Title:
触媒組成物及び芳香族化合物のハロゲン化方法
Document Type and Number:
Japanese Patent JP4960224
Kind Code:
B2
Abstract:
A method for ring-halogenating an aromatic compound comprises contacting with chlorine or bromine, a mixture comprising the aromatic compound and a mixed copper salt of formula Cu(Y)X, where Y comprises a counterion derived from an organic acid, where the organic acid has a pKa relative to water of 0 or greater; and X comprises Cl, Br, I, or (SO42−)1/2; to produce a reaction mixture comprising a haloaromatic compound and a copper(II) halide residue.
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Inventors:
Ganethan, Balakrishnan
Nadkany, Pradeep Zivaji
Nadkany, Pradeep Zivaji
Application Number:
JP2007516610A
Publication Date:
June 27, 2012
Filing Date:
June 13, 2005
Export Citation:
Assignee:
Subic Innovative Plastics IP Besloten Fennaught Shap
International Classes:
C07C17/12; B01J20/34; B01J27/122; B01J31/02; B01J31/04; C07B39/00; C07C17/00; C07C25/125; C07B61/00
Domestic Patent References:
| JP59206051A | ||||
| JP3120232A |
Other References:
Peng Cheng et al.,Crystal structure and ferromagnetic behavior of a μ-acetato-bridged one-dimensional linear-chain copper(II) complex,Inorganica Chimica Acta,1997年,254(2),371-373
Hassan Ali Dessouki et al.,Physicochemical studies on metal complexes of some o-hydroxy and o-carboxypenylazo-.beta.-diketones,Acta Chimica Hungarica,1989年,126(5),653-663
M. A. Khan et al.,Theoretical aspects of an equilibrium study in the non-dissociating molecular solvent scetic scid,Polyhedron,1990年,Vol.9, No.21,2613-2617
M. A. Khan et al.,Stability, spectra and structure of the copper(II) chloride complexes in acetic acid,Polyhedron,1983年,Vol. 2, No. 6,459-463
D. C. Nonhebel,Acylation of Metal Chelates. Part II. The Anomalous Behavior of Copper(II) Chelates,Journal of the Chemical Society,1962年,4628-4632
Y. Y. Lim et al.,Autooxidation of catechols in solutions of copper(II) surfactants and hydrated metal ions in sodium dodecyl sulphate,Journal of Molecular Catalysis,1993年,85,173-181
Hassan Ali Dessouki et al.,Physicochemical studies on metal complexes of some o-hydroxy and o-carboxypenylazo-.beta.-diketones,Acta Chimica Hungarica,1989年,126(5),653-663
M. A. Khan et al.,Theoretical aspects of an equilibrium study in the non-dissociating molecular solvent scetic scid,Polyhedron,1990年,Vol.9, No.21,2613-2617
M. A. Khan et al.,Stability, spectra and structure of the copper(II) chloride complexes in acetic acid,Polyhedron,1983年,Vol. 2, No. 6,459-463
D. C. Nonhebel,Acylation of Metal Chelates. Part II. The Anomalous Behavior of Copper(II) Chelates,Journal of the Chemical Society,1962年,4628-4632
Y. Y. Lim et al.,Autooxidation of catechols in solutions of copper(II) surfactants and hydrated metal ions in sodium dodecyl sulphate,Journal of Molecular Catalysis,1993年,85,173-181
Attorney, Agent or Firm:
Sakaki Morishita