Title:
【発明の名称】シリカ多孔体の製造方法
Document Type and Number:
Japanese Patent JP3322115
Kind Code:
B2
Abstract:
A process for manufacturing a silica porous material with high solid acidity, catalytic activity and adsorption ability as well as excellent crystallinity and heat resistance has the steps of adding a compound of metallic element such as Al to a waterglass, aging the resultant mixture, calcining the aged mixture to form a layered crystal, incorporating an organic substance between layers of the layered crystal, calcining the resultant layered crystal for crosslinking the layered crystal. By this process, a plurality of layers formed of SiO4 tetrahedral and metallic oxide constitute a silica porous material, and the gap between adjacent layers of the layered crystal is reduced at a crosslinking site, while the gap of the other portion is expanded to form a micro pore.
Inventors:
Yuri Yamada
Shinji Inagaki
Yoshiaki Fukushima
Shinji Inagaki
Yoshiaki Fukushima
Application Number:
JP3564896A
Publication Date:
September 09, 2002
Filing Date:
January 29, 1996
Export Citation:
Assignee:
Toyota Central R & D Labs.
International Classes:
B01J20/10; B01J21/08; B01J29/035; C01B33/12; C01B33/18; C01B33/20; C04B38/04; C01B33/26; C04B38/06; (IPC1-7): C01B33/12; B01J20/10; B01J29/035; C04B38/04; C04B38/06
Domestic Patent References:
| JP867578A | ||||
| JP834607A | ||||
| JP4238810A |
Other References:
ＣＯＮＧ−ＹＡＮ ＣＨＥＮ，Ｓｔｕｄｉｅｓ ｏｎ ｍｅｓｏｐｏｒｏｕｓ ｍａｔｅｒｉａｌｓ，Ｍｉｃｒｏｐｏｒｏｕｓ Ｍａｔｅｒｉａｌｓ，１９９３年，ｖｏｌ．２ Ｎｏ．１，ｐ．１７−２６
Ｋ．Ｒ．ＫＬＯＥＳＴＲＡ，ＭＣＭ−４１ ｔｙｐｅ ｍａｔｅｒｉａｌｓ ｗｉｔｈ ｌｏｗ Ｓｉ／Ａｌ ｒａｔｉｏｓ，Ｃａｔａｌｙｓｉｓ Ｌｅｔｔｅｒｓ，１９９５年，ｖｏｌ．３３ Ｎｏ．１，２，ｐ．１５７−１６３
ＴＳＵＮＥＯ ＹＡＮＡＧＩＳＡＷＡ，Ｔｈｅ Ｐｒｅｐａｒａｔｉｏｎ ｏｆ Ａｌｋｙｌｔｒｉｍｅｔｙｌａｍｍｏｎｉｕｍ−Ｋａｎｅｍｉｔｅ Ｃｏｍｐｌｅｘｓｅ ａｎｄ Ｔｈｅｉｒ Ｃｏｎｖｅｒｓｉｏｎ，Ｂｕｌｌｅｔｉｎ ｏｆ ｔｈｅ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ，１９９０年，ｖｏｌ．６３，Ｎｏ．４，ｐ．９８８−９９２
Ｋ．Ｒ．ＫＬＯＥＳＴＲＡ，ＭＣＭ−４１ ｔｙｐｅ ｍａｔｅｒｉａｌｓ ｗｉｔｈ ｌｏｗ Ｓｉ／Ａｌ ｒａｔｉｏｓ，Ｃａｔａｌｙｓｉｓ Ｌｅｔｔｅｒｓ，１９９５年，ｖｏｌ．３３ Ｎｏ．１，２，ｐ．１５７−１６３
ＴＳＵＮＥＯ ＹＡＮＡＧＩＳＡＷＡ，Ｔｈｅ Ｐｒｅｐａｒａｔｉｏｎ ｏｆ Ａｌｋｙｌｔｒｉｍｅｔｙｌａｍｍｏｎｉｕｍ−Ｋａｎｅｍｉｔｅ Ｃｏｍｐｌｅｘｓｅ ａｎｄ Ｔｈｅｉｒ Ｃｏｎｖｅｒｓｉｏｎ，Ｂｕｌｌｅｔｉｎ ｏｆ ｔｈｅ Ｃｈｅｍｉｃａｌ Ｓｏｃｉｅｔｙ ｏｆ Ｊａｐａｎ，１９９０年，ｖｏｌ．６３，Ｎｏ．４，ｐ．９８８−９９２
Attorney, Agent or Firm:
Yoshiyasu Takahashi