Title:
ポリオレフィンからの、コントロールされたフリーラジカルグラフティング
Document Type and Number:
Japanese Patent JP5897786
Kind Code:
B2
Abstract:
Described are novel monomers bearing functionalities capable of initiating control free radical reactions, and a novel process using these initiating monomers in the co-polymerization of an olefin for the formation of well-controlled polyethylene graft polymers where the graft component is derived from controlled free radical polymerization reactions. The initiating monomers are produced by combining an amount of 5-norbornen-2-ol with a hydride or amine for a predetermined amount of time to form a mixture; and adding an amount of an alkyl or acyl halide to said mixture. Polymerization of an olefin with an initiating monomer is conducted in the presence of a metal compound, where the metal compound is comprised of a Group VIII transition metal complex.
Inventors:
Bazan, Guillermo, Sea
Coffin, robert, sea
Coffin, robert, sea
Application Number:
JP2009546364A
Publication Date:
March 30, 2016
Filing Date:
December 06, 2007
Export Citation:
Assignee:
The Regents of The University of California
International Classes:
C07C67/14; C07C69/63; C07C239/20; C08F4/80; C08F210/00; C08F255/00; C08F297/00
Domestic Patent References:
| JP2000500516A | ||||
| JP2003238494A | ||||
| JP2004131620A | ||||
| JP2006519914A | ||||
| JP5262830A | ||||
| JP2004002878A | ||||
| JP2008500307A | ||||
| JP2006199745A | ||||
| JP2007517120A | ||||
| JP1163248A | ||||
| JP6095372A | ||||
| JP2007131703A | ||||
| JP2002531830A | ||||
| JP2000154169A |
Foreign References:
| WO2005118651A1 |
Other References:
Iwao Tabushi, Kazuo Yamamura, Atsushi Togashi,Mechanism and stereochemistry in addition of acetic acid to quadricyclane,Journal of Organic Chemistry,1976年,第41巻,第12号,第2169頁~第2172頁
化学大辞典1 縮刷版,共立出版株式会社,2006年,縮刷版第39刷,第920頁~第921頁
Keith J. Watson,Donde R. Anderson,SonBinh T. Nguyen,Toward Polymeric Anticancer Drug Cocktails from Ring-Opening Metathesis Polymerization,Macromolecules ,2001年 5月22日,第34巻,第11号 ,第3507頁-第3509頁
化学大辞典1 縮刷版,共立出版株式会社,2006年,縮刷版第39刷,第920頁~第921頁
Keith J. Watson,Donde R. Anderson,SonBinh T. Nguyen,Toward Polymeric Anticancer Drug Cocktails from Ring-Opening Metathesis Polymerization,Macromolecules ,2001年 5月22日,第34巻,第11号 ,第3507頁-第3509頁
Attorney, Agent or Firm:
Noboru Fujimoto
Hiroaki Nakatani
Hiroaki Nakatani