Title:
水素化および脱水素法のためのアミノ−ホスフィンリガンドに基づく錯体触媒
Document Type and Number:
Japanese Patent JP6670108
Kind Code:
B2
Abstract:
The present application discloses novel PWNN and PWNWP metal catalysts for organic chemical syntheses including hydrogenation (reduction) of unsaturated compounds or dehydrogenation of substrates. The range of hydrogenation substrate compounds includes esters, lactones, enals, enones, enolates, oils and fats, resulting in alcohols, enols, diols, and triols as reaction products. The catalysts of current application can be used to catalyze a hydrogenation reaction under solvent free conditions. The present catalysts also allow the hydrogenation to proceed without added base, and it can be used in place of the conventional reduction methods employing hydrides of the main-group elements. Furthermore, the catalysts of the present application can catalyze a dehydrogenation reaction under homogenous and/or acceptorless conditions. As such, the catalysts provided herein can be useful in substantially reducing cost and improving the environmental profile of manufacturing processes for a variety of chemicals.
Inventors:
Dmitry Gossab
Dennis Spashku
Dennis Spashku
Application Number:
JP2015561871A
Publication Date:
March 18, 2020
Filing Date:
March 17, 2014
Export Citation:
Assignee:
Dmitry Gossab
Dennis Spashku
Dennis Spashku
International Classes:
C07F9/58; B01J31/24; B01J31/30; C01B3/04; C01B3/22; C07C29/141; C07C29/145; C07C29/149; C07C31/125; C07C33/02; C07C33/025; C07C33/05; C07C33/14; C07C33/20; C07C33/22; C07C35/18; C07C35/21; C07C35/28; C07F9/46
Domestic Patent References:
| JP2008537946A | ||||
| JP2001294594A |
Foreign References:
| WO2011048727A1 | ||||
| WO2013023307A1 | ||||
| US20120323007 |
Other References:
SGRO, Michael J. , et al.,Dalton Transactions,2012年,41(22),pp. 6791-6802
SGRO, Michael J. , et al.,Organometallics,2012年,31(5),pp. 1584-1587
BENDAYAN, Andree, et al.,Journal of Organometallic Chemistry ,1987年,326(2),pp. 289-297
DURAP, Feyyaz, et al.,Comptes Rendus Chimie ,2013年,16(4),pp. 363-371
POWELL, John, et al.,Organometallics,1989年,8(12),pp. 2942-2947
SGRO, Michael J. , et al.,Dalton Transactions,2013年 5月31日,42(29),pp. 10460-10472
ELMA, Duygu, et al.,Journal of Organometallic Chemistry,2013年 4月 1日,729,pp. 46-52
SGRO, Michael J. , et al.,Organometallics,2012年,31(5),pp. 1584-1587
BENDAYAN, Andree, et al.,Journal of Organometallic Chemistry ,1987年,326(2),pp. 289-297
DURAP, Feyyaz, et al.,Comptes Rendus Chimie ,2013年,16(4),pp. 363-371
POWELL, John, et al.,Organometallics,1989年,8(12),pp. 2942-2947
SGRO, Michael J. , et al.,Dalton Transactions,2013年 5月31日,42(29),pp. 10460-10472
ELMA, Duygu, et al.,Journal of Organometallic Chemistry,2013年 4月 1日,729,pp. 46-52
Attorney, Agent or Firm:
Hiromori Arai