Title:
β-ニトロスチレン化合物の製造方法
Document Type and Number:
Japanese Patent JP5187616
Kind Code:
B2
Abstract:
A method for producing a ²-nitrostyrene compound is provided in which a benzaldehyde derivative represented by the following formula (I):
and nitromethane are condensed in an acetic acid solvent in the presence of a primary amine. This method allows production of a ²-nitrostyrene compound at a high yield in the industrially-safe reaction temperature range.
Inventors:
Takeo Masao
Koji Yuno
Kazuo Murakami
Koji Yuno
Kazuo Murakami
Application Number:
JP2007199547A
Publication Date:
April 24, 2013
Filing Date:
July 31, 2007
Export Citation:
Assignee:
Sumitomo Chemical Co., Ltd.
International Classes:
C07C201/12; C07C205/09; C07B61/00
Domestic Patent References:
| JP2005320346A | ||||
| JP62042923A | ||||
| JP9118655A | ||||
| JP3081745A | ||||
| JP38017017A | ||||
| JP2001278702A |
Foreign References:
| WO2007066828A1 |
Other References:
BOURGUIGNON J,CANADIAN JOURNAL OF CHEMISTRY,カナダ,NATIONAL RESEARCH COUNCIL,1985年,V63 N9,P2354-2361
BAJPAI L.K. ET AL.,UNUSUAL DENITROHYDROGENATION OF ALLYLIC TERTIARY NITRO COMPOUNDS DURING HYDROGENATION,SYNTHETIC COMMUNICATIONS,1995年,vol. 25, no. 12,pages 1765 - 1775
N. LATIF ET AL.,N-Unsubstituted (Carbamoyloxy)nitrostyrenes: A New Series of Aryl-beta-nitroalkenes with Fungicidal Properties,LIEBIGS ANNALEN DER CHEMIE,1987年,495-498,XP002614712
N. LATIF ET AL.,Reaction of biologically Active beta-Nitrostyrenes with o-Phenylenediamine: A New Route to the Synthesis of 2-Substituted Benzimidazoles,INDIAN JOURNAL OF CHEMISTRY, SECTION B,1982年,vol. 21b No.9,pages 872-874
LI,X. et al,Catalytic synthesis of β-nitro-p-chlorophenylethylene with quaternary ammonium salt PTCA,Zhongnan Daxue Xuebao, Ziran Kexueban,中国,Zhongnan Daxue Xuebao Ziran Kexueban Bianji Weiyuanhui,2004年,Vol.35, No.5,p.802-805
VALLEJOS G. ET AL.,Heteroarylisopropylamines as MAO inhibitors,BIOORGANIC & MEDICINAL CHEMISTRY,2005年,vol. 13, no. 14,pages 4450 - 4457
BAJPAI L.K. ET AL.,UNUSUAL DENITROHYDROGENATION OF ALLYLIC TERTIARY NITRO COMPOUNDS DURING HYDROGENATION,SYNTHETIC COMMUNICATIONS,1995年,vol. 25, no. 12,pages 1765 - 1775
N. LATIF ET AL.,N-Unsubstituted (Carbamoyloxy)nitrostyrenes: A New Series of Aryl-beta-nitroalkenes with Fungicidal Properties,LIEBIGS ANNALEN DER CHEMIE,1987年,495-498,XP002614712
N. LATIF ET AL.,Reaction of biologically Active beta-Nitrostyrenes with o-Phenylenediamine: A New Route to the Synthesis of 2-Substituted Benzimidazoles,INDIAN JOURNAL OF CHEMISTRY, SECTION B,1982年,vol. 21b No.9,pages 872-874
LI,X. et al,Catalytic synthesis of β-nitro-p-chlorophenylethylene with quaternary ammonium salt PTCA,Zhongnan Daxue Xuebao, Ziran Kexueban,中国,Zhongnan Daxue Xuebao Ziran Kexueban Bianji Weiyuanhui,2004年,Vol.35, No.5,p.802-805
VALLEJOS G. ET AL.,Heteroarylisopropylamines as MAO inhibitors,BIOORGANIC & MEDICINAL CHEMISTRY,2005年,vol. 13, no. 14,pages 4450 - 4457
Attorney, Agent or Firm:
Kuro Fukami
Toshio Morita
Yoshihei Nakamura
Yutaka Horii
Hisato Noda
Masayuki Sakai
Nobuo Arakawa
Toshio Morita
Yoshihei Nakamura
Yutaka Horii
Hisato Noda
Masayuki Sakai
Nobuo Arakawa