Title:
ゲルミレン系有機触媒を用いたヒドロシリル化方法
Document Type and Number:
Japanese Patent JP6953440
Kind Code:
B2
Abstract:
The invention relates to a method for hydrosilylating an unsaturated compound comprising at least one ketone function, one aldehyde function, one alkene function and/or one alkyne function, with a compound comprising at least one hydrogenosilyl function, using an organic germanium catalyst.
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Inventors:
Magari Busquier
Yan Lee Mao
Rafael Milgare
Go Kato
Antoine Baseiled
Yan Lee Mao
Rafael Milgare
Go Kato
Antoine Baseiled
Application Number:
JP2018559887A
Publication Date:
October 27, 2021
Filing Date:
May 05, 2017
Export Citation:
Assignee:
ELKEM SILICONES France SAS
International Classes:
C07F7/18; B01J31/22; C07F19/00
Domestic Patent References:
| JP2003516230A | ||||
| JP7285970A | ||||
| JP2018500290A |
Other References:
TAKAGI, N et al.,Theoretical Study of Reactivity of Ge(II)-hydride Compound: Comparison with Rh(I) Hydride Complex and Prediction of Full Catalytic Cycle by Ge(II)-hydride,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,THE AMERICAN CHEMICAL SOCIETY,2013年,Vo. 135,pp. 8955-8965
MICHALSKA, ZM,TRANSITION METAL COMPLEXES WITH POLYSTYRENE-ATTACHED AMINE-PHOSPHINE LIGANDS AS HYDROSILYLATION CATALYSTS,Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis,1986年,pp. 527-540
JANA, A et al.,Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a metal analogue with trimethylsilyl diazomethane,Dalton Transactions,2010年,Vol. 39,pp. 132-138
CHOONG, SL et al.,Synthesis, Characterization. and Reactivity of an N-Heterocyclic Germanium(II) Hydride: Reversible Hydrogermylation of a Phosphaalkyne,ORGANOMETALLICS,2011年,Vol. 30,pp. 5543-5550
CIPOT, J et al.,Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene: A Comparative Synthetic, Structual, and Catalytic Investigation,Organometallics,2007年,Vol. 26,pp. 594-608
GARCIA, JM et al.,Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes,Inorganic Chemistry,2012年,Vol. 51,pp. 8187-8193
BERTHE, J et al.,Synthesis and Reactivity of a Phosphine-Stabilized Monogermanium Analogue of Alkynes,Journal of the American Chemical Society,2011年,Vol. 133,pp. 15930-15933
MULLER, T,Non planar silylium, germylium and stannylium ions,Silicon Chemistry,2005年,Vol. 3,pp. 123-130
MICHALSKA, ZM,TRANSITION METAL COMPLEXES WITH POLYSTYRENE-ATTACHED AMINE-PHOSPHINE LIGANDS AS HYDROSILYLATION CATALYSTS,Homogeneous and Heterogeneous Catalysis: Proceedings of the Fifth International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis,1986年,pp. 527-540
JANA, A et al.,Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a metal analogue with trimethylsilyl diazomethane,Dalton Transactions,2010年,Vol. 39,pp. 132-138
CHOONG, SL et al.,Synthesis, Characterization. and Reactivity of an N-Heterocyclic Germanium(II) Hydride: Reversible Hydrogermylation of a Phosphaalkyne,ORGANOMETALLICS,2011年,Vol. 30,pp. 5543-5550
CIPOT, J et al.,Cationic and Formally Zwitterionic Rhodium(I) and Iridium(I) Derivatives of a P,N-Substituted Indene: A Comparative Synthetic, Structual, and Catalytic Investigation,Organometallics,2007年,Vol. 26,pp. 594-608
GARCIA, JM et al.,Synthesis and Characterization of Rhodium Complexes with Phosphine-Stabilized Germylenes,Inorganic Chemistry,2012年,Vol. 51,pp. 8187-8193
BERTHE, J et al.,Synthesis and Reactivity of a Phosphine-Stabilized Monogermanium Analogue of Alkynes,Journal of the American Chemical Society,2011年,Vol. 133,pp. 15930-15933
MULLER, T,Non planar silylium, germylium and stannylium ions,Silicon Chemistry,2005年,Vol. 3,pp. 123-130
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