To provide a LiCoO2 particulate material in which the shapes of the particulate material are uniform as a whole in a certain direction, a method of manufacturing the LiCoO2 particulate material, and a secondary battery using the LiCoO2 particulate material as a positive-electrode active material.
A LiCoO2 particulate material includes a wire-shaped material and has a major peak equivalent to a (104) surface, based on XRD measurement. The method of manufacturing the LiCoO2 particulate material includes: a step of preparing wire-shaped Co-containing precursor particulates; a step of bringing a Li source into contact with the wire-shaped Co-containing precursor particulates in flux and forming the LiCoO2 particulate material containing a wire-shaped material; and a step of isolating and obtaining the resultant LiCoO2 particulate material from the other components. A secondary battery uses the LiCoO2 particulate material as a positive-electrode active material.
TEJIMA KATSUYA
UNIV SHINSHU
WO2010074314A1 | 2010-07-01 |
CHANGLU SHAO ET AL.: "Preparation of LiCoO2 nanofibers by electrospinning technique", J. PHYS. CHEM. SOLIDS, vol. 67, no. 7, JPN6014023346, July 2006 (2006-07-01), pages 1423 - 1426, ISSN: 0002827232
YUANXIANG GU ET AL.: "Synthesis and Electrochemical Properties of Nanostructured LiCoO2 Fibers as Cathode Materials for Li", J. PHYS. CHEM. B, vol. 109, no. 38, JPN6014023347, 29 September 2005 (2005-09-29), US, pages 17901 - 17906, ISSN: 0002827233
KATSUYA TESHIMA ET AL.: "Environmentally Friendly Growth of Well-Developed LiCoO2 Crystals for Lithium-Ion Rechargeable Batte", CRYST. GROWTH DES., vol. 10, no. 10, JPN6014023348, October 2010 (2010-10-01), US, pages 4471 - 4475, XP055640631, ISSN: 0002827234, DOI: 10.1021/cg100705d
HIKARU INAGAKI ET AL.: "Low-temperature flux growth of LiCoO2 oand LiMn2O4 crystals for rechargeable lithium ion batteries", 日本セラミックス協会秋季シンポジウム講演予稿集, vol. 23, JPN6014023350, 14 November 2010 (2010-11-14), JP, pages 9 - 010, ISSN: 0002827235
櫻井慶太他: "1次元形状CoO結晶のフラックス育成", 日本セラミックス協会年会講演予稿集, vol. 2011, JPN6014039642, 16 March 2011 (2011-03-16), JP, pages 303, ISSN: 0002901299
Takashi Ishida
Tetsuji Koga
Nobuo Sekine
Yasuo Dogaki