Title:
METHOD FOR PRODUCING 1,3-BENZOXATHIIN-4-ONE 1-OXIDE COMPOUND
Document Type and Number:
Japanese Patent JP2011011982
Kind Code:
A
Abstract:
To provide an industrially advantageous method for safely producing, in a good yield, a 1,3-benzoxathiin-4-one 1-oxide compound which is a raw material compound for a 1,2-benzoisothiazolin-3-one compound useful as an industrial antimicrobial agent and the like.
The method for producing the 1,3-benzoxathiin-4-one 1-oxide compound represented by formula (A) includes reacting the 1,3-benzoxathiin-4-one compound represented by formula (B) with an aqueous hydrogen peroxide solution in the presence of a catalyst or formic acid.
Inventors:
SHIMIZU MASAO
Application Number:
JP2009154591A
Publication Date:
January 20, 2011
Filing Date:
June 30, 2009
Export Citation:
Assignee:
AIST
International Classes:
C07D327/06; C07B61/00
Domestic Patent References:
| JPS4891087A | 1973-11-27 |
Foreign References:
| CN101434609A | 2009-05-20 | |||
| CN1201795A | 1998-12-16 |
Other References:
JPN6012064456; ＳＯＧＡＡＲＤ，Ｌ．Ｂ． ｅｔ ａｌ: 'Ｐｈｏｔｏｃｈｅｍｉｓｔｒｙ-ＩＩ Ｔｈｅ ｐｈｏｔｏｃｈｅｍｉｓｔｒｙ ｏｆ ｔｈｅ ４-ｔｈｉｏｉｓｏｃｈｒｏｍａｎ-１-ｏｎｅ-４-ｏｘｉｄｅ ｓｙｓｔｅｍ' Ｔｅｔｒａｈｅｄｒｏｎ Ｖｏｌ．２７， Ｎｏ．１１, 1971, ｐ．５１６３-５１７６
JPN6012064457; ＳＩＥＤＬＥＣＫＡ，Ｒ． ｅｔ ａｌ: 'Ｐｒｅｐａｒａｔｉｏｎ ａｎｄ ｐｒｏｐｅｒｔｉｅｓ ｏｆ ３，１-ｂｅｎｚｏｘａｔｈｉａｎ-４-ｏｎｅ ｄｅｒｉｖａｔｉｖｅｓ' Ｐｏｌｉｓｈ Ｊｏｕｒｎａｌ ｏｆ Ｃｈｅｍｉｓｔｒｙ Ｖｏｌ．７４， Ｎｏ．１０, 2000, ｐ．１３６９-１３７４
JPN6012064458; ＡＤＡＭ，Ｗ． ｅｔ ａｌ: 'Ｃｈｅｍｏｓｅｌｅｃｔｉｖｅ ｍｅｔｈｙｌｔｒｉｏｘｏｒｈｅｎｉｕｍ（ＶＩＩ）-ｃａｔａｌｙｚｅｄ ｓｕｌｆｏｘｉｄａｔｉｏｎｓ ｗｉｔｈ ｈｙｄｒｏｇｅｎ ｐｅｒｏｘｉｄｅ' Ｔｅｔｒａｈｅｄｒｏｎ Ｖｏｌ．５０， Ｎｏ．４６, 1994, ｐ．１３１２１-１３１２４
JPN6012064459; 'Ｓｅｌｅｃｔｉｖｅ ｓｙｎｔｈｅｓｉｓ ｏｆ ｓｕｌｆｏｘｉｄｅｓ ａｎｄ ｓｕｌｆｏｎｅｓ ｂｙ ｍｅｔｈｙｌｔｒｉｏｘｏｒｈｅｎｉｕｍ-ｃａｔａｌｙｚｅｄ ｏｘｉｄａｔｉｏｎ ｏｆ ｓｕｌｆｉｄｅ' Ｂｕｌｌｅｔｉｎ ｏｆ ｔｈｅ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ Ｖｏｌ．６９， Ｎｏ．１０, 1996, ｐ．２９５５-２９５９
JPN6012064460; ＣＡＢＲＥ，Ｃ．Ｊ． ｅｔ ａｌ: 'Ｓｉｓｔｅｍａｓ ｃａｔａｌｉｔｉｃｏｓ ｄｅ ｏｘｉｄａｃｉｏｎ ＩＩ： Ｏｘｉｄａｃｉｏｎ ｄｅ ｓｕｌｆｕｒｏｓ ａ ｓｕｌｆｏｘｉｄｏｓ． Ｕｎ ｍｅｔｏｄｏ ｓｅｎｃｉｌｌｏ ｙ ｅｃｏｎｏ' Ａｆｉｎｉｄａｄ Ｖｏｌ．４３， Ｎｏ．４０６, 1986, ｐ．５０５-５０７
JPN6012064457; ＳＩＥＤＬＥＣＫＡ，Ｒ． ｅｔ ａｌ: 'Ｐｒｅｐａｒａｔｉｏｎ ａｎｄ ｐｒｏｐｅｒｔｉｅｓ ｏｆ ３，１-ｂｅｎｚｏｘａｔｈｉａｎ-４-ｏｎｅ ｄｅｒｉｖａｔｉｖｅｓ' Ｐｏｌｉｓｈ Ｊｏｕｒｎａｌ ｏｆ Ｃｈｅｍｉｓｔｒｙ Ｖｏｌ．７４， Ｎｏ．１０, 2000, ｐ．１３６９-１３７４
JPN6012064458; ＡＤＡＭ，Ｗ． ｅｔ ａｌ: 'Ｃｈｅｍｏｓｅｌｅｃｔｉｖｅ ｍｅｔｈｙｌｔｒｉｏｘｏｒｈｅｎｉｕｍ（ＶＩＩ）-ｃａｔａｌｙｚｅｄ ｓｕｌｆｏｘｉｄａｔｉｏｎｓ ｗｉｔｈ ｈｙｄｒｏｇｅｎ ｐｅｒｏｘｉｄｅ' Ｔｅｔｒａｈｅｄｒｏｎ Ｖｏｌ．５０， Ｎｏ．４６, 1994, ｐ．１３１２１-１３１２４
JPN6012064459; 'Ｓｅｌｅｃｔｉｖｅ ｓｙｎｔｈｅｓｉｓ ｏｆ ｓｕｌｆｏｘｉｄｅｓ ａｎｄ ｓｕｌｆｏｎｅｓ ｂｙ ｍｅｔｈｙｌｔｒｉｏｘｏｒｈｅｎｉｕｍ-ｃａｔａｌｙｚｅｄ ｏｘｉｄａｔｉｏｎ ｏｆ ｓｕｌｆｉｄｅ' Ｂｕｌｌｅｔｉｎ ｏｆ ｔｈｅ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ Ｖｏｌ．６９， Ｎｏ．１０, 1996, ｐ．２９５５-２９５９
JPN6012064460; ＣＡＢＲＥ，Ｃ．Ｊ． ｅｔ ａｌ: 'Ｓｉｓｔｅｍａｓ ｃａｔａｌｉｔｉｃｏｓ ｄｅ ｏｘｉｄａｃｉｏｎ ＩＩ： Ｏｘｉｄａｃｉｏｎ ｄｅ ｓｕｌｆｕｒｏｓ ａ ｓｕｌｆｏｘｉｄｏｓ． Ｕｎ ｍｅｔｏｄｏ ｓｅｎｃｉｌｌｏ ｙ ｅｃｏｎｏ' Ａｆｉｎｉｄａｄ Ｖｏｌ．４３， Ｎｏ．４０６, 1986, ｐ．５０５-５０７
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