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Title:
アルミニウム錯体と分子内閉環反応における触媒としてのその使用
Document Type and Number:
Japanese Patent JP5564506
Kind Code:
B2
Abstract:
To provide a process for increasing the proportion of an optical isomer of not only a compound having a closed ring but also a compound not having a closed ring when an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule is subjected to a ring closing reaction. A process for increasing the proportion of an optical isomer characterized by subjecting an optical isomer mixture of a compound having both a formyl group and a double bond capable of causing a carbonyl-ene ring closing reaction in the same molecule to a ring closing reaction in the presence of a predetermined aluminum complex represented by the general formula: [Al2(L1)n(L2)3-n]m.

Inventors:
Ito
Yohori Hori
Application Number:
JP2011525768A
Publication Date:
July 30, 2014
Filing Date:
December 17, 2009
Export Citation:
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Assignee:
Takasago International Corporation
International Classes:
C07C29/56; C07C35/17; B01J31/22; C07B53/00; C07B61/00; C07F5/06
Domestic Patent References:
JP2003501411A
JP2002212121A
Attorney, Agent or Firm:
Koichi Tsujii
Atsushi Hakoda
Kenji Asai
Kazuo Yamazaki