Title:
アルケノールの製造方法および１，３−ブタジエンの製造のためのその使用
Document Type and Number:
Japanese Patent JP6804300
Kind Code:
B2
Abstract:
Process for the production of alkenols comprising the dehydration of at least one diol in the presence of at least one catalyst based on cerium oxide, wherein said catalyst based on cerium oxide is obtained by precipitation, in the presence of at least one base, of at least one compound containing cerium. Preferably, said diol may be a butanediol, more preferably 1,3-butanediol, still more preferably bio-1,3-butanediol derived from biosynthetic processes. Said alkenols may advantageously be used for the production of 1,3-butadiene, in particular of bio-1,3-butadiene.
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Inventors:
Albert Sesana
Stefano Ramello
Guido Spano
Stefano Ramello
Guido Spano
Application Number:
JP2016562016A
Publication Date:
December 23, 2020
Filing Date:
May 15, 2015
Export Citation:
Assignee:
VERSALIS S.P.A.
International Classes:
C07C29/60; B01J21/12; B01J23/10; B01J35/10; B01J37/00; B01J37/03; B01J37/12; C07C1/24; C07C11/167; C07C33/025; C07C33/03
Domestic Patent References:
| JP2014030376A | ||||
| JP50010563B1 | ||||
| JP8253435A |
Foreign References:
| CN101759529A | ||||
| WO2011052718A1 |
Other References:
SATO, Satoshi et al.,Selective dehydration of diols to allylic alchols catalyzed by ceria,Catalysis Communications,2003年,Vol.4,pp.77-81
DIEZ, V. K. et al.,GAS-PHASE CONVERSION OF 1,3-BUTANEDIOL ON SINGLE ACID-BASE AND CU-PROMOTED OXIDES,CATALYSIS TODAY,ELSEVIER,2013年 4月18日,VOL:213,PAGE(S):18 - 24,URL,http://dx.doi.org/10.1016/j.cattod.2013.02.030
HE, Y. et al.,SELECTIVE CATALYTIC DEHYDRATION OF 1,4-BUTANEDIOL TO 3-BUTEN-1-OL OVER CEO2 WITH 以下備考,CHINESE JOURNAL OF CATALYSIS / DALIAN INSTITUTE OF CHEMICAL PHYSICS,NL,ELSEVIER,2010年,VOL:31, NR:6,PAGE(S):619 - 622,DIFFERENT MORPHOLOGY,URL,http://www.sciencedirect.com/science/article/pii/S1872206709600759
DIEZ, V. K. et al.,GAS-PHASE CONVERSION OF 1,3-BUTANEDIOL ON SINGLE ACID-BASE AND CU-PROMOTED OXIDES,CATALYSIS TODAY,ELSEVIER,2013年 4月18日,VOL:213,PAGE(S):18 - 24,URL,http://dx.doi.org/10.1016/j.cattod.2013.02.030
HE, Y. et al.,SELECTIVE CATALYTIC DEHYDRATION OF 1,4-BUTANEDIOL TO 3-BUTEN-1-OL OVER CEO2 WITH 以下備考,CHINESE JOURNAL OF CATALYSIS / DALIAN INSTITUTE OF CHEMICAL PHYSICS,NL,ELSEVIER,2010年,VOL:31, NR:6,PAGE(S):619 - 622,DIFFERENT MORPHOLOGY,URL,http://www.sciencedirect.com/science/article/pii/S1872206709600759
Attorney, Agent or Firm:
Kenji Sugimura
Mitsutsugu Sugimura
Takao Inoue
Mitsutsugu Sugimura
Takao Inoue