To provide a fluorous sugar-bonded crown ether derivative having an anomer carbon atom of a hemiketal structure as a cyclic carbon atom of the crown ether, where a hydroxy group of the sugar molecule is bonded to a fluorous tag, a fluorous sugar-bonded crown ether derivative composed of a sugar molecule, whose hydroxy group is bonded to a fluorous tag, and a crown ether bonded thereto by chemical synthesis, and a manufacturing method of these.
The fluorous sugar-bonded crown ether derivative is manufactured by bonding a fluorous tag to a sugar-bonded crown ether having an anomer carbon atom of a hemiketal structure of the sugar as a cyclic carbon atom of the crown ether. The fluorous sugar-bonded crown ether derivative is also manufactured by bonding a fluorous tag to a hydroxy group of the sugar and subjecting the resultant compound to a condensation reaction with an azacrown ether.
YOSHIDA TERUHIRO
ODA YOSHINOBU
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