Title:
【発明の名称】オレフィンの低圧ロジウム接触ヒドロホルミル化
Document Type and Number:
Japanese Patent JP2831011
Kind Code:
B2
Abstract:
The hydroformylation of olefins with rhodium complex catalysts is described. The catalysts employed comprise a rhodium complex with at least one phosphine having a specified structure, e.g., tris(benzyl)phosphine. Preferred phosphines have a pKa in the range of about 3.5 up to 5.3 and a cone angle in the range of about 160 up to 195 DEG . Hydroformylation reactions at relatively low temperatures and pressure and yet with high rates of reaction and high selectivity to aldehyde product are obtained by the practice of the present invention.
Inventors:
PAKETSUTO TOOMASU AREN
DEBON TOOMASU JEIMUZU
DEBON TOOMASU JEIMUZU
Application Number:
JP50711088A
Publication Date:
December 02, 1998
Filing Date:
August 04, 1988
Export Citation:
Assignee:
IISUTOMAN CHEM CO
International Classes:
B01J31/20; C07B41/06; C07B61/00; C07C45/49; C07C45/50; C07C47/02; C07C47/19; C07C47/198; B01J31/24; C07C69/67; C07C233/02; C07C319/20; C07C323/22; (IPC1-7): C07C47/02; B01J31/20; B01J31/24; C07C45/50; C07C47/19; C07C47/198; C07C69/67
Other References:
【文献】米国特許4370504(US,A)
【文献】西独国特許出願公開2045169(DE,A1)
【文献】西独国特許出願公開2045169(DE,A1)
Attorney, Agent or Firm:
Takashi Ishida (2 outside)