ALICYCLIC DICARBOXYLIC ACID DIALLYL DERIVATIVE AND ITS PRODUCTION

Title:

ALICYCLIC DICARBOXYLIC ACID DIALLYL DERIVATIVE AND ITS PRODUCTION

Document Type and Number:

Japanese Patent JPH1149724

Kind Code:

A

Abstract:

PROBLEM TO BE SOLVED: To obtain the subject new derivative, useful for the production of a polyester having improved chemical resistance. SOLUTION: This method for producing a derivative of a tricyclo [5.2.1.0<2> ,<6> ]decane-8,9-dicarboxylic acid diallyl derivative of formula I [(n) is 0-3], e.g. tricyclo[5.2.1.0<2> ,<6> ]decane-8,9-dicarboxylic acid diallyoxyethyl, is obtained by reacting (A) tricyclo[5.2.1.0<2> ,<6> ]decane-8,9-dicarboxylic acid of formula II with (B) an allyl alcohol derivative of formula III in the presence of (C) 0.1-100 wt.% inorganic mineral acid (sulfuric acid, etc.), heteropolyacid (H3 PW12 O40 , etc.), organic acid (p-toluene sulfonic acid, etc.), cation exchanging resin (amberlite IR120, etc.), or H-type zeolite (H-ZSM-5, etc.), as a catalyst at 50-200 deg.C for 1-50 hr.

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Inventors:

SUZUKI HIDEO

Application Number:

JP20794597A

Publication Date:

February 23, 1999

Filing Date:

August 01, 1997

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Assignee:

NISSAN CHEMICAL IND LTD

International Classes:

B01J23/30; B01J27/02; B01J27/18; B01J31/02; C07B61/00; C07C67/03; C07C67/08; C07C69/753; (IPC1-7): C07C69/753; B01J23/30; B01J27/02; B01J27/18; B01J31/02; C07C67/03; C07C67/08

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