lower alkyl, lower alkoxy, lower alkenyl, halogen or trifluoromethyl; R1 and R2 are lower alkyl), e.g. (E)-α-methoxyimino-2-(2,5-dimethylphenoxymethyl) phenyl-N-methylacetamidine. The compound of formula I is obtained by reacting acetonitriles of formula II with an alkylamine of formula III. N-Alkylacetamides of formula IV useful as a germicide for agriculture is obtained by reacting the compound of formula I with a nitrous acid derivative. N-Alkyl-acetamides of formula IV can be produced in high yield by using a new intermediate of formula I.
Inventors:
Katsuhisa Masumoto
Akihiko Nakamura
Yujiro Kiyoshima
Mikio Sasaki
Akashi Tanahashi
Akihiko Nakamura
Yujiro Kiyoshima
Mikio Sasaki
Akashi Tanahashi
Application Number:
JP23000293A
Publication Date:
October 22, 2001
Filing Date:
September 16, 1993
Export Citation:
Assignee:
Shionogi Pharmaceutical Co., Ltd.
Sumitomo Chemical Co., Ltd.
Sumitomo Chemical Co., Ltd.
International Classes:
C07C249/12; C07C251/48; C07C257/14; (IPC1-7): C07C257/14; C07C249/12
Domestic Patent References:
JP543533A | ||||
JP5159844A | ||||
JP489464A | ||||
JP4288045A | ||||
JP6219986A |
Attorney, Agent or Firm:
Takashi Kuboyama (1 person outside)
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