Title:
COMPOSITION STABILIZED AGAINST EARLY STAGE POLYMERIZATION
Document Type and Number:
Japanese Patent JP2009242802
Kind Code:
A
Abstract:
To provide a composition stabilized against early stage polymerization.
The composition stabilized against the early stage polymerization comprises a stable and sterically hindered organic nitroxyl compound expressed by formulae I and II and an ethylenically unsaturated monomer. For example, a 1,2-bis-adduct of 1-oxyl-2,2,6,6-tetramethyl-4-benzoyloxypiperidine with styrene is included.
Inventors:
CUNKLE GLEN THOMAS
THOMPSON THOMAS FRIEND
VON AHN VOLKER HARTMUT
WINTER ROLAND ARTHUR EDWIN
THOMPSON THOMAS FRIEND
VON AHN VOLKER HARTMUT
WINTER ROLAND ARTHUR EDWIN
Application Number:
JP2009121997A
Publication Date:
October 22, 2009
Filing Date:
May 20, 2009
Export Citation:
Assignee:
CIBA HOLDING INC
International Classes:
C07D209/46; C07C7/20; C08F2/40; C07C17/42; C07C239/20; C07D209/08; C07D211/94; C07D295/24; C08K5/3435; C08L101/00; C07C15/46; C07D209/44; C08F12/00
Domestic Patent References:
| JPH02300170A | 1990-12-12 | |||
| JPH04233905A | 1992-08-21 | |||
| JPH01113368A | 1989-05-02 |
Other References:
JPN6008040114; Ｒ． Ｅ． ＢＡＮＫＳ: 'Ｎｉｔｒｏｘｉｄｅ ｃｈｅｍｉｓｔｒｙ． Ｐａｒｔ Ｖ． Ｒｅａｃｔｉｏｎｓ ｂｅｔｗｅｅｎ ｂｉｓｔｒｉｆｌｕｏｒｏｍｅｔｈｙｌｎｉｔｒｏｘｉｄｅ ａｎｄ ａｌｋｙｌｂｅｎｚｅｎｅｓ： Ｍｅｃｈａｎ' ＪＯＵＲＮＡＬ ＯＦ ＴＨＥ ＣＨＥＭＩＣＡＬ ＳＯＣＩＥＴＹ， ＰＥＲＫＩＮ ＴＲＡＮＳＡＣＴＩＯＮＳ １ Ｖｏｌ．１０, 1973, ｐｐ．１０９２-１０９９
JPN6008040116; Ｄ． Ｗ． ＤＩＸＯＮ: 'Ｏｘｉｄａｔｉｏｎ ｏｆ １，２-ｂｉｓ（ｈｙｄｒｏｘｙｌａｍｉｎｅｓ）' ＪＯＵＲＮＡＬ ＯＦ ＯＲＧＡＮＩＣ ＣＨＥＭＩＳＴＲＹ Ｖｏｌ．４９，Ｎｏ．２３, 1984, ｐｐ．４４８７-４４９４
JPN6008040117; Ｃｏｎｎｏｌｌｙ， Ｔｅｒｒｅｎｃｅ Ｊ．: 'Ｒｅａｃｔｉｏｎｓ ｏｆ ｔｈｅ ""ｓｔａｂｌｅ"" ｎｉｔｒｏｘｉｄｅ ｒａｄｉｃａｌ ＴＥＭＰＯ． Ｒｅｌｅｖａｎｃｅ ｔｏ ""ｌｉｖｉｎｇ"" ｆｒｅｅ ｒａｄｉｃａｌ ｐｏｌｙｍｅｒｉｚａ' Ｔｅｔｒａｈｅｄｒｏｎ Ｌｅｔｔｅｒｓ Ｖｏｌ．３８，Ｎｏ．７, 1997, ｐｐ．１１３３-１１３６
JPN6008040119; Ｄｅｖｏｎｐｏｒｔ， Ｗａｙｎｅ: '""Ｌｉｖｉｎｇ"" Ｆｒｅｅ-Ｒａｄｉｃａｌ Ｐｏｌｙｍｅｒｉｚａｔｉｏｎｓ ｉｎ ｔｈｅ Ａｂｓｅｎｃｅ ｏｆ Ｉｎｉｔｉａｔｏｒｓ： Ｃｏｎｔｒｏｌｌｅｄ Ａｕｔｏｐｏｌｙｍｅｒｉｚａｔｉｏｎ' Ｍａｃｒｏｍｏｌｅｃｕｌｅｓ Ｖｏｌ．３０，Ｎｏ．７, 1997, ｐｐ．１９２９-１９３４
JPN6008040113; Ｇｒａｅｍｅ Ｍｏａｄ: 'Ａ Ｐｒｏｄｕｃｔ Ｓｔｕｄｙ ｏｆ ｔｈｅ Ｎｉｔｒｏｘｉｄｅ Ｉｎｈｉｂｉｔｅｄ Ｔｈｅｒｍａｌ Ｐｏｌｙｍｅｒｉｚａｔｉｏｎ ｏｆ Ｓｔｙｒｅｎｅ' Ｐｏｌｙｍｅｒ Ｂｕｌｌｅｔｉｎ Ｖｏｌ．６, 1982, ｐｐ．５８９-５９３
JPN6008040116; Ｄ． Ｗ． ＤＩＸＯＮ: 'Ｏｘｉｄａｔｉｏｎ ｏｆ １，２-ｂｉｓ（ｈｙｄｒｏｘｙｌａｍｉｎｅｓ）' ＪＯＵＲＮＡＬ ＯＦ ＯＲＧＡＮＩＣ ＣＨＥＭＩＳＴＲＹ Ｖｏｌ．４９，Ｎｏ．２３, 1984, ｐｐ．４４８７-４４９４
JPN6008040117; Ｃｏｎｎｏｌｌｙ， Ｔｅｒｒｅｎｃｅ Ｊ．: 'Ｒｅａｃｔｉｏｎｓ ｏｆ ｔｈｅ ""ｓｔａｂｌｅ"" ｎｉｔｒｏｘｉｄｅ ｒａｄｉｃａｌ ＴＥＭＰＯ． Ｒｅｌｅｖａｎｃｅ ｔｏ ""ｌｉｖｉｎｇ"" ｆｒｅｅ ｒａｄｉｃａｌ ｐｏｌｙｍｅｒｉｚａ' Ｔｅｔｒａｈｅｄｒｏｎ Ｌｅｔｔｅｒｓ Ｖｏｌ．３８，Ｎｏ．７, 1997, ｐｐ．１１３３-１１３６
JPN6008040119; Ｄｅｖｏｎｐｏｒｔ， Ｗａｙｎｅ: '""Ｌｉｖｉｎｇ"" Ｆｒｅｅ-Ｒａｄｉｃａｌ Ｐｏｌｙｍｅｒｉｚａｔｉｏｎｓ ｉｎ ｔｈｅ Ａｂｓｅｎｃｅ ｏｆ Ｉｎｉｔｉａｔｏｒｓ： Ｃｏｎｔｒｏｌｌｅｄ Ａｕｔｏｐｏｌｙｍｅｒｉｚａｔｉｏｎ' Ｍａｃｒｏｍｏｌｅｃｕｌｅｓ Ｖｏｌ．３０，Ｎｏ．７, 1997, ｐｐ．１９２９-１９３４
JPN6008040113; Ｇｒａｅｍｅ Ｍｏａｄ: 'Ａ Ｐｒｏｄｕｃｔ Ｓｔｕｄｙ ｏｆ ｔｈｅ Ｎｉｔｒｏｘｉｄｅ Ｉｎｈｉｂｉｔｅｄ Ｔｈｅｒｍａｌ Ｐｏｌｙｍｅｒｉｚａｔｉｏｎ ｏｆ Ｓｔｙｒｅｎｅ' Ｐｏｌｙｍｅｒ Ｂｕｌｌｅｔｉｎ Ｖｏｌ．６, 1982, ｐｐ．５８９-５９３
Attorney, Agent or Firm:
Calyx
Miyazaki Yoshio
Tsutomu Kato
Kyoko Oyama
Kaoru Onozuka
Akio Tagami
High Masahiro
Norio Mori
Seiji Yamada
Miyazaki Yoshio
Tsutomu Kato
Kyoko Oyama
Kaoru Onozuka
Akio Tagami
High Masahiro
Norio Mori
Seiji Yamada