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Title:
ジエンの製造方法
Document Type and Number:
Japanese Patent JP6672325
Kind Code:
B2
Abstract:
Process for the production of a diene, preferably a conjugated diene, more preferably 1,3-butadiene, comprising the dehydration of at least one alkenol in the presence of at least one catalytic material comprising at least one acid catalyst based on silica (SiO2) and alumina (AI2O3), preferably a silica-alumina (SiO2-AI2O3), said catalyst having a content of alumina (AI2O3) lower than or equal to 12% by weight, preferably ranging from 0.1% by weight to 10% by weight, with respect to the total weight of the catalyst. Preferably, said alkenol can be obtained directly from biosynthesis processes, or through the catalytic dehydration of at least one diol, preferably a butanediol, more preferably 1,3-butanediol, even more preferably bio-1,3-butanediol, deriving from biosynthesis processes. Preferably, said 1,3-butadiene is bio-1,3-butadiene.

Inventors:
Ramello Stefano
Milanese Vittorio
Butuzzoni roberto
Application Number:
JP2017543383A
Publication Date:
March 25, 2020
Filing Date:
February 22, 2016
Export Citation:
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Assignee:
Versalis Societa Peratini
International Classes:
C07C1/24; B01J21/12; B01J35/10; B01J37/00; B01J37/02; B01J37/03; B01J37/08; B01J37/30; C07C11/167; C07C29/60; C07C33/025
Domestic Patent References:
JP2010137227A
JP51122003A
JP6198171A
JP2017520511A
JP201694402A
JP2015182031A
Foreign References:
WO2013125389A1
Other References:
APPLIED CATALYSIS A: GENERAL,2015年,Vol.491,pp.163-169
Guayule: A Source of Natural Rubber,[オンライン],1997.04.18 [検索日 2019.06.27],,インターネット:
Attorney, Agent or Firm:
Shinichiro Tanaka
Disciple Maru Ken
▲吉▼田 和彦
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki
Satsuki Ichikawa
Hironobu Hattori