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Title:
COORDINATION POLYMERIZATION
Document Type and Number:
Japanese Patent JPH0333101
Kind Code:
A
Abstract:

PURPOSE: To obtain a fine free flowable granular coordination polymerization polymer containing no largely contaminated agglomerates from a coordination polymerizable monomer by using a reactor not substantially containing a dead space during polymerization and receiving mechanical wiping-off action during polymerization by its whole inner surface being in contact with reaction content.

CONSTITUTION: A coordination polymerizable monomer is brought into contact with a coordination polymerization catalyst under a coordination polymerization condition within a reactor having no dead space under a reaction condition and receiving mechanical wiping-off action by its total surface being contact with reaction content to perform polymerization for a time sufficient to form a granular solid polymer. As the reactor, a twin-screw reactor having surface wiping-off action is pref. used. As the coordination polymerizable monomer, styrene, a styrene derivative, ethylene, propylene or butene are designated. The coordination polymerization catalyst is prepared from a transition metal compd. and to polyalkylaluminoxane.


Inventors:
JIYONASAN EICHI SHITSUDARU
Application Number:
JP7228090A
Publication Date:
February 13, 1991
Filing Date:
March 23, 1990
Export Citation:
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Assignee:
DOW CHEMICAL CO
International Classes:
B01J14/00; C08F2/00; C08F2/02; C08F2/04; C08F2/06; C08F4/42; C08F4/60; C08F4/64; C08F4/642; C08F4/6592; C08F4/80; C08F10/00; C08F210/00; (IPC1-7): B01J14/00; C08F2/00; C08F2/06; C08F4/42
Attorney, Agent or Firm:
Otani Ho



 
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