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Title:
Perfluoro sulfonic acid polymer Azole - acid blend membrane, a manufacturing method for the same, perfluoro sulfonic acid polymer Azole blend membrane, a manufacturing method for the same, and a proton exchange film fuel cell
Document Type and Number:
Japanese Patent JP6252886
Kind Code:
B2
Abstract:
PROBLEM TO BE SOLVED: To provide an electrolyte membrane for PEMFC endurable to a high temperature.SOLUTION: A Nafion solution containing a propanol, a 1,2,3-triazole and a phosphoric acid are mixed and heated and reacted in an autoclave for drying a reaction solution as a membrane. Alternatively reaction is carried out for film formation without adding phosphoric acid for applying an activation process in sulfuric acid. A PEMFC using such a membrane as the electrolyte membrane is operated highly efficiently in conditions with a temperature of 100°C or higher and a low humidity, which are unable to attain a normal operation in the case of using only Nafion.

Inventors:
Kim Jinde
Whole sentence tin
Application Number:
JP2013080573A
Publication Date:
December 27, 2017
Filing Date:
April 08, 2013
Export Citation:
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Assignee:
National Institute for Materials Science
International Classes:
C08J5/22; C08K3/24; C08K5/05; C08K5/3445; C08L101/02; H01M8/00
Domestic Patent References:
JP2007109634A
JP2010526912A
JP2010526911A
Other References:
ECS Transactions, Vol.35, No.32 (2011) p.241-250
Journal of Membrane Science Vol.396 (2012) p.32-37
Journal of The Electrochemical Society, Vol.157, No.12 (2010) p.B1872-B1877