Title:
CATALYST COMPLEX WITH CARBENE LIGAND
Document Type and Number:
Japanese Patent JP2010188341
Kind Code:
A
Abstract:
To provide catalysts including metal carbene complexes which are useful for synthetic chemical reactions.
A catalyst complex includes (a) a metal atom selected from the group consisting of ruthenium and osmium, (b) at least one anionic ligand ligated to the metal atom, (c) at least one nucleophilic carbene ligand ligated to the metal atom, (d) another ligand ligated to the metal atom and (e) a carbon-containing ligand ligated to the metal atom. The carbon-containing ligand is selected from the group consisting of alkylidene, benzylidene, indenylidene, vinylidene and allenylidene.
COPYRIGHT: (C)2010,JPO&INPIT
Inventors:
NOLAN STEVEN P
HUANG JINKUN
HUANG JINKUN
Application Number:
JP2010051468A
Publication Date:
September 02, 2010
Filing Date:
March 09, 2010
Export Citation:
Assignee:
UNIV OF NEW ORLEANS FOUNDATION
International Classes:
B01J31/24; B01J31/16; B01J31/22; C07C4/08; C07C13/20; C07F9/50; C07F15/00; C07F19/00
Domestic Patent References:
| JPH05505795A | 1993-08-26 | |||
| JPH09512828A | 1997-12-22 | |||
| JP2003500412A | 2003-01-07 | |||
| JPH11510807A | 1999-09-21 | |||
| JP5066656B2 | 2012-11-07 | |||
| JP2002510658A | 2002-04-09 | |||
| JP2003500412A | 2003-01-07 |
Foreign References:
| US5312940A | 1994-05-17 | |||
| WO1997006185A1 | 1997-02-20 |
Other References:
JPN6009047240; ＡＲＤＵＥＮＧＯ， Ａ．Ｊ． ＩＩＩ ｅｔ ａｌ: 'Ａ ｓｔａｂｌｅ ｄｉａｍｉｎｏｃａｒｂｅｎｅ' Ｊ． Ａｍ． Ｃｈｅｍ． Ｓｏｃ． １１７ （４４）, 1995, ｐ．１１０２７-１１０２８
JPN6009047244; ＨＥＲＲＭＡＮＮ， Ｗ．Ａ． ｅｔ ａｌ: 'Ｎ-Ｈｅｔｅｒｏｃｙｃｌｉｃ Ｃａｒｂｅｎｅｓ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３６, 1997, ｐ．２１６２-２１８７
JPN7009004189; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'ＣＯＯＲＤＩＮＡＴＩＶＥＬＹ ＵＮＳＡＴＵＲＡＴＥＤ ＲＵＴＨＥＮＩＵＭ ＡＬＬＥＮＹＬＩＤＥＮＥ ＣＯＭＰＬＥＸＥＳ： ＨＩＧＨＬＹ ＥＦＦＥＣＴＩＶＥ， ＷＥＬＬ ＤＥＦＩＮＥＤ ＣＡＴＡＬＹＳＴ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ Ｖｏｌ．５， Ｎｏ．７, 19990407, ｐ．６０１-６０２
JPN6009047256; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'Ｉｎｃｒｅａｓｅｄ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅｔａｔｈｅｓｉｓ Ａｃｔｉｖｉｔｙ ｏｆ Ｒｕｔｈｅｎｉｕｍ-Ｂａｓｅｄ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ Ｃａｔａｌｙｓｔｓ Ｃｏｏｒｄｉｎａｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．１２, 19990319, ｐ．２２４７-２２５０
JPN7013003541; ＫＯＣＨＥＲ， Ｃ．Ｐ．: 'Ｎｅｕｅ Ｗｅｇｅ ｚｕ Ｎ-ｈｅｔｅｒｏｃｙｃｌｉｓｃｈｅｎ Ｃａｒｂｅｎｅｎ ｕｎｄ ｄｅｒｅｎ Ｍｅｔａｌｌｋｏｍｐｌｅｘｅｎ： Ａｎｗｅｎｄｕｎｇｅｎ ｉｎ ｄｅｒ Ｈｏｍｏｇｅｎｋａｔａｌｙ' Ｄｉｓｓｅｒｔａｔｉｏｎ， Ｔｅｃｈｎｉｓｃｈｅ Ｕｎｉｖｅｒｓｉｔａｔ Ｍｕｎｃｈｅｎ , 199703, ｐ．２，３，３０-５９，１２４-１４８
JPN7009004188; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ Ｒｕｔｈｅｎｉｕｍ Ａｌｌｅｎｙｌｉｄｅｎｅ Ｃｏｍｐｌｅｘｅｓ ａｓ ａ Ｎｅｗ Ｃｌａｓｓ ｏｆ Ｐｅｒｆｏｒｍｉｎｇ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ ｎｏ．１２, 19980621, ｐ．１３１５-１３１６
JPN6009047274; ＷＥＳＫＡＭＰ，Ｔ． ｅｔ ａｌ: 'Ａ Ｎｏｖｅｌ Ｃｌａｓｓ ｏｆ Ｒｕｔｈｅｎｉｕｍ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ' Ａｎｇｅｗａｎｄｔｅ Ｃｈｅｍｉｅ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｅｄｉｔｉｏｎ Ｖｏｌ．３７， Ｎｏ．１８, 19981002, ｐ．２４９０ - ２４９３
JPN6009047259; ＷＥＳＫＡＭＰ Ｔ． ｅｔ ａｌ: 'ＨＩＧＨＬＹ ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＡＴＡＬＹＳＴＳ ＦＯＲ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ： ＴＨＥ ＳＹＮＥＲＧＹ ＯＦ Ｎ-ＨＥＴＥＲＯＣＹＣＬＩＣ ＣＡＲＢＥＮＥＳ ＡＮＤ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３８， Ｎｏ．１６, 19990806, ｐ．２４１６-２４１９
JPN6009047262; ＡＣＫＥＲＭＡＮＮ Ｌ． ｅｔ ａｌ: 'Ｒｕｔｈｅｎｉｕｍ ｃａｒｂｅｎｅ ｃｏｍｐｌｅｘｅｓ ｗｉｔｈ ｉｍｉｄａｚｏｌｉｎ-２-ｙｌｉｄｅｎｅ ｌｉｇａｎｄｓ ａｌｌｏｗ ｔｈｅ ｆｏｒｍａｔｉｏｎ ｏｆ ｔｅｔｒａｓｕｂｓｔｉｔｕｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．２６, 19990625, ｐ．４７８７-４７９０
JPN6009047265; ＨＵＡＮＧ Ｊ． ｅｔ ａｌ: 'ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ-ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＯＭＰＬＥＸＥＳ ＢＥＡＲＩＮＧ Ａ ＮＵＣＬＥＯＰＨＩＬＩＣＣＡＲＢＥＮＥ ＬＩＧＡＮＤ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＡＭＥＲＩＣＡＮ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ ｖｏｌ．１２１， Ｎｏ．１２, 19990311, ｐ．２６７４-２６７８
JPN6009047269; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'ＳＹＮＴＨＥＳＩＳ ＡＮＤ ＡＣＴＩＶＩＴＹ ＯＦ Ａ ＮＥＷ ＧＥＮＥＲＡＴＩＯＮ ＯＦ ＲＵＴＨＥＮＩＵＭ-ＢＡＳＥＤ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ ＣＡＴＡＬＹＳＴＳ ＣＯＯＲＤＩＮＡＴＥ' ＯＲＧＡＮＩＣ ＬＥＴＴＥＲＳ ｖｏｌ．１， Ｎｏ．６, 19990813, ｐ．９５３-９５６
JPN6014024966; ＦＵＥＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ ｒｕｔｈｅｎｉｕｍ ａｌｌｅｎｙｌｉｄｅｎｅ ｃｏｍｐｌｅｘｅｓ ａｓ ａ ｎｅｗ ｃｌａｓｓ ｏｆ ｐｅｒｆｏｒｍｉｎｇ ｃａｔａｌｙｓｔｓ ｆｏｒ ｒｉｎｇ ｃｌｏｓｉｎｇ ｍｅ' Ｃｈｅｍ． Ｃｏｍｍｕｎ． Ｖｏｌ．１２, 19980621, ｐ．１３１５-１３１６
JPN6009047244; ＨＥＲＲＭＡＮＮ， Ｗ．Ａ． ｅｔ ａｌ: 'Ｎ-Ｈｅｔｅｒｏｃｙｃｌｉｃ Ｃａｒｂｅｎｅｓ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３６, 1997, ｐ．２１６２-２１８７
JPN7009004189; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'ＣＯＯＲＤＩＮＡＴＩＶＥＬＹ ＵＮＳＡＴＵＲＡＴＥＤ ＲＵＴＨＥＮＩＵＭ ＡＬＬＥＮＹＬＩＤＥＮＥ ＣＯＭＰＬＥＸＥＳ： ＨＩＧＨＬＹ ＥＦＦＥＣＴＩＶＥ， ＷＥＬＬ ＤＥＦＩＮＥＤ ＣＡＴＡＬＹＳＴ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ Ｖｏｌ．５， Ｎｏ．７, 19990407, ｐ．６０１-６０２
JPN6009047256; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'Ｉｎｃｒｅａｓｅｄ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅｔａｔｈｅｓｉｓ Ａｃｔｉｖｉｔｙ ｏｆ Ｒｕｔｈｅｎｉｕｍ-Ｂａｓｅｄ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ Ｃａｔａｌｙｓｔｓ Ｃｏｏｒｄｉｎａｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．１２, 19990319, ｐ．２２４７-２２５０
JPN7013003541; ＫＯＣＨＥＲ， Ｃ．Ｐ．: 'Ｎｅｕｅ Ｗｅｇｅ ｚｕ Ｎ-ｈｅｔｅｒｏｃｙｃｌｉｓｃｈｅｎ Ｃａｒｂｅｎｅｎ ｕｎｄ ｄｅｒｅｎ Ｍｅｔａｌｌｋｏｍｐｌｅｘｅｎ： Ａｎｗｅｎｄｕｎｇｅｎ ｉｎ ｄｅｒ Ｈｏｍｏｇｅｎｋａｔａｌｙ' Ｄｉｓｓｅｒｔａｔｉｏｎ， Ｔｅｃｈｎｉｓｃｈｅ Ｕｎｉｖｅｒｓｉｔａｔ Ｍｕｎｃｈｅｎ , 199703, ｐ．２，３，３０-５９，１２４-１４８
JPN7009004188; ＦＵＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ Ｒｕｔｈｅｎｉｕｍ Ａｌｌｅｎｙｌｉｄｅｎｅ Ｃｏｍｐｌｅｘｅｓ ａｓ ａ Ｎｅｗ Ｃｌａｓｓ ｏｆ Ｐｅｒｆｏｒｍｉｎｇ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｒｉｎｇ Ｃｌｏｓｉｎｇ Ｍｅ' ＣＨＥＭＩＣＡＬ ＣＯＭＭＵＮＩＣＡＴＩＯＮＳ ｎｏ．１２, 19980621, ｐ．１３１５-１３１６
JPN6009047274; ＷＥＳＫＡＭＰ，Ｔ． ｅｔ ａｌ: 'Ａ Ｎｏｖｅｌ Ｃｌａｓｓ ｏｆ Ｒｕｔｈｅｎｉｕｍ Ｃａｔａｌｙｓｔｓ ｆｏｒ Ｏｌｅｆｉｎ Ｍｅｔａｔｈｅｓｉｓ' Ａｎｇｅｗａｎｄｔｅ Ｃｈｅｍｉｅ Ｉｎｔｅｒｎａｔｉｏｎａｌ Ｅｄｉｔｉｏｎ Ｖｏｌ．３７， Ｎｏ．１８, 19981002, ｐ．２４９０ - ２４９３
JPN6009047259; ＷＥＳＫＡＭＰ Ｔ． ｅｔ ａｌ: 'ＨＩＧＨＬＹ ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＡＴＡＬＹＳＴＳ ＦＯＲ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ： ＴＨＥ ＳＹＮＥＲＧＹ ＯＦ Ｎ-ＨＥＴＥＲＯＣＹＣＬＩＣ ＣＡＲＢＥＮＥＳ ＡＮＤ' ＡＮＧＥＷＡＮＤＴＥ ＣＨＥＭＩＥ． ＩＮＴＥＲＮＡＴＩＯＮＡＬ ＥＤＩＴＩＯＮ ｖｏｌ．３８， Ｎｏ．１６, 19990806, ｐ．２４１６-２４１９
JPN6009047262; ＡＣＫＥＲＭＡＮＮ Ｌ． ｅｔ ａｌ: 'Ｒｕｔｈｅｎｉｕｍ ｃａｒｂｅｎｅ ｃｏｍｐｌｅｘｅｓ ｗｉｔｈ ｉｍｉｄａｚｏｌｉｎ-２-ｙｌｉｄｅｎｅ ｌｉｇａｎｄｓ ａｌｌｏｗ ｔｈｅ ｆｏｒｍａｔｉｏｎ ｏｆ ｔｅｔｒａｓｕｂｓｔｉｔｕｔｅ' ＴＥＴＲＡＨＥＤＲＯＮ ＬＥＴＴＥＲＳ ｖｏｌ．４０， Ｎｏ．２６, 19990625, ｐ．４７８７-４７９０
JPN6009047265; ＨＵＡＮＧ Ｊ． ｅｔ ａｌ: 'ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ-ＡＣＴＩＶＥ ＲＵＴＨＥＮＩＵＭ ＣＯＭＰＬＥＸＥＳ ＢＥＡＲＩＮＧ Ａ ＮＵＣＬＥＯＰＨＩＬＩＣＣＡＲＢＥＮＥ ＬＩＧＡＮＤ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＡＭＥＲＩＣＡＮ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ ｖｏｌ．１２１， Ｎｏ．１２, 19990311, ｐ．２６７４-２６７８
JPN6009047269; ＳＣＨＯＬＬ Ｍ． ｅｔ ａｌ: 'ＳＹＮＴＨＥＳＩＳ ＡＮＤ ＡＣＴＩＶＩＴＹ ＯＦ Ａ ＮＥＷ ＧＥＮＥＲＡＴＩＯＮ ＯＦ ＲＵＴＨＥＮＩＵＭ-ＢＡＳＥＤ ＯＬＥＦＩＮ ＭＥＴＡＴＨＥＳＩＳ ＣＡＴＡＬＹＳＴＳ ＣＯＯＲＤＩＮＡＴＥ' ＯＲＧＡＮＩＣ ＬＥＴＴＥＲＳ ｖｏｌ．１， Ｎｏ．６, 19990813, ｐ．９５３-９５６
JPN6014024966; ＦＵＥＲＳＴＮＥＲ， Ａ． ｅｔ ａｌ: 'Ｃａｔｉｏｎｉｃ ｒｕｔｈｅｎｉｕｍ ａｌｌｅｎｙｌｉｄｅｎｅ ｃｏｍｐｌｅｘｅｓ ａｓ ａ ｎｅｗ ｃｌａｓｓ ｏｆ ｐｅｒｆｏｒｍｉｎｇ ｃａｔａｌｙｓｔｓ ｆｏｒ ｒｉｎｇ ｃｌｏｓｉｎｇ ｍｅ' Ｃｈｅｍ． Ｃｏｍｍｕｎ． Ｖｏｌ．１２, 19980621, ｐ．１３１５-１３１６
Attorney, Agent or Firm:
Kazuo Shamoto
Shosuke Imai
Tadashi Masui
Yasushi Kobayashi
Hiroyuki Tomita
Shosuke Imai
Tadashi Masui
Yasushi Kobayashi
Hiroyuki Tomita
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