Title:
イミド化合物触媒を用いた有機化合物の製造法
Document Type and Number:
Japanese Patent JP4390394
Kind Code:
B2
Abstract:
(A) A compound capable of forming a stable radical and selected from (A1) oxygen-atom-containing compounds each having a carbon-hydrogen bond at the adjacent position to an oxygen atom, (A2) carbonyl-group-containing compounds, and (A3) compounds each having a hydrocarbon group with a methine carbon atom is allowed to react with (B) a radical scavenging compound selected from, for example, (B1) unsaturated compounds, and (B2) compounds each having a hydrocarbon group with a methine carbon atom, in the presence of molecular oxygen by catalysis of, for example, an imide compound shown by the following formula (1): wherein each of R<1> and R<2> is a hydrogen atom or the like, where R<1> and R<2> may be combined to form a double bond, or an aromatic or non-aromatic ring; X is an oxygen atom or a hydroxyl group, to yield a product of an addition or substitution reaction of the compound (A) and the compound (B) or its oxidized product. The process can efficiently produce a variety of organic compounds by an addition or substitution reaction using molecular oxygen under mild conditions.
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Inventors:
Yasutaka Ishii
Takahiro Iwahama
Tatsuya Nakano
Takahiro Iwahama
Tatsuya Nakano
Application Number:
JP2000588099A
Publication Date:
December 24, 2009
Filing Date:
December 09, 1999
Export Citation:
Assignee:
Daicel Chemical Industry Co., Ltd.
International Classes:
C07B37/02; B01J31/02; C07B37/04; C07B41/00; C07C2/76; C07C2/82; C07C13/615; C07C29/32; C07C29/36; C07C31/137; C07C45/33; C07C45/34; C07C45/39; C07C49/323; C07C49/345; C07C67/333; C07C67/347; C07C69/675; C07C69/716; C07C69/732; C07D307/33; C07D315/00; C07D317/30; C08F20/28; C08F20/30; C08L33/14; C07B61/00
Domestic Patent References:
| JP63135378A | ||||
| JP10307396A | ||||
| JP9110851A | ||||
| JP9090637A |
Foreign References:
| WO1998040337A1 |
Other References:
Tetrahedron Letters,1984年,25(39),4375-4378
Biotechnology Letters,1994年,16(10),1047-1052
Journal of Chemical Research (Synop.),1993年,(2),68-69
Tetrahedron Letters,1992年,33(38),5625-5628
Helvetica Chimica Acta,1980年,63(1),197-200
Tetrahedron,1997年,53(30),10555-10564
The Journal of Organic Chemistry,1995年,60(17),5693-5695
The Journal of Organic Chemistry,1994年,59(12),3487-3489
SYNTHESIS,1977年,(10),718-720
Biotechnology Letters,1994年,16(10),1047-1052
Journal of Chemical Research (Synop.),1993年,(2),68-69
Tetrahedron Letters,1992年,33(38),5625-5628
Helvetica Chimica Acta,1980年,63(1),197-200
Tetrahedron,1997年,53(30),10555-10564
The Journal of Organic Chemistry,1995年,60(17),5693-5695
The Journal of Organic Chemistry,1994年,59(12),3487-3489
SYNTHESIS,1977年,(10),718-720
Attorney, Agent or Firm:
Yukihisa Goto