Title:
NEW METHOD FOR OXIDIZING ALCOHOLS
Document Type and Number:
Japanese Patent JP2003113131
Kind Code:
A
Abstract:
To provide a new method for oxidizing an alcohol, which is safe and simple and with which aftertreatment is readily carried out by solving a problem that in conventional general-purpose alcohol oxidation methods, an oxidation method using Dess-Martin periodinane is reported to have explosivity, Swern oxidation requires strict control of reaction temperature and though an oxidation method using (diacetoxyiodo)benzene is also reported, operations of removal of unreacted oxidizing agent and by-products are frequently complicated.
A polymer on which (diacetoxyiodo)benzene is supported is used as an oxidizing agent to solve the problem. TEMPO (2,2,6,6-tetramethyl-1- piperidine-1-oxyl) is used in order to efficiently carry out the reaction.
Inventors:
TOGO HIDEO
SAKURATANI KENJI
TAHARA KENJI
SAKURATANI KENJI
TAHARA KENJI
Application Number:
JP2001337066A
Publication Date:
April 18, 2003
Filing Date:
September 28, 2001
Export Citation:
Assignee:
TOKYO KASEI KOGYO KK
International Classes:
C07C45/29; C07C47/232; C07C49/443; (IPC1-7): C07C45/29; C07C47/232; C07C49/443