Title:
新規イソシアニド化合物及びヒドロシリル化反応触媒
Document Type and Number:
Japanese Patent JP6620823
Kind Code:
B2
Abstract:
Provided are a novel isocyanide compound, a hydrosilylation reaction catalyst having excellent handling properties and storage properties that allows a hydrosilylation reaction to proceed under moderate conditions by using the isocyanide compound, and a method for producing an addition compound by a hydrosilylation reaction using the hydrosilylation reaction catalyst. A hydrosilylation reaction catalyst prepared from a catalyst precursor comprising a transition metal compound of groups 8, 9, or 10 of the periodic table, excluding platinum, such as an iron carboxylate, cobalt carboxylate, or nickel carboxylate, and a ligand comprising an isocyanide compound having an organosiloxane group.
Inventors:
Koji Sakuta
Hideo Nagashima
Yusuke Sunada
Daisuke Noda
Hideo Nagashima
Yusuke Sunada
Daisuke Noda
Application Number:
JP2017562858A
Publication Date:
December 18, 2019
Filing Date:
January 18, 2017
Export Citation:
Assignee:
Shin-Etsu Chemical Co., Ltd.
Kyushu University
Kyushu University
International Classes:
C07F7/10; B01J31/22; B01J37/04; C07F7/08; C07F7/18; C07F7/21; C08G77/08; C08G77/38
Domestic Patent References:
| JP11271521A |
Other References:
KOTHA, Sambasivarao et al.,Synthesis and reactions of silicon-containing cyclic α-amino acid derivatives,Journal of Organometallic Chemistry,2004年,Vol.689, No.1,p.158-163,特にScheme 1., ISSN 0022-328X
KERCHER, Timothy et al.,Stereocontrolled Synthesis of 5-Acyl-3,4-dihydro-2H-pyrroles and Related Heterocycles via Intramolec,Journal of Organic Chemistry,1997年,Vol.62, No.4,p.805-812,特にScheme 1, ISSN 0022-3263
KING, R. B. et al.,Studies on Poly(iminomethylenes),Journal of Polymer Science, Part A: Polymer Chemistry,1987年,Vol.25, No.3,p.907-918,特に917頁の式(1), ISSN 0887-624X
MAGNUS, Philip et al.,Studies on the synthesis of the antitumor agent CC-1065. Synthesis of the unprotected cyclopropapyrr,Journal of the American Chemical Society,Vol.109, No.9,p.2706-2711,特に2708頁の右欄, ISSN 0002-7863
SCHOELLKOPF, Ulrich et al.,Syntheses with α-metalated isocyanides, XXXVII. 1-Lithio-1-alkenyl isocyanides and their reactions,Justus Liebigs Annalen der Chemie,1977年,Vol.1977, No.7,p.1167-1173,特に1169頁, ISSN 0075-4617
KERCHER, Timothy et al.,Stereocontrolled Synthesis of 5-Acyl-3,4-dihydro-2H-pyrroles and Related Heterocycles via Intramolec,Journal of Organic Chemistry,1997年,Vol.62, No.4,p.805-812,特にScheme 1, ISSN 0022-3263
KING, R. B. et al.,Studies on Poly(iminomethylenes),Journal of Polymer Science, Part A: Polymer Chemistry,1987年,Vol.25, No.3,p.907-918,特に917頁の式(1), ISSN 0887-624X
MAGNUS, Philip et al.,Studies on the synthesis of the antitumor agent CC-1065. Synthesis of the unprotected cyclopropapyrr,Journal of the American Chemical Society,Vol.109, No.9,p.2706-2711,特に2708頁の右欄, ISSN 0002-7863
SCHOELLKOPF, Ulrich et al.,Syntheses with α-metalated isocyanides, XXXVII. 1-Lithio-1-alkenyl isocyanides and their reactions,Justus Liebigs Annalen der Chemie,1977年,Vol.1977, No.7,p.1167-1173,特に1169頁, ISSN 0075-4617
Attorney, Agent or Firm:
Hideaki International Patent Office