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Title:
MATERIAL FOR PLASTIC LENS
Document Type and Number:
Japanese Patent JPS56147101
Kind Code:
A
Abstract:

PURPOSE: To manufacture a lens with a high refractive index and change the abrasion resistance, weather resistance and grindability in accordance with the blending ratio of a three-dimensional polymer by introducing an M-O bond chain into the polymer.

CONSTITUTION: A three-dimensional polymer is manufactured by using starting material selected from Ti, Zr, Pb, Ta, La, Cu, Zn, Sn, Cr and Tl and adding halogen except F, and a bond chain represented by formula I or II is introduced into the polymer to obtain a highly refractive lens with ≥1.65nD refractive index. For example, a Ti-contg. methacrylate monomer is synthesized from tetra-n-butoxy titanium and methacrylic acid ester as starting materials, and the monomer is mixed with diallyl phthalate in 1:1 wt. ratio. After adding 0.3wt% diisopropyl peroxycarbonate as a polymn. initiator, the monomer mixture is injected into hollow part 4 of glass mold 2, 2' set on the top and bottom of gasket 1, and it is polymerized at 60°C for 5hr. Thus, a three-dimensional polymer is obtd. by the reaction of formula III (where R is C4H9), and the polymer has properties such as 1.634nD and 34 Abbe's number enough for lenses for glasses.


Inventors:
KASAI YOSHIHIKO
SUMI HIROO
Application Number:
JP5065480A
Publication Date:
November 14, 1981
Filing Date:
April 17, 1980
Export Citation:
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Assignee:
SUWA SEIKOSHA KK
International Classes:
C08F220/00; C08F30/00; C08F30/04; C08F220/04; C08F230/04; C08G79/00; G02B1/04; (IPC1-7): C08F20/10; C08F30/04; C08G83/00



 
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