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Title:
含フッ素スルフィド化合物の製造方法
Document Type and Number:
Japanese Patent JP7208976
Kind Code:
B2
Abstract:
The present invention aims to provide a method by which fluorine-containing sulfide compounds, particularly sulfide compounds that contain hydrogen and fluorine, can be produced in a simple, low-cost and industrial manner. Provided is a method of producing a fluorine-containing sulfide compound represented by the following formula (2):(F)n-A3-S-A4-(F)m  (2)(wherein A3 and A4 are independently an optionally substituted hydrocarbyl group with a carbon number of 1 to 3; n and m represent the numbers of fluorine atoms binding to A3 and A4, with n+m=1 to 13 being satisfied), comprising reacting a chlorine-containing sulfide compound represented by the following formula (1):(Cl)n-A1-S-A2-(Cl)m  (1)(wherein A1 and A2 are independently an optionally substituted hydrocarbyl group with a carbon number of 1 to 3; n and m represent the numbers of chlorine atoms binding to A1 and A2, with n+m=1 to 13 being satisfied) and a fluorinating agent.

Inventors:
Wataru Kashiwakura
Yoshihiko Ikeya
Yuki Sato
Application Number:
JP2020511063A
Publication Date:
January 19, 2023
Filing Date:
March 29, 2019
Export Citation:
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Assignee:
Kanto Denka Kogyo Co., Ltd.
International Classes:
C07C319/20; C07C323/03
Domestic Patent References:
JP2001514645A
JP2009167187A
Foreign References:
US6316636
DD274820A1
Other References:
TRUCE,WILLIAM E.,Chlorination of dimethyl sulfide and some of its derivatives with sulfuryl chloride and thionyl chlo,JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,1952年,74,3594-3599
SAINT-JALMES,LAURENT,Selective aliphatic fluorination by halogen exchange in mild conditions,JOURNAL OF FLUORINE CHEMISTRY,2006年,127,85-90
Attorney, Agent or Firm:
Osamu Yamamoto
Toru Miyamae
Motoharu Nakanishi
Toyoji Matsuda