To provide a compound having high mobility and a high on/off value, capable of being formed into a film, by coating a solution thereof, a printing procedure, including inkjet printing, and a vapor deposition procedure, and capable of being used as a material for an n-type organic semiconductor.

This π electron-based compound has a skeletal structure containing a π electron-based ring, wherein both ends of the skeletal structure each have a perfluoroalkylphenyl group. The compound has the high mobility and the high on/off value and is formed into the film, by coating the solution thereof, the printing procedure, including the inkjet printing, and the vapor deposition procedure.