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Title:
N−ビニルアミドの製造方法およびそれに用いられるアパタイト
Document Type and Number:
Japanese Patent JP5663964
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide a method for producing an N-vinylamide which attains extremely high conversion and selectivity in the production of an N-vinylamide by dealcoholation reaction of N-(α-alkoxyalkyl)amide, and a catalyst used in the method.SOLUTION: According to the method, an N-vinylamide is produced by subjecting N-(α-alkoxyalkyl)amide to dealcoholation reaction in the presence of a surface-modified apatite catalyst prepared by surface-modifying an apatite represented by general formula (1) with a phosphoric acid compound. (In the formula, M is at least one member selected from the group consisting of Mg, Ca, Sr, Ba, Pb, Mn and Cd; Z is at least one member selected from the group consisting of P, As and Sb; X is at least one member selected from the group consisting of OH, F, Cl, Br, I and At; and 0≤y<1).

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Inventors:
山田 敦士
辻 哲郎
Application Number:
JP2010125433A
Publication Date:
February 04, 2015
Filing Date:
June 01, 2010
Export Citation:
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Assignee:
宇部興産株式会社
International Classes:
B01J27/18; C07C231/12; C07C233/03; C07D207/267; C07D223/10