Title:
ヨウ化芳香族化合物の製造方法
Document Type and Number:
Japanese Patent JP7173911
Kind Code:
B2
Abstract:
To provide a method for producing iodinated aromatic compound, in which the regioselectivity of iodine introduction position is high, and the desired iodide compound can be obtained in a high yield.SOLUTION: The method for producing iodinated aromatic compound of the present invention is characterized by having an iodination step of reacting, in the presence of a porous material, an aromatic compound as a reaction substrate, and a specific iodination agent which is an N iodide amide compound or an N iodide imide compound having a cyclic structure including a partial structure represented by the following formula (1).SELECTED DRAWING: None
Inventors:
Shuji Ebata
Yuki Hoshino
Naoto Abe
Yuki Hoshino
Naoto Abe
Application Number:
JP2019053704A
Publication Date:
November 16, 2022
Filing Date:
March 20, 2019
Export Citation:
Assignee:
Toho Earth Tech Co., Ltd.
International Classes:
C07C67/287; C07C29/62; C07C33/20; C07C69/157
Domestic Patent References:
| JP2018076289A | ||||
| JP2004262770A |
Other References:
JI, Pengfi et al.,Tuning Lewis Acidity of Metal-Organic Frameworks via Perfluorination of Bridging Ligands: Spectroscopic, Theoretical, and Catalytic Studies,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2018年,Vol.140,pp.10553-10561,DOI: 10.1021/jacs.8b05765
LOSCH, P. et al.,Eco-compatible zeolite-catalysed continuous halogenation of aromatics,Green Chemistry,2016年,Vol.18,pp.4714-4724,DOI: 10.1039/c6gc00731g
DOLENC, Darko,N-Iodosaccharin - a New Reagent for Iodination of Alkenes and Activated Aromatics,Synlett,2000年,No.4,pp.544-546,DOI: 10.1055/S-2000-6561
CAI, Y. et al.,Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on ScandiumACHTUNGTRENUNG(III) and a N,N’-Dioxide Ligand,Chem. Eur. J.,2011年,Vol.17,pp.14916-14921,DOI: 10.1002/chem.201102453
MORI, K. et al.,Enantioselective Synthesis of Chiral Biaryl Chlorides/Iodides by a Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy,Adv. Synth. Catal.,2015年,Vol.357,pp.35-40,DOI: 10.1002/adsc.201400611
LOSCH, P. et al.,Eco-compatible zeolite-catalysed continuous halogenation of aromatics,Green Chemistry,2016年,Vol.18,pp.4714-4724,DOI: 10.1039/c6gc00731g
DOLENC, Darko,N-Iodosaccharin - a New Reagent for Iodination of Alkenes and Activated Aromatics,Synlett,2000年,No.4,pp.544-546,DOI: 10.1055/S-2000-6561
CAI, Y. et al.,Asymmetric Iodoamination of Chalcones and 4-Aryl-4-oxobutenoates Catalyzed by a Complex Based on ScandiumACHTUNGTRENUNG(III) and a N,N’-Dioxide Ligand,Chem. Eur. J.,2011年,Vol.17,pp.14916-14921,DOI: 10.1002/chem.201102453
MORI, K. et al.,Enantioselective Synthesis of Chiral Biaryl Chlorides/Iodides by a Chiral Phosphoric Acid Catalyzed Sequential Halogenation Strategy,Adv. Synth. Catal.,2015年,Vol.357,pp.35-40,DOI: 10.1002/adsc.201400611
Attorney, Agent or Firm:
Tatsuya Masuda
Kazuo Asahi
Kazuo Asahi