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Title:
メタクリル酸メチルの製造方法
Document Type and Number:
Japanese Patent JP4539599
Kind Code:
B2
Abstract:
A method of producing methyl methacrylate comprising the following steps: Thermal decomposition step: a hydrocarbon having 3 or more carbon atoms is thermally decomposed to obtain a decomposed gas having a total content of propyne and propadiene of 2 wt% or more, Separation step: mixed liquid rich in propyne and propadiene is separated from the decomposed gas obtained in the thermal decomposition step, Propyne purification step: the mixed liquid rich in propyne and propadiene obtained in the separation step is subjected to extractive distillation, for separation into purified propyne, and crude propadiene containing propadiene as the main component, Isomerization step: the crude propadiene obtained in the propyne purification step is isomerized in the presence of an isomerization catalyst, to obtain crude propyne containing propyne as the main component, and Carbonylation step: the purified propyne obtained in the propyne purification step is reacted with carbon monoxide and methanol in the presence of a group VIII metal catalyst system, to produce methyl methacrylate.

Inventors:
Masahiko Mizuno
Takeo Seo
Tetsuya Suzuda
Application Number:
JP2006097937A
Publication Date:
September 08, 2010
Filing Date:
March 31, 2006
Export Citation:
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Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
C07C67/38; B01D3/14; B01D3/40; C07C4/10; C07C5/23; C07C11/12; C07C11/22; C07C69/653; C07B61/00
Domestic Patent References:
JP5194317A
JP2290831A
JP2000510818A
Attorney, Agent or Firm:
Toru Nakayama