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Title:
MODERATE LOW SULFURIZATION BY HYDROGENATION TREATMENT/ EXTRACTION FOR USING IN FUEL CELL
Document Type and Number:
Japanese Patent JP2003020485
Kind Code:
A
Abstract:

To provide a method of desulfurization, attached directly to a fuel cell, performing the desulfurization of its fuel as a part of the fuel cell system and capable of directly supplying the fuel as a fuel for a PEM fuel cell.

This method of desulfurization comprises bringing a hydrocarbon-based fuel containing sulfur in contact with hydrogen in the presence of a hydrogenation catalyst at 300-500°F temperature, 50-500 psig total pressure and 0.5-10 hr-1 space velocity for a sufficient time to convert up to 95% thiophene presenting in the fuel, and also bringing the above hydrogenation- treated hydrocarbon-based fuel in contact with a solid adsorbent or a liquid extracting agent selected from reducing the sulfur compound remaining in the above fuel to ≤5.0 ppm, recovering the hydrocarbon-based fuel reduced with the sulfur content and supplying it as the fuel for the PEM fuel cell.


Inventors:
JOSSENS LAWRENCE W
DIECKMANN GUNTHER H
MUNSON CURTIS
Application Number:
JP2002101363A
Publication Date:
January 24, 2003
Filing Date:
April 03, 2002
Export Citation:
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Assignee:
CHEVRON USA INC
International Classes:
B01J20/02; B01J20/08; B01J20/12; C10G21/00; C10G25/06; C10G45/04; C10G45/08; C10G45/10; C10G49/10; C10G65/04; C10G65/06; C10G67/04; C10G67/06; H01M8/06; H01M8/10; (IPC1-7): C10G67/06; B01J20/02; B01J20/08; B01J20/12; C10G21/00; C10G25/06; C10G45/08; C10G45/10; C10G67/04; H01M8/06; H01M8/10
Domestic Patent References:
JPH04285691A1992-10-09
JPH0680972A1994-03-22
Foreign References:
WO1999067018A11999-12-29
WO2000039873A12000-07-06
WO2000078443A12000-12-28
Attorney, Agent or Firm:
Akira Asamura (3 outside)