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Title:
METAL CUPTURING AGENT AND ITS PRODUCTION
Document Type and Number:
Japanese Patent JP3412842
Kind Code:
B2
Abstract:

PURPOSE: To obtain a metal capturing agent quick in sedimentation velocity of flock and capable of readily and surely carrying out waste water treatment without jointly using a polymer flocculant by reacting an aminomethyl group- containing polyamine with carbon disulfide.
CONSTITUTION: A polyamine having an aminomethyl group is made to react with carbon disulfide to provide the metal capturing agent having a structure of the formula [R is CSSM (M is H, alkali metal, etc.); R' is H or CSSM; n is integer]. In this metal capturing agent, a dithio acid group or its salt substituted with H atom bound to a nitrogen atom of a polyamine having an aminomethyl group is introduced. Concretely, the aminomethyl group-containing polyamine is dissolved in water, alcohol, etc., and then carbon disulfide is added thereto and the above-methioned reaction is carried out at 10-100°C for 1-20hr. Furthermore, the aminomethyl group-containing polyamine is obtained by dissolving, e.g. polyacrylonitrile in a solvent and then hydrogenating the polyacrylonitrile in the presence of a Raney nickel catalyst under high pressure to reduce the compound.


Inventors:
Masafumi Moriya
Kazuo Hosoda
Masatoshi Yoshida
Oi Ariake
Application Number:
JP22084392A
Publication Date:
June 03, 2003
Filing Date:
July 28, 1992
Export Citation:
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Assignee:
Miyoshi Oil & Fat Co., Ltd.
International Classes:
C02F1/62; C08F8/34; C08F26/02; C09K3/00; B01J20/26; (IPC1-7): C09K3/00; B01J20/26; C02F1/62; C08F8/34; C08F26/02
Domestic Patent References:
JP63182390A
JP1164492A
Attorney, Agent or Firm:
Isamu Hosoi