To provide a method for producing an aromatic carbonyl compound that can produce easily and in a high yield an aromatic carbonyl compound having a substituent introduced in an aromatic ring adjacent to a carbonyl group.
The method for producing the aromatic carbonyl compound of the present invention is conducted by reacting a raw material carbonyl compound containing a structure having a carbonyl group linked with an aromatic ring and a boron compound represented by general formula (1) in the presence of a transition metal catalyst to obtain the aromatic carbonyl compound having R11 in general formula (1) linked with at least one aromatic ring in the raw material carbonyl compound, [wherein R11 indicates an aromatic group, an alkyl group, an alkynyl group or an alkenyl group; R12 and R13 indicate each a hydrogen atom, an alkyl group, an aryl group or a halogen-substituted alkyl group; X1 and X2 indicate each a nitrogen atom or an oxygen atom; l and p indicate each 1 or 2; and R12 and R13 may combine with each other to form a ring].
OGUMA JUN
SUMITOMO CHEMICAL CO
JP2004272414A | 2004-09-30 | |||
JPS56100855A | 1981-08-13 | |||
JPH06266031A | 1994-09-22 | |||
JPH0411214A | 1992-01-16 |
JPN6013013217; Bulletin of the Chemical Society of Japan 78(5), 2005, p.917-928
JPN6013013218; Journal of Organic Chemistry 51(6), 1986, p.921-929
JPN6013013219; Chemische Berichte 113(2), 1980, p.676-689
JPN6013013220; Organic Mass Spectrometry 1(2), 1968, p.273-278
JPN6013013221; Journal of the Chemical Society , 1954, p.1049-1059
Yoshinori Shimizu
Takashi Mikami